随机截尾的Warner与Simmons模型

本文在随机截尾模型的基础上,为了提高回答者的合作程度,提出了两种改进的调查敏感性问题数量特征的随机化回答方法。     

Wolmershäuser radicals: Chemistry and materials science

Chemistry and materials science of stable 1,3,2-benzodi-thiazolyls (Wolmershäuser radicals) are discussed. These easily-accessible chromogenic and redox-active compounds are promising building blocks of conductive and magnetic molecular materials including spin-crossover materials. Their comparison with 1,2,3-isomers (Herz radicals), also involved in contemporary materials science, is given.     

沉默策略对囚徒困境博弈合作水平的影响

研究沉默策略对囚徒困境博弈合作水平的影响.在博弈中玩家得到的利益不能达到期望值时,大部分的玩家会选择沉默来避免在博弈中的损失,在下一次的博弈中再选择有利的策略来获取更多的收益.利用矩阵的半张量积方法,建立带有沉默策略的网络化囚徒困境博弈演化的数学模型,并结合逻辑的矩阵表达,将其表示成代数形式.最后讨论博弈的最终合作水平并给出实例.     

New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2′-Bis(aminomethyl)-1,1′-binaphthyl

As a candidate for bifunctional asymmetric catalysts containing a half-sandwich C–N chelating Ir(III) framework (azairidacycle), a dinuclear Ir complex with an axially chiral linkage is newly designed. An expedient synthesis of chiral 2,2′-bis(aminomethyl)-1,1′-binaphthyl (1) from 1,1-bi-2-naphthol (BINOL) was accomplished by a three-step process involving nickel-catalyzed cyanation and subsequent reduction with Raney-Ni and KBH₄. The reaction of (S)-1 with an equimolar amount of [IrCl₂Cp*]₂ (Cp* = η⁵–C₅(CH₃)₅) in the presence of sodium acetate in acetonitrile at 80 °C gave a diastereomeric mixture of new dinuclear dichloridodiiridium complexes (5) through the double C–H bond cleavage, as confirmed by ¹H NMR spectroscopy. A loss of the central chirality on the Ir centers of 5 was demonstrated by treatment with KOC(CH₃)₃ to generate the corresponding 16e amidoiridium complex 6. The following hydrogen transfer from 2-propanol to 6 provided diastereomers of hydrido(amine)iridium retaining the bis(azairidacycle) architecture. The dinuclear chlorido(amine)iridium 5 can serve as a catalyst precursor for the asymmetric transfer hydrogenation of acetophenone with a substrate to a catalyst ratio of 200 in the presence of KOC(CH₃)₃ in 2-propanol, leading to (S)-1-phenylethanol with up to an enantiomeric excess (ee) of 67%.     

基于多维任务驱动下的物理化学实验课程探索*

设计不同维度的课程任务学习单,并将自主探究、协作交流等学习模式引入物理化学实验的实践教学,深入探讨了物理化学实验课程实施翻转课堂的教学模式的研究。整个教学环节包括:课前资源导学、课内知识拓展、课后成效评价。实践表明,翻转课堂有利于提高学生的知识内化能力、分析解决问题能力、合作交流能力以及自学能力,尤其是文献调研的能力有显著提升,该模式取得了较好的教学效果。     

System throughput maximization in IRS-assisted phase cooperative NOMA networks

This work investigates performance of system throughput in intelligent reflecting surfaces (IRSs)-enabled phase cooperative non-orthogonal multiple access (NOMA) framework. By exploiting heterogeneous cognitive radio networks concept the aim is to maximize the sum rate of secondary users in the proposed phase cooperative downlink network configuration via optimization solutions. However, the optimization problem comes out to be NP-hard and precludes direct solution. Hence, an alternating optimization is applied at the primary network to solve the maximization problem by exploiting the transmit beamforming (BF) at the power station (PS) and phase shift optimization at the IRS. Later, sum rate maximization for secondary network is performed by utilizing phase shifts of primary network via phase cooperation. In order to find global optimal solutions for active beamformers at both PSs, a branch-reduce-and-bound (BRnB) method is used whereas, passive phase shift optimization at the primary PS is performed via a simple iterative solution, i.e., the element-wise block coordinate descent method. For the proposed framework, Monte-Carlo simulations are performed where the optimality of the global solution is compared with heuristic BF methods including minimum-mean-square-error/regularized zero-forcing-beamforming (ZFBF) and ZFBF. The BRnB algorithm sets an upper performance bound by improving the sum rate of users in comparison with the conventional heuristic BF schemes. This work signifies the utilization of phase cooperation in IRS-assisted NOMA networks for a multi-user environment.     

A probabilistic model of quantum states for classical data security

The phenomenal progress of quantum information theory over the last decade has substantially broadened the potential to simulate the superposition of states for exponential speedup of quantum algorithms over their classical peers. Therefore, the conventional and modern cryptographic standards (encryption and authentication) are susceptible to Shor’s and Grover’s algorithms on quantum computers. The significant improvement in technology permits consummate levels of data protection by encoding classical data into small quantum states that can only be utilized once by leveraging the capabilities of quantum-assisted classical computations. Considering the frequent data breaches and increasingly stringent privacy legislation, we introduce a hybrid quantum-classical model to transform classical data into unclonable states, and we experimentally demonstrate perfect state transfer to exemplify the classical data. To alleviate implementation complexity, we propose an arbitrary quantum signature scheme that does not require the establishment of entangled states to authenticate users in order to transmit and receive arbitrated states to retrieve classical data. The consequences of the probabilistic model indicate that the quantum-assisted classical framework substantially enhances the performance and security of digital data, and paves the way toward real-world applications.     

Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach

The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non-innocent behaviour are being documented. Here, we provide evidence for reversible intramolecular C−H activation at one methyl terminus of C₅Me₅ in [(η-C₅Me₅)Rh(PMe₃)₂] to form a new Rh−H bond, a process so far restricted to early transition metals. Experimental evidence was acquired from bimetallic rhodium/gold structures in which the gold center binds either to the rhodium atom or to the activated Cp* ring. Reversibility of the C−H activation event regenerates the Rh^I and Au^I monometallic precursors, whose cooperative reactivity towards polar E−H bonds (E=O, N), including the N−H bonds in ammonia, can be understood in terms of bimetallic frustration.     

Hysteresis behavior and nonequilibrium phase transition in a one-dimensional evolutionary game model

We investigate a simple evolutionary game model in one dimension. It is found that the system exhibits a discontinuous phase transition from a defection state to a cooperation state when the b payoff of a defector exploiting a cooperator is small. Furthermore, if b is large enough, then the system exhibits two continuous phase transitions between two absorbing states and a coexistence state of cooperation and defection, respectively. The tri-critical point is roughly estimated. Moreover, it is found that the critical behavior of the continuous phase transition with an absorbing state is in the directed percolation universality class.     

泡沫铝率相关本构模型及其在三明治夹芯板冲击吸能特性的应用研究

高孔隙率泡沫铝芯体三明治板具有轻质、高比刚度和减振吸能等优良的力学特性和物理特性,被广泛地应用于碰撞吸能部件上.近年来,高孔隙率泡沫铝在动态压缩下是否具有应变率敏感性成为广大学者的研究焦点.论文建立了横观各向同性率相关本构模型来描述高孔隙率泡沫铝的应变率效应,给出了有限元的计算步骤,基于ABAQUS/Explicit平...