水体系中含Mn~Ⅲ离子多酸化合物的原位合成、结构及性质研究

采用常规水溶液法在低热环境下得到了一种新的基于砷钨酸和Mn~Ⅲ的夹心型化合物,该化合物为单斜晶系,空间群为P2_1/c,晶胞参数为a=2.041 26(8)nm,b=3.227 58(8)nm,c=1.325 35(5)nm,β=94.427(3)°,V=8.705 8(5)nm~3,Z=4;分子式为(NH_4)_(10)[(MnH_2O)_2WO_2(AsW_9O_(33))_2]·3.5H_2O.性质分析表明,标题化合物对Hela细胞具有较高的抗肿瘤活性,可以作为潜在的抗肿瘤药物模型.     

一种混合价态钌配合物的合成、晶体结构和电化学性质

[Ru6(μ-O2CCH3)12(CH3OH)2(HCOO)2][Ru2(μ-O2CCH3)4(H2O)2](PF6)2.2H2O(Ru2(Ⅱ,Ⅲ)混合价)是通过二步反应合成的。首先Ru2(O2CCH3)4Cl在加热条件下与甲醇反应得到红棕色中间物,然后将该中间物在甲醇水(体积比7∶1)溶液中用Ag2SO4和NH4PF6进行脱氯配位反应得到此化合物。用元素分析、红外光谱、热重分析、循环伏安、X-衍射单晶结构分析等对其进行了表征。晶体结构表明,标题化合物的晶体属单斜晶系,空间群为P21/n,晶胞参数:a=0.85362(14)nm,b=1.19589(19)nm,c=3.6642(6)nm,β=92.316(3)°,Z=2,每个结构基元包含2个不同的配离子,其中[Ru2(μ-O2CCH3)4(H2O)2]+是1个双核钌配离子,[Ru6(μ-O2CCH3)12(CH3OH)2(HCOO)2]+是由另1个由甲醇配位、甲酸根桥连的六核钌配离子。2个独立的结构单元通过氢键形成三维超分子网络结构。采用循环伏安法对其电化学性质进行了表征,结果为一对准可逆的氧化还原峰,表明该配合物的中心金属二价钌原子Ru(Ⅱ)与三价钌原子Ru(Ⅲ)之间存在电子转移。     

Synthesis and Crystal Structure of the Heteropolymate Compound Na_3H_2[Ce_3(H_2O)_(18)Bi_2W_(22)O_(76)]·23H_2O

1 INTRODUCTION As a rich remarkable class of inorganic cluster systems, polyoxometalates continue to be the focus of significant attention in the 21th century because of their various and alluring topologies as well as their unusual physicochemical prope…     

金属络合物分子间交换反应的核磁共振研究Ⅲ.噻吩甲酰三氟丙酮铝与苯甲酰丙酮铝体系分子间配体交换的19F NMR研究

用¹⁹F NMR研究了噻吩甲酰三氟丙酮铝与苯甲酰丙酮铝体系分子间的团体交换反应,求得了交换反应的平衡常数及自由能,结果表明交换反应有利于混合配体络合物生成,平衡时混和溶液中各组分分布偏离统计分布。     

Lagrange系统Mei对称性的Ⅲ型结构方程和Ⅲ型Mei守恒量

研究Lagrange系统Mei对称性的Ⅲ型结构方程和Ⅲ型Mei守恒量.在群的无限小变换下,由Lagrange系统Mei对称性的定义和判据,得到Lagrange系统Mei对称性的Ⅲ型结构方程和Ⅲ型Mei守恒量.举例说明结果的应用.     

分光光度法研究在氯化钠-四丁基溴化铵体系中Au(Ⅲ)与U(Ⅵ)、Ce(Ⅲ)、Mg(Ⅱ)和Cu(Ⅱ)的浮选分离

用分光光度法研究了氯化钠和四丁基溴化铵浮选分离金的行为及与一些金属离子分离的条件。结果表明,当溶液中氯化钠和四丁基溴化铵的浓度分别为2.5×10-3mol/L和4.0×10-4mol/L,pH3.0时,Au(Ⅲ)可与U(Ⅵ)、Ce(Ⅲ)、Mg(Ⅱ)和Cu(Ⅱ)离子定量分离,对合成水样中Au(Ⅲ)的分离和测定,结果满意。     

Trigger efficiencies at BESⅢ

Trigger efficiencies at BESⅢ were determined for both the J/ψ and ψ' data taking of 2009. Both dedicated runs and physics datasets are used; efficiencies are presented for Bhabha-scattering events, generic hadronic decay events involving charged tracks, dimuon events and ψ'→π+π-J/ψ, J/ψ→ 1+1- events.The efficiencies are found to lie well above 99% for all relevant physics cases, thus fulfilling the BESⅢ design specifications.     

Charmonium results from BES

Using ～ 14 × 10^6 ψ（2S） and ～ 58 × 10^ J/ ψ data collected at BES Ⅱ/BEPC, the branching fraction of ψ（2S）→Ω-Ω^＋ is measured with about 5a statistical significance. The A electric dipole and ∧ decay parameter are studied using the decay J/ψ →∧∧→ ppπ^＋π^-. Using （106±3）× 10^6 ψ（2S） decays collected at BESⅢ/BEPC Ⅱ, we have obtained some interesting physics results. The branching fractions of XcJ→π^0π^0, ηη are measured with precision improved. The mass and width of he（l^1P1） state, together with the branching fractions of Br（ψ（2S） →π^0hc） and Br（hc →γηc） are the first measurements. Surprisingly, the decays of Xc1→φφ, ωω, and ωφ are firstly observed in BESⅢ data.     

Trigger efficiencies at BESⅢ

Trigger efficiencies at BESⅢ were determined for both the J/ψ and ψ＇ data taking of 2009. Both dedicated runs and physics datasets are used; efficiencies are presented for Bhabha-scattering events, generic hadronic decay events involving charged tracks, dimuon events and ψ＇→π＋π-J/ψ, J/ψ→ 1＋1- events.The efficiencies are found to lie well above 99% for all relevant physics cases, thus fulfilling the BESⅢ design specifications.