全文获取类型
收费全文 | 6649篇 |
免费 | 1059篇 |
国内免费 | 698篇 |
专业分类
化学 | 2647篇 |
晶体学 | 99篇 |
力学 | 1046篇 |
综合类 | 75篇 |
数学 | 1375篇 |
物理学 | 3164篇 |
出版年
2024年 | 10篇 |
2023年 | 52篇 |
2022年 | 124篇 |
2021年 | 117篇 |
2020年 | 177篇 |
2019年 | 211篇 |
2018年 | 197篇 |
2017年 | 269篇 |
2016年 | 323篇 |
2015年 | 364篇 |
2014年 | 358篇 |
2013年 | 513篇 |
2012年 | 375篇 |
2011年 | 438篇 |
2010年 | 312篇 |
2009年 | 389篇 |
2008年 | 388篇 |
2007年 | 406篇 |
2006年 | 396篇 |
2005年 | 339篇 |
2004年 | 292篇 |
2003年 | 315篇 |
2002年 | 301篇 |
2001年 | 252篇 |
2000年 | 255篇 |
1999年 | 231篇 |
1998年 | 199篇 |
1997年 | 148篇 |
1996年 | 127篇 |
1995年 | 97篇 |
1994年 | 67篇 |
1993年 | 48篇 |
1992年 | 62篇 |
1991年 | 38篇 |
1990年 | 30篇 |
1989年 | 27篇 |
1988年 | 21篇 |
1987年 | 12篇 |
1986年 | 19篇 |
1985年 | 25篇 |
1984年 | 20篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 16篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有8406条查询结果,搜索用时 15 毫秒
981.
Pavel Dudin Paolo Lacovig Claudio Fava Eugenio Nicolini Anna Bianco Giuseppe Cautero Alexei Barinov 《Journal of synchrotron radiation》2010,17(4):445-450
The extensive upgrade of the experimental end‐station of the SPECTROMICROSCOPY‐3.2L beamline at Elettra synchrotron light source is reported. After the upgrade, angle‐resolved photoemission spectroscopy from a submicrometre spot and scanning microscopy images monitoring the photoelectron signal inside selected acquisition angle and energy windows can be performed. As a test case, angle‐resolved photoemission spectroscopy from single flakes of highly oriented pyrolitic graphite and imaging of the flakes with image contrast owing to rotation of the band dispersion of different flakes are presented. 相似文献
982.
碰撞转动传能中存在量子干涉效应已经在静态池实验中被观测到,并且积分角也能被测量.利用分子束实验可得到转动传能更准确的信息,进而得到影响干涉角的的具体因素.文中利用一阶含时波恩近似和L-J相互作用势,建立了原子—双原子分子碰撞系统转动传能的量子干涉模型,描述了观察和测量微分干涉角的方法,得到了微分干涉角与碰撞半径和碰撞速度间的关系,同时也得到了积分干涉角和实验温度的关系.此理论模型对于理解和进行分子束实验是非常重要的. 相似文献
983.
苗刚 《原子与分子物理学报》2010,27(1)
碰撞转动传能中存在量子干涉效应已经在静态池实验中被观测到,并且积分角也能被测量。但静态池掩盖了大量的实验信息,利用分子束实验可得到转动传能更准确的信息,进而得到影响干涉角的的具体因素。文中运用含时微扰的一级波恩近似理论和各向异性相互作用势,建立了原子-双原子分子(混合态)体系碰撞诱导转动能量传递中的量子干涉效应的理论模型,描述了观察和测量微分干涉角的方法,得到了微分干涉角与碰撞半径和碰撞速度间的关系,同时也得到了实验温度对微分干涉角的影响。此理论模型对于理解和进行分子束实验是非常重要的. 相似文献
984.
An angle-resolved laser detector based on a pair of a non-mechanical scanning Fabry-Perot cavities is described. The differential signal from the two cavities is approximately independent from the polarization of the incident laser beam and it is used to determine the angle of incidence of the beam on the Fabry-Perot cavities. The F-P etalon is made of interferometric filter combination. A laser incident angle sensor experimental platform is built up, and the experiment is carried out with a given laser range finder. When the incident angle is less than 5°, the transmission difference measured by the laser angle sensor is significantly lower than theoretical value, and deviation is more than 10%. When the incident angle is greater than 10°, the deviation is much lower than that of the situation of the incident angle is lower than 10°. 相似文献
985.
Facile fabrication of a lotus-effect composite coating via wrapping silica with polyurethane 总被引:1,自引:0,他引:1
Changhong Su 《Applied Surface Science》2010,256(7):2122-1094
A lotus-effect coating was fabricated by wrapping micro-silica and nano-silica with polyurethane (PU) and subsequent spraying. The coating shows the similar self-cleaning property as lotus leaves: the contact angle is as large as 168° and the sliding angle is as low as 0.5°. Surface morphology of the coating was studied with scanning electron microscopy and atomic force microscopy. The composite coating shows the similar structure as lotus leaves. 相似文献
986.
