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101.
The adsorption of asymmetrical triblock copolymers from a non-selective solvent on solid surface has been studied by using Scheutjens-Fleer mean-field theory and Monte Carlo simulation method on lattice model. The main aim of this paper is to provide detailed computer simulation data, taking A8-kB20Ak as a key example, to study the influence of the structure of copolymer on adsorption behavior and make a comparison between MC and SF results. The simulated results show that the size distribution of various configurations and density-profile are dependent on molecular structure and adsorption energy. The molecular structure will lead to diversity of adsorption behavior. This discrepancy between different structures would be enlarged for the surface coverage and adsorption amount with increasing of the adsorption energy. The surface coverage and the adsorption amount as well as the bound fraction will become larger as symmetry of the molecular structure becomes gradually worse. The adsorption layer becomes thicker with increasing of symmetry of the molecule when adsorption energy is smaller but it becomes thinner when adsorption energy is higher. It is shown that SF theory can reproduce the adsorption behavior of asymmetrical triblock copolymers. However, systematic discrepancy between the theory and simulation still exists.The approximations inherited in the mean-filed theory such as random mixing and the allowance of direct back folding may be responsible for those deviations. 相似文献
102.
Ming Zhao WANG Guan Liang CAI Ling XIA Jun Jian YAO Hong Yan CHEN Zhao Xing MENG Bo Li LIUDepartment of Chemistry Beijing Normal University Beijing Chemical Defense Institute PLA Beijing 《中国化学快报》2004,15(4):495-497
The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents. 相似文献
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两相同部件温贮备可修的人机系统解的性质分析 总被引:5,自引:1,他引:4
郭卫华 《数学的实践与认识》2003,33(7):88-95
本文首先用强连续算子半群理论证明了两相同部件温贮备可修的人机系统动态非负解的存在唯一性 ,然后证明了 0是系统主算子的本征值 ,并得到 0本征值对应的本征向量是正的 ,从而系统存在稳态正解 . 相似文献
106.
n阶矩阵A称为完全正的,如果A有分解:A=BBT,其中B为元素非负矩阵,B的最小可能列数称为A的分解指数.本文考察低阶双非负矩阵在整数环上的完全正分解及其分解指数. 相似文献
107.
利用内部爆炸加载方法对U-Nb合金进行爆破试验,对爆破试验产生的破片进行回收,并对U-Nb合金破片进行一些微观检测分析,从而初步研究在爆炸加载下U-Nb合金的微观断裂机制。 相似文献
108.
Zhao Fang BAI Jin Chuan HOU 《数学学报(英文版)》2005,21(5):1167-1182
Let X be a (real or complex) Banach space with dimension greater than 2 and let B0(X) be the subspace of B(X) spanned by all nilpotent operators on X. We get a complete classification of surjective additive maps Ф on B0(X) which preserve nilpotent operators in both directions. In particular, if X is infinite-dimensional, we prove that Ф has the form either Ф(T) = cATA^-1 or Ф(T) = cAT'A^-1, where A is an invertible bounded linear or conjugate linear operator, c is a scalar, T' denotes the adjoint of T. As an application of these results, we show that every additive surjective map on B(X) preserving spectral radius has a similar form to the above with |c| = 1. 相似文献
109.
Spin-Polarized Tunnelling Magnetoresistance Effects in La0.833K0.167MnO3/SrTiO3 Polycrystalline Perovskite Manganites
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A sample of La0.833K0.167MnO3-SrTiO3 (LKMO/STO) is fabricated by the sol-gel method. The microstructure,magnetic and transportation properties have been studied. X-ray diffraction patterns indicate that the structure of LKMO/STO is a homogeneous solid solution phase. The resistivity of LKMO/STO shows the insulator behaviour, which is different from La0.833K0.167MnO3 (LKMO) whose resistivity shows metal-insulator transition with decreasing temperature. The low-field (moH = 0.02 T) magnetoresistance decreases from 11% to 0.2% with the increasing temperature from 4 K‘to 220K for the LKMO/STO sample. The magnitude of magnetoresistance in a strong field (μoH = 5.5 T) almost increases linearly with decreasing temperature and reaches the maximum of 65% at the low temperature of 4.2K, which is much higher than that oE LKMO (40%). The enhanced low-field magnetoresistance effects are quantitatively explained by the spin-polarized tunnelling at grain boundaries. 相似文献
110.