几何构型不同的Na团簇碰撞动力学研究

采用距离相关紧密束缚的分子动力学模型,在不同碰撞能量以及不同的碰撞参数下,研究了两种构型的Na6(2D),Na6(3D)与Na8团簇间的碰撞.讨论了反应机制的变化,即全融合、深度非弹、非弹性碰撞过程.结果表明:构型不同的团簇与相同的靶碰撞显示了不同的特征.低能时Na6(3D)易融合;DIC反应时,易于形成大的团簇 关键词： Na团簇 原子团簇碰撞 紧束缚模型     

对称正-负离手表面活性剂的胶团化和表面吸附自由能

根据所建议的表面活性剂疏水碳氢基在水溶液中自卷曲的分子构型和碳氢链/水界面自由能降低模型导出了对称正-负离子表面活性剂胶团化和表面吸附自由能及疏水自由能公式,计算结果支持上述理论模型。     

H+2,H+3团簇离子在沟道条件下的背散射质子产额测量

采用卢瑟福背散射方法,测得了每质子能量为650 keV的H+2,H+3团簇离子在Si晶体<100>和<110>沟道条件下的质子背散射能谱.结果发现,由于H+2,H+3团簇在晶体中的库仑爆炸和团簇效应,H+2的背散射质子产额大于H+的背散射产额,而H+3的背散射质子产额又大于H+2的背散射质子产额.通过计算,分别得到了H+2,H+3在<100>和<110>沟道方向的背散射质子产额相对于随机方向背散射产额之比随深度的分布.     

重核的结团放射性

对重核的结团放射性(¹⁴C—³⁴Si)的实验数据进行了系统的分析和研究.提出了一个描述结团放射性寿命的新公式.理论计算结果与实验寿命在5倍以内符合.指出结团放射性的衰变能和结团内α粒子数有一个新的线性关系,标志着重核表面有α凝聚.     

加速器束流脉冲化及氢二次离子发射研究

详细介绍了快速高压晶体管开关在加速器束流脉冲化和用于二次离子测量的加速器飞行时间谱仪上的应用. 利用飞行时间法研究了碳纳米管在不同能量的Si和Si2团簇离子轰击下氢二次离子的发射. 实验结果表明， 在每个原子质量单位的速度为2.5×108 cm/s以上， Si和Si2离子引起的氢二次离子的发射主要受电子阻止过程控制； 在每个原子质量单位的速度为2.5×108 cm/s以下和Si2团簇离子轰击的情况下， 氢二次离子的发射产额明显增加， 团簇离子在靶表面的核能损增强效应起主要作用. The application of Fast High Voltage Transistor Switches (HTS) in pulsed ion beam and the time of flight(TOF ) setup is described. Secondary ion emissions from carbon nanotubes under bombardments of MeV Si and Si2 clusters are measured by using TOF. The measurements indicate that the yield of the secondary ion emissions of hydrogen increases with increasing energy of Si and it is attributed to the electronic processes. The yield of the secondary ions of hydrogen decreases with increasing energy of Si2 clusters and the enhancement of nuclear energy loss of cluster constituents at the surface of sample plays a more significant role in the secondary ion emission of hydrogen at the low energies.     

HIRFL-CSR实验环内靶系统

兰州重离子加速器冷却储存环 (HIRFL CSR)的内靶系统 ,是用于为实验环内的物理实验提供厚度为 10 11— 10 13 atoms/cm2 的团簇靶和极化靶 .采用超声喷气技术获得团簇粒子束 ,采用Stern Gerlach方法获得极化氢束和极化氘束. The structure and the design of the HIRFL-CSR internal target system is reported. The HIRFL-CSR internal target can operate in two modes: cluster target mode and polarized target mode. The cluster target may provide the gas target of H 2, N 2, noble gases and small molecular gases with a density of ≥10 13 atoms/cm 2, and the polarized target may provide polarized H and D beams with a density of about 2×10 11 atoms/cm 2. The target polarization is expected to be...     

含笼状Si20的金属硅化物的合成和物性

含笼状Ｓｉ＿（２０）的金属硅化物的合成和物性随着Ｃ６０等富勒烯和Ｍ３Ｃ６０（Ｍ＝Ｋ，Ｒｂ等）超导材料研究的巨大进展，人们对其他含笼状团簇化合物的探索正在加紧进行。１９９５年日本学者在《固体物理》期刊上介绍了含笼状Ｓｉ２０的金属Ｓｉ化物、特别是对Ｎａ２...     

高能pp碰撞末态粒子的结团产生和前后关联

本工作在三火球模型的基础上引进结团(cluster)机制对多种窗口的前后关联进行Monte Carlo模拟.与s=200,546,900GeV的实验数据的符合表明了模型的合理性.同时从理论上说明了cluster机制对多重数关联的影响表现为短程加强,长程减弱.     

Theoretical investigation electroopticalof nonlinear properties ofchromophores

Organic electrooptical (EO) chromophores are now gaining more attention because the property of organic photorefrative (PR) materials could be controlled by doped EO chromophores. In this paper, nonlinear optical (NLO) properties of a new group of organic electrcoptical chromophores, synthesized recently in our laboratory, were elucidated theoretically with the quantum chemical density functional theory (DFT) and the intermediate neglect of differential overlap Hamilton and the configuration interaction (INDO/CI), as well as semiemperical Austin Modlel 1 (AM1) methods. The electronic transition intensity, dipole moment and the second- order polarizability were obtained. The results show this group of chromophores possess appropriate optical absorption property and good electrooptical property and optical activity. The second-order polarizabilities β are as large as the order of 10^-29 to 10^-28 ESU, indicating the promising applications in the future. The physical mechanism of NLO is discussed by means of molecular orbital and electronic charge distribution.