Surface modification of porous poly(tetrafluoraethylene) film by a simple chemical oxidation treatment 总被引:1,自引:0,他引:1
A simple, inexpensive and environmental chemical treatment process, i.e., treating porous poly(tetrafluoroethylene) (PTFE) films by a mixture of potassium permanganate solution and nitric acid, was proposed to improve the hydrophilicity of PTFE. To evaluate the effectiveness of this strong oxidation treatment, contact angle measurement was performed. The effects of treatment time and temperature on the contact angle of PTFE were studied as well. The results showed that the chemical modification decreased contact angle of as-received PTFE film from 133 ± 3° to 30 ± 4° treated at 100 °C for 3 h, effectively converting the hydrophobic PTFE to a hydrophilic PTFE matrix. The changes in chemical structure, surface compositions and crystal structure of PTFE were examined by attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), environmental scanning electron microscopy (ESEM), X-ray diffraction (XRD), respectively. It was found that the F/C atomic ratio decreased from untreated 1.65-0.10 treated by the mixture at 100 °C for 3 h. Hydrophilic groups such as carbonyl (CO) and hydroxyl (OH) were introduced on the surface of PTFE after treatment. Furthermore, hydrophilic compounds K0.27MnO2·0.54H2O was absorbed on the surface of porous PTFE film. Both the introduction of hydrophilic groups and absorption of hydrophilic compounds contribute to the significantly decreased contact angle of PTFE. 相似文献
987.
A novel strong water-repellent alumina thin film is fabricated by chemically adsorbing stearic acid (STA) layer onto the porous and roughened aluminum film coated with polyethyleneimine (PEI). The formation process and the structure of the strong water-repellent alumina film are investigated by means of contact angle measurement and atomic force microscope (AFM). Results show that the water contact angles for the alumina films increase with the increase of the immersion time in the boiling water, and meanwhile, the roughness of the alumina films increases with the dissolution of the boehmite in the boiling water. Finally, the strong water-repellent film with a high water contact angle of 139.1° is obtained when the alumina films have distinct roughened morphology with some papillary peaks and porous structure. Moreover, both the roughened structure and the hydrophobic materials of the STA endow the alumina films with the strong water-repellence. 相似文献
988.
In order to enhance the compatibility with plastic polymers, magnesium hydroxide sulfate hydrate (MHSH) nanowhiskers were modified through grafting methyl methacrylate (MMA) on the surface of the nanowhiskers by emulsion polymerization. The influences of the reaction time, MMA monomer content, adding speed of monomer and the reaction temperature on the grafting ratio were investigated. Thermogravimetry (TG), Fourier transform infrared (FT-IR) spectroscopy, X-ray powder diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray (EDX) spectroscopy and surface contact angle measurement were used to characterize the effect of surface modification. The results showed that the MHSH nanowhiskers were uniformly coated by polymethyl methacrylate (PMMA), and a well-defined core-shell hybrid structure of MHSH/PMMA was obtained. The surface contact angle of the hybrid whiskers increased to 87.32° from 12.71° and the whiskers surface was changed from hydrophilic to lipophilic. 相似文献
989.
Haihong Jiang 《Applied Surface Science》2010,256(14):4559-264
Contact angles and surface energy of wood, as well as interfacial shear strength between wood and polyvinyl chloride (PVC) were investigated and used to monitor the modifications generated on the surfaces of wood treated with a copper ethanolamine solution. An increase in surface energy of wood after treatments promotes wetting of PVC on wood surfaces. Improved interfacial shear strength between treated wood and PVC matrix can be attributed to the formation of a stronger wood-PVC interphase. This suggests that treatment may be used to improve the adhesion between wood surface and PVC in the formulation of wood fiber composites to yield products with enhanced mechanical properties and better biological and physical performance against decay and insect destroying wood. 相似文献
990.
Ming-De Pei Er Li Xue-hong Zhang Xue-mei Song Hui Yan 《Applied Surface Science》2010,256(20):5824-18220
The lotus-leaf-like superhydrophobic copper was fabricated by a facile two-step method without the chemical modification, on which the water contact angle can reach 158° and the water-sliding angle is less than 10°. Reversible superhydrophobicity to superhydrophilicity transition was observed and controlled by alternation of UV irradiation and dark storage. More interestingly, the superhydrophobic surface exhibits superoleophilicity and all those properties can be well used in reversible switch, separating the water and oil and so on. 相似文献