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111.
Jelena Šamonina-Kosicka 《Isotopes in environmental and health studies》2013,49(3):357-364
Diamine oxidase (DAO), the enzyme that is responsible for amine biodegradation in animals, plants and humans, catalyses the biotransformation of amines such as histamine (HA), putrescine, 1-phenylethylamine, tyrosine, tryptamine, serotonine and spermine. The kinetic and solvent isotope effects (SIEs) were applied to study the mechanism of the biotransformation using HA and its methylderivatives. The SIE for the biotransformation of HA, Nτ-methylhistamine and Nπ-methylhistamine was found to be 3.58, 2.22 and 5.70 on Vmax, and 1.58, 1.06 and 1.14 on Vmax/KM, respectively. On the other hand, the kinetic isotope effect for oxidation of stereospecifically deuterium-labelled [(α R)-2H]-Nτ-methylhistamine and [(α R)-2H]-Nπ-methylhistamine was 0.69 and 0.62 on Vmax, and 15.06 and 7.50 on Vmax/KM, respectively. These results demonstrate that DAO catalyses amine biotransformation by stereospecifically cleaving the αC\bond H bond in the pro-S position. Moreover, the oxidation of amine to aldehyde involves several transition states, including hybridisation change from sp3 (Schiff base) to sp2 (imine), then back again to sp3 to give a final product with hybridisation sp2 (aldehyde). 相似文献
112.
A. Robert 《Isotopes in environmental and health studies》2013,49(5):153-159
In der Arbeit wird das im Kernforschungszentrum Saclay, Frankreich, entwicketle Gerät “SARIEL” für die Röntgenfluores-zenzanalyse mit Radionuklid-Stralungsquellen bechrieben. Das Gerät besitzt als Detektor einen fensterlosen Proportional-zāhler und ermöglicht bei Verwendung von α-Quellen die Bestimmung auch leichter Elemente, wie z. B. Kohlenstoff. Der Aufbau des Geräts und einige typische Anwedungsbeispiele werden erläutert. 相似文献
113.
Frequency differences of up to 170 GHz between a cw dye laser and a krypton laser at 568 nm were measured by mixing laser and microware radiation with a metalinsulator-metal point contact diode. Beat signals are well above noise and there is still great potential for improvement when better microwave oscillators are used. From the measurements reported it follows that the diode can be used for determining still higher frequency differences of visible laser radiation. 相似文献
114.
Summary. We have discovered a new implementation of the
qd algorithm that has a far wider domain of stability than Rutishauser's version. Our algorithm was
developed from an examination of the {Cholesky~LR} transformation and can be adapted
to parallel computation in stark contrast to traditional qd. Our algorithm also yields
useful a posteriori upper and lower bounds on the smallest singular
value of a bidiagonal matrix.
The zero-shift bidiagonal QR of Demmel and Kahan computes the smallest singular
values to maximal relative accuracy and the others to maximal absolute accuracy
with little or no degradation in efficiency when compared with the
LINPACK code. Our algorithm obtains maximal relative accuracy for all
the singular values and runs at least four times faster than the LINPACK code.
Received August 8, 1993/Revised version received May 26, 1993 相似文献
115.
Martin Lorenz 《Commentarii Mathematici Helvetici》1994,69(1):474-482
LetG be a finite group acting by automorphisms on an algebraS over some commutative ringk. We show that if the action ofG restricted to the center ofS is Galois in the sense of [C-H-R], thenHH
*(S
G)≊HH
*
(S)
G. An analogous result holds for cyclic homology, provided the order ofG is invertible ink.
The author was supported in part by a grant from the NSF. 相似文献
116.
A familyF of subsets is calledk-dense if there exists ak-element setA such that all 2
k
of its subsets can be obtained in the formAF for someFF. Best possible bounds are obtained for the maximum number of sets in notk-densek-partite families. This is a consequence of a new rank formula for inclusion matrices. 相似文献
117.
Vsevolod K. Malinovskii 《Acta Appl Math》1994,34(1-2):261-281
Edgeworth expansions for the distribution of a sequential least squares estimator in the random coefficient autoregressive (RCA) model are derived. The regenerative approach to second-order asymptotic analysis of Markov-type statistical models is developed. 相似文献
118.
We give cogenerators for the categories of convex (= finitely superconvex), finitely positively convex, and absolute convex (= finitely totally convex) spaces introduced by Pumplün and Röhrl.Dedicated to our academic teacher Dieter Pumplün on the occasion of his sixtieth birthday. 相似文献
119.
120.
Günter Last 《Probability Theory and Related Fields》1994,99(3):361-388
Summary We consider a point process with the Polish phase space (X,X) and a system of -fields (x),xX, generated by on certain sets (x)X. We define predictability for random processes indexed byX and for random measures onX and prove the existence and uniqueness of predictable and dual predictable projections under a regularity condition on . ForX=
2
+
and under monotonicity assumptions on the sets x we will identify the predictable projections of some simple processes as regular versions of certain martingales. 相似文献