首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   662篇
  免费   96篇
  国内免费   17篇
化学   341篇
力学   9篇
综合类   96篇
数学   292篇
物理学   37篇
  2024年   2篇
  2023年   8篇
  2022年   25篇
  2021年   28篇
  2020年   29篇
  2019年   27篇
  2018年   17篇
  2017年   39篇
  2016年   53篇
  2015年   23篇
  2014年   52篇
  2013年   54篇
  2012年   38篇
  2011年   44篇
  2010年   43篇
  2009年   51篇
  2008年   24篇
  2007年   30篇
  2006年   21篇
  2005年   25篇
  2004年   16篇
  2003年   14篇
  2002年   15篇
  2001年   16篇
  2000年   13篇
  1999年   10篇
  1998年   7篇
  1997年   2篇
  1996年   7篇
  1995年   1篇
  1994年   3篇
  1993年   2篇
  1992年   3篇
  1991年   1篇
  1990年   9篇
  1989年   5篇
  1988年   5篇
  1987年   1篇
  1986年   3篇
  1985年   1篇
  1984年   2篇
  1982年   1篇
  1979年   1篇
  1977年   1篇
  1976年   1篇
  1959年   2篇
排序方式: 共有775条查询结果,搜索用时 15 毫秒
11.
This paper presents a review of procedural steps and implementation techniques used in the development of artificial intelligence models, generally referred to as artificial neural networks (ANNs), within the water resources domain. It focusses on identifying different areas wherein ANNs have found application thereby elucidating its advantages and disadvantages as well as various challenges encountered in its use. Results from this review provide useful insights into how the performance of ANNs can be improved and potential areas of application that are yet to be explored in hydrological modeling. Recommendations for Resource Managers
  • Development of integrated and hybrid artificial intelligent tools is critical to achieving improved forecasts in hydrological modeling studies.
  • Further research into comprehending the internal mechanisms of neural networks is required to obtain a practical meaning of each network component deployed to solve real‐world problems.
  • More robust optimization techniques and tools like differential evolution, particle swarm optimization and deep neural nets, are yet to be fully explored in the water resources analysis, and should be given more attention to enhance neural networks aptitude for modeling complex and nonlinear hydrological processes.
  相似文献   
12.
This study describes an environmentally friendly and green synthetic approach for the preparation of poly(aminoethylmethacrylate)-based hydrogels crosslinked through Diels–Alder (DA) reaction in water. This “click” reaction offers the possibility of preparing chemically crosslinked hydrogels in the absence of any catalyst, initiator or coupling agent, thus preserving the biocompatibility of the material. The suitable