Synthesis and Photocatalytic Property of ZnO/TiO2 Inverse Opals Films with Controllable Composition and Topology

A novel method to fabricate composition- and topology-controlled ZnO/TiO₂ inverse opals (IO) films using a positive sacrificial ZnO IO template has been developed. This method includes a two-step process, preparation of ZnO IO by a simple electrochemical deposition using a self-assembly polystyrene colloidal crystal template and preparation of ZnO/TiO₂ IO by a liquid phase deposition (LPD) process at room temperature. The composition and topology of ZnO/TiO₂ IO can be easily controlled by changing the duration of the LPD. After 20 min LPD process, a ZnO/TiO2 composite IO with non-close-packed face-centered cubic air sphere array was obtained. Prolonging the duration to 60 min, a pure TiO₂ IO (TIO-LPD60) with obviously thickened walls was formed. The formation mechanism for the compositional and topological variation was discussed. A preliminary study on UV photocatalytic property of the samples for degradation of methylene blue reveals that the composition and topology significantly influenced the photocatalytic activity of the IO film. The ZnO/TiO₂ composite IO demonstrates a higher degree of activity than both pure ZnO and pure TiO₂ IO, although they have a similar IO wall thickness. Moreover, with increasing IO wall thickness from ～52 nm to ～90 nm, TIO-LPD60 exhibits the highest level of photocatalytic performance.     

反相气相色谱法探究铜镁铝水滑石的表面性质

采用共沉淀法合成了Cu_xMg_3-xAl-LDHs (x＝0～3), 利用FTIR 及IGC 法(反相气相色谱法)对合成的样品进行测试和表征, 并结合计算机模拟的结果来探讨铜镁铝水滑石的表面性质. 结果表明, 随 Cu²⁺含量的增加, 铜镁铝水滑石表面吸附自由能及表面能色散组分增加, 稳定性下降, 这可能由于Cu²⁺本身具有的Jahn-Teller 畸变会很大程度地影响层板的稳定性, 导致含铜水滑石体系的稳定性降低; 随着Cu²⁺含量的增加, 水滑石表面碱性先减小后增大.     

A Compton scattering image reconstruction algorithm based on total variation minimization

Compton scattering imaging is a novel radiation imaging method using scattered photons.Its main characteristics are detectors that do not have to be on the opposite side of the source,so avoiding the rotation process.The reconstruction problem of Compton scattering imaging is the inverse problem to solve electron densities from nonlinear equations,which is ill-posed.This means the solution exhibits instability and sensitivity to noise or erroneous measurements.Using the theory for reconstruction of sparse images,a reconstruction algorithm based on total variation minimization is proposed.The reconstruction problem is described as an optimization problem with nonlinear data-consistency constraint.The simulated results show that the proposed algorithm could reduce reconstruction error and improve image quality,especially when there are not enough measurements.     

光纤倒像器调制传递函数测试结果的加权修正

狭缝式调制传递函数测试系统可以测试光纤倒像器的调制传递函数,但由于测试过程中较多的人工参与,使得调制传递函数测试结果的重复性较差。针对影响光纤倒像器调制传递函数测试重复性的数据采样、积分时间以及人眼疲劳特性进行了分析,给出了针对数据采样和积分时间的解决方法,针对人眼疲劳特性提出了基于人眼时间递增因子的加权修正方法。对6块光纤倒像器的调制传递函数进行了三批次测试,并对测试结果进行了直接校正和加权修正的比较,结果表明:加权修正较好地解决了测试重复性问题,被测6块光纤倒像器加权修正后的调制传递函数最大重复性偏差不超过7%。     

Improved frequency standard via weighted graph states

We study the spin squeezing property of weighted graph states,which can be used to improve sensitivity in interferometry.We study the time evolution of spin squeezing under local decoherence acting independently on each qubit.Based on the analysis,the spin squeezing of the weighted graph states is somehow robust in the presence of decoherence and the decoherence limit in the improvement of the interferometric sensitivity is still achievable.Furthermore,one can obtain the optimal improvement of sensitivity by tuning the weighted of each edges of the weighted graph state.     

PECULIARITIES OF IRREVERSIBLE STRAINING IN STEP-WISE LOADING, REVERSE AND INVERSE CREEP

The paper is concerned with the generalization of synthetic theory to the modeling of phenomena such as the Bauschinger negative effect,creep delay,reverse and inverse creep.Detailed calculations of pl...     

WEIGHTED ESTIMATES FOR MULTIVARIATE HAUSDORFF OPERATORS

In this paper,some weighted estimates for the multivariate Hausdorff operators are obtained.It is proved that the multivariate Hausdorff operators are bounded on L p spaces with power weights,which is based on the boundedness of multivariate Hausdorff operators on Herz spaces,and are bounded on weighted L p spaces with the weights satisfying the homogeneity of degree zero.     

Evaluation of boron industrial solid waste in composite materials

Boron industrial solid waste is used as reinforcement for preparing composite materials. This waste has boron trioxide which holds unique properties may affect the surface or interface of the composite. The prepared composites are characterized in order to determine the dispersion and the structure by means of inverse gas chromatography (IGC), Fourier transform infrared spectroscopy, thermal gravimetric analysis, scanning electron microscopy (SEM) and X-ray diffraction (XRD). There is a strong relation between the dispersion of reinforcement and the properties of newly formed composite. The dispersive component of the surface energies of the composites and components are determined by IGC. This parameter is difficult to measure by other methods and it is related to the wettability and adhesive characters of solid materials. The effect of compounding ratios of reinforcement is also examined. Furthermore, XRD diffractograms and SEM images of composites showed well dispersion. Thermal analysis revealed that the addition of the boron industrial solid waste to the polymer increased the thermal stability of pure polymer. Infrared spectra of the composites indicated that the composites were formed from the waste reinforcement and the polymer matrix.     

高对比度目标的电磁逆散射超分辨成像

提出了一种适用于高对比度目标的超分辨成像方法,通过结合对比度源反演方法与基于轨道角动量的超分辨技术,实现对高对比度目标的超分辨成像.首先采用基于轨道角动量的成像方法求解出对比度函数,将其作为对比度源反演方法的迭代初值,虽然初值结果与实际目标相差较大,但是由于初值中已经包含了关于目标的倏逝波信息,再利用这个初值开始迭代便可以得到超分辨重建结果,这种方法具有一定的抗噪声能力.本文研究表明,为了实现超分辨成像,一方面需要将目标对应的倏逝波信息转化到测量数据中,另一方面还要保证成像算法能够充分利用这些信息.本文所引申出的关于超分辨信息的概念对于逆散射超分辨成像的研究具有一定的借鉴意义.     

若干运算图的倍乘赋权Harary指标

ALIZADEH等近期提出了一个修正的Harary指标,即顶点对的贡献被赋予其度的乘积.其指标被称为倍乘赋权Harary指标,定义为H_M（G）=Σ_u≠v（δ_G（u）δ_G（v））（d_G（u,v））,其中,δ_G（u）表示顶点u在图G中的度,d_G（u,v）表示2个顶点u和v在图G中的距离.给出了张量积G×K_r,强积GK_r,圈积G₁oG₂的倍乘赋权Harary指标值的精确计算公式,这些公式与图的其他不变量（如倍加赋权Harary指标、Harary指标、第1类和第2类Zagreb指标、第1类和第2类反Zagreb指标）有关.此外,利用所得结果计算了开栅栏与闭栅栏的倍乘赋权Harary指标.