全文获取类型
收费全文 | 28776篇 |
免费 | 4434篇 |
国内免费 | 13933篇 |
专业分类
化学 | 28706篇 |
晶体学 | 621篇 |
力学 | 1192篇 |
综合类 | 851篇 |
数学 | 5438篇 |
物理学 | 10335篇 |
出版年
2024年 | 267篇 |
2023年 | 1007篇 |
2022年 | 1212篇 |
2021年 | 1295篇 |
2020年 | 1130篇 |
2019年 | 1261篇 |
2018年 | 807篇 |
2017年 | 1181篇 |
2016年 | 1360篇 |
2015年 | 1450篇 |
2014年 | 2232篇 |
2013年 | 2286篇 |
2012年 | 2384篇 |
2011年 | 2335篇 |
2010年 | 2268篇 |
2009年 | 2419篇 |
2008年 | 2881篇 |
2007年 | 2649篇 |
2006年 | 2829篇 |
2005年 | 2473篇 |
2004年 | 2662篇 |
2003年 | 1680篇 |
2002年 | 838篇 |
2001年 | 763篇 |
2000年 | 759篇 |
1999年 | 874篇 |
1998年 | 500篇 |
1997年 | 373篇 |
1996年 | 301篇 |
1995年 | 281篇 |
1994年 | 288篇 |
1993年 | 382篇 |
1992年 | 388篇 |
1991年 | 395篇 |
1990年 | 299篇 |
1989年 | 289篇 |
1988年 | 191篇 |
1987年 | 80篇 |
1986年 | 33篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1959年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
22.
5,6-Dihydro-OSW-1 (1) was synthesized following our previous procedure for the total synthesis of OSW-1. This compound demonstrated slightly stronger potency than that of OSW-1 against the growth of cancer cells. 相似文献
23.
Ming Zhao WANG Guan Liang CAI Ling XIA Jun Jian YAO Hong Yan CHEN Zhao Xing MENG Bo Li LIUDepartment of Chemistry Beijing Normal University Beijing Chemical Defense Institute PLA Beijing 《中国化学快报》2004,15(4):495-497
The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents. 相似文献
24.
Spin-Polarized Tunnelling Magnetoresistance Effects in La0.833K0.167MnO3/SrTiO3 Polycrystalline Perovskite Manganites 下载免费PDF全文
A sample of La0.833K0.167MnO3-SrTiO3 (LKMO/STO) is fabricated by the sol-gel method. The microstructure,magnetic and transportation properties have been studied. X-ray diffraction patterns indicate that the structure of LKMO/STO is a homogeneous solid solution phase. The resistivity of LKMO/STO shows the insulator behaviour, which is different from La0.833K0.167MnO3 (LKMO) whose resistivity shows metal-insulator transition with decreasing temperature. The low-field (moH = 0.02 T) magnetoresistance decreases from 11% to 0.2% with the increasing temperature from 4 K‘to 220K for the LKMO/STO sample. The magnitude of magnetoresistance in a strong field (μoH = 5.5 T) almost increases linearly with decreasing temperature and reaches the maximum of 65% at the low temperature of 4.2K, which is much higher than that oE LKMO (40%). The enhanced low-field magnetoresistance effects are quantitatively explained by the spin-polarized tunnelling at grain boundaries. 相似文献
25.
We investigate magnetic and crystalline microstructures of melt-spun (Fe0.675Pt0.325)100-xBx (x=12, 14, 16, 18,20) nanocomposite ribbons after optimal thermal treatment using a magnetic force microscope. The magnetic microstructures are characterized by darker spots adjacent to brighter ones in a sub-micro scale and in random distribution. It is found that the strength of the exchange coupling interaction between the crystals in the 10-100 nm scale, implied by the maximum value (δM)max of the Henkel plot, could be roughly described by the ratio of the average width of the magnetic spots w^- to the average crystal size D^- for the ribbons. Moreover, we find that the intrinsic coercivity jHc of the ribbons is sensitive to their crystal sizes, and the smaller D^-, the higher jHc. Finally, by using roughness analysis, the curve of the root mean square values (δФ)rms of the phase shift of the magnetic force images versus the boron content x is obtained, which is qualitatively consistent with that of the magnetization σ12 kOe of the ribbons versus x. 相似文献
26.
基于改进遗传算法的布局优化子问题 总被引:2,自引:0,他引:2
本针对子问题,构造了布局子问题(关于同构布局等价类)的改进遗传算法。将该算法应用于二维布局优化子问题,数值实验表明该算法能够在很好地保持图元的邻接关系的前提下找到子问题的最优解。由于布局优化问题可分解为有限个子问题,所以利用该算法可以找到整个布局优化问题的全局最优解。 相似文献
27.
HUYUDA MENGZHIQING 《高校应用数学学报(英文版)》1998,13(4):473-477
In this paper, the existence theorem of the cone-weak subdiflerential of set-valued mapping in locally convex topological vector space is proved. 相似文献
28.
29.
该文对Cd-HEDTA(N-(2-羟基乙基)乙二胺-N',N',N'-三乙酸),Cd-PDTA(1,2丙二胺四乙酸)和Cd-DTPA(二乙三胺五乙酸)的113Cd NMR谱和自旋晶格弛豫时间T1,及NOE因子进行了研究.结果表明,Cd-HEDTA和Cd-PDTA结构与Cd-EDTA类似,Cd-PDTA双线归因于其可能的两种异构体.Cd-DTPA大的化学位移表明其具有七配位的五角双锥结构.在这种结构中DTPA可用三个氮原子参加配位.对113Cd自旋晶格弛豫时间分析表明,Cd-DTPA配合物中质子偶极作用机理的贡献较大,这归因于Cd DTPA有更多的乙酸根亚甲基质子参与偶极作用. 相似文献
30.
A temperature-dependent photoluminescence measurement is performed in CdSe/ZnSe quantum dots with a ZnCdSe quantum well.We deduce the temperature dependence of the exciton linewidth and peak energy of the zero-dimensional exciton in the quantum dots and two-dimensional exciton in the CdSe wetting layer.The experimental data reveal a reduction of homogeneous broadening of the exciton line in the quantum dots in comparison with that in the two-dimensional wetting layer,which indicates the decrease of exciton and optical phonon coupling in the CdSe quantum dots. 相似文献