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161.
162.
Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering 下载免费PDF全文
The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents. 相似文献
163.
K-强凸空间的一些性质 总被引:4,自引:0,他引:4
结合Banach空间的Drop性,利用K维体积给出了K—强凸空间的一个新的定义,同时也给出了K—强光滑空间定义的K维体积表示,然后利用单位圆的切片证明了K—强凸空间是自反空间,进而证明了K—强凸空间与K—强光滑空间是一对对偶空间.最后利用Drop性的切片描述证明了K—强凸空间具有Drop性. 相似文献
164.
There are two conservation quantities needed to derive conservation laws of sine-Gordon equation in a frame of laboratory reference.one of them could be derived easily with a standard process,but the other could not .After the gauge transformation e^-iθσ2/2is introduced,we simply obtain the other one without any questionable assumption. 相似文献
165.
ZuoWei 《近代物理研究所和兰州重离子加速器实验室年报》2003,(1):6-6
The three-body force effects on the equation of state and its iso-spin dependence of asymmetric nuclear matter and on the proton fraction in neutron star matter have been investigated[1] within Brueckner Hartree-Fock (BHF) approach by using a microscopic three-body force. It is shown that, even in the presence of the three-body force, the empirical parabolic law of the energy per nucleon vs. isospin asymmetry β=(N-Z)/A is fulfilled in the whole asymmetry range 0 ≤β ≤1 and also up to high density. The three-body force provides a strong enhancement of symmetry energy at high density in agreement with relativistic approaches. Thecalculated proton fraction in β stable neutron star matter is given in Fig.l, where the thick solid line is the BHF prediction using AV18 TBF, while the dotted one is the BHF result using AVis. The thin solid line is the prediction of the Dirac-Brueckner approach taken from Ref.[2]. The results extracted according to the phenomenological paramete rizations of the symmetry energy suggested in Ref.[3] are also plotted. It is seen from 相似文献
166.
异方差回归中的广义方差比检验 总被引:1,自引:0,他引:1
在同方差假设之下,线性模型在回归分析的理论与应用方面起着突出的作用,很受许多研究工作者的青睐.然而,回归模型中同方差性这一标准假设不一定总是成立的.因此我们考虑了用一类基于似残差的方法来检验异方差情形下线性模型拟合观测数据的情况.本文既给出了大量的模拟,又给出了实际数据作为应用的例子.效果都很好. 相似文献
167.
关于高阶中立型偏微分方程系统解的振动性 总被引:16,自引:0,他引:16
近年来,由于偏泛函微分方程(组)理论在人口动力学,生物遗传工程和化学反应过程等领域中有广泛的应用,因而很多学者在偏泛函微分方程(组)解的振动性理论的研究方面做了大量工作,取得了许多成果.本文将研究一类较广泛的高阶中立型偏微分方程组 相似文献
168.
Nikolaos S. PAPAGEORGIOU Nikolaos YANNAKAKIS 《数学学报(英文版)》2005,21(5):977-996
This is the first part of a work on second order nonlinear, nonmonotone evolution inclusions defined in the framework of an evolution triple of spaces and with a multivalued nonlinearity depending on both x(t) and x(t). In this first part we prove existence and relaxation theorems. We consider the case of an usc, convex valued nonlinearity and we show that for this problem the solution set is nonempty and compact in C^1 (T, H). Also we examine the Isc, nonconvex case and again we prove the existence of solutions. In addition we establish the existence of extremal solutions and by strengthening our hypotheses, we show that the extremal solutions are dense in C^1 (T, H) to the solutions of the original convex problem (strong relaxation). An example of a nonlinear hyperbolic optimal control problem is also discussed. 相似文献
169.
进一步研究了具有三个cM公共值的亚纯函数的唯一性,改进了H.Ueda和仪洪勋等人的有关结果. 相似文献
170.
用A的不变子空间作参数,给出了算子方程AX=XAX的全部解。当A是单射或稠值域时,或者当A是正规算子时,给出了算子方程AX=XA=XAX的全部解。我们还给出正规算子X是算子方程AX=XZ=XAX的解的充分必要条件。 相似文献