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981.
Barium ferrites substituted by Mn-Sn, Co-Sn, and Mn-Co-Sn with general formulae BaFe12−2xMnxSnxO19 (x=0.2-1.0), BaFe12−2xCoxSnxO19 (x=0.2-0.8), and BaFe12−2xCox/2Mnx/2SnxO19 (x=0.1-0.6), respectively, have been prepared by a previously reported co-precipitation method. The efficiency of the method was refined by lowering the reaction temperature and shortening the required reaction time, due to which crystallinity improved and the value of saturated magnetization increased as well. Low coercivity temperature coefficients, which are adjustable by doping, were achieved by Mn-Sn and Mn-Co-Sn doping. Synthesis efficiency and the effect of doping are discussed taking into account accumulated data concerning the synthesis and crystal structure of ferrites. 相似文献
982.
ZnSe/SiO2半导体量子点玻璃的光谱特性 总被引:1,自引:0,他引:1
对采用溶胶凝胶法制备的ZnSe/SiO2半导体量子点玻璃的光谱性质进行了测试分析.UV-Vis透射光谱中观察到光吸收边相对于体相半导体有明显蓝移.稳态发射光谱(PL)中观察到ZnSe纳米晶体的位于蓝区的基本呈高斯分布的弱的最低激子发射峰、强而宽的表面态发光带以及对应杂质能级的三个锐峰发光.时间分辨荧光光谱(TRPL)中观察到发光效率高的最低激子发射峰,并测量其荧光衰减寿命,经尾部拟合为28.5 ps.同时,结合有效质量近似(EMA)模型,估计ZnSe纳米晶体的平均粒径介于2.45~3.60 nm之间,尺寸分布基本呈高斯型. 相似文献
983.
984.
985.
G.A. Medvedkin V.M. Smirnov T. Ishibashi 《Journal of Physics and Chemistry of Solids》2005,66(11):2015-2018
Photoluminescence of CdGeP2 (112) single crystal and CdGeP2 epitaxial film grown on GaAs (001) substrate have been studied and their spectral similarity found. Spectral bands associated with donor/acceptor transitions peak at close energies for both substances and all are lower than the energy gap of the chalcopyrite crystal.On the other hand, the growth of (Cd,Mn)GeP2 ferromagnetic layer on CdGeP2 (112) single crystal was performed to make it possible observation of PL from both the ferromagnetic layer and substrate. The green laser excitation (514, 532 nm) produces a proper photoluminescence similar to that in the undoped CdGeP2 crystal and film. An extra emission from the ferromagnetic-nonmagnetic heterojunction occurs to extend up to photon energies exceeding Eg of the host semiconductor. The short wavelength photoluminescence is to be due to (Cd,Mn)GeP2 dilute magnetic semiconductor (DMS). This fact states that Mn-doped II-IV-V2 chalcopyrites are closer to II-VI DMS than to another group III-V DMS, where the heavy Mn-doping suppresses photoluminescence at all. Features of the observed short wavelength emission are discussing based on the temperature and spectral analyses. 相似文献
986.
Xu Xiaoyong Zheng Guoguang Wang Qing-an 《Journal of Quantitative Spectroscopy & Radiative Transfer》2005,92(1):61-72
This paper experimentally and theoretically examines the scattering properties of simulated non-spherical hydrometeors including water oblates, ice oblates and ice sphere-cone-oblates, in terms of the backscattering cross-section and the differential reflectivity. The experimental measurements of the backscattering cross-sections of non-spherical hydrometeor samples were performed in the Electromagnetic Scattering Laboratory of China National Space Industrial Corporation. Meanwhile, the backscattering cross-sections have been computed with the transition (T) matrix method. The theoretical results are compared with the experimental data, showing that the calculations are consistent with the observations in general. Experimental and theoretical analyses indicate that the backscattering cross-section of non-spherical particles increases as the particle size parameter increases, and fluctuates when the sizes are larger under the effect of resonance scattering. Differential reflectivity ZDR of water oblates in natural rainfall is always greater than 0 dB whereas ZDR of hailstones may be negative. There is a good linear relationship between differential reflectivity and aspect ratio of a particle. These derivations agree with the literature and can be used to identify the presence of hail particles and distinguish between plate-type and columnar-type hydrometeors. In this study, the measuring experiment and the T-matrix method calculations for the scattering of simulated raindrop and ice particles are also briefly described. 相似文献
987.
以电子仓单融资为例, 基于银行下侧风险规避角度, 研究联合授信和委托授信下当第三方B2B平台存在行为隐匿的道德风险时, 银行对B2B平台的激励策略设计问题。研究发现:B2B平台的最优努力水平随收益分配比例、回购比例的增大而减小, 随质押率、贷款利率、产品采购量、损失补偿比例的增大而增大;同时银行为规避违约风险, 需设置质押率、贷款利率和贷款额上限及回购比例下限, 并且银行最优收益分配比例与损失补偿比例、最优损失补偿比例与贷款损失率均成正相关关系。此外, 随着B2B平台工作效率的提高, 联合授信下最优收益分配比例将减小, 最优损失补偿比例将增大, 最终近似于委托授信下的最优损失补偿比例。最后给出数值分析。 相似文献
988.
Charging of the surface of an oxide caused by the adsorption of hydrogen ions and ions of inert 1:1 electrolyte was investigated by using grand canonical Monte Carlo simulation technique. In particular, adsorption isotherms of protons as well as of ions of the electrolyte together with the resulting charge density of the surface were obtained for different system parameters. Also, the effect of the surface energetic heterogeneity and the concentration of the background electrolyte on the isotherms and the charge density curves was examined. Furthermore, lateral interactions in the mixed adsorbed phase were taken into account in the modeling of the system behavior. The obtained results, in general, suggest that the three factors mentioned above may have substantial influence on the charging mechanism at the liquid/oxide interface. 相似文献
989.
Effects of pulsed bias duty ratio on microstructure and mechanical properties of TiN/TiAlN multilayer coatings 总被引:2,自引:0,他引:2
Yongqiang WeiChunzhi Gong 《Applied Surface Science》2011,257(17):7881-7886
TiN/TiAlN multilayer coatings were deposited on M2 high speed steel by a pulsed bias arc ion plating system. The effect of pulsed bias duty ratio on the microstructure, mechanical and wear properties was investigated. The amount of macroparticles reduced with the increase of the duty ratio. The surface roughness was 0.0858 μm at duty ratio of 50%. TiN/TiAlN multilayer coatings were crystallized with orientations in the (1 1 1), (2 0 0) (2 2 2) and (3 1 1) crystallographic planes and the microstructure strengthened at (1 1 1) preferred orientation. At duty ratio of 20%, the hardness of TiN/TiAlN multilayer coatings reached a maximum of 3004 HV, which was 3.2 times that of the substrate. The adhesion strength reached a maximum of 77 N at 50% duty ratio. Friction and wear analyses were carried out by pin-on-disc tester at room temperature. Compared with the substrate, all the specimens coated with TiN/TiAlN multilayer coatings exhibited better tribological properties. 相似文献
990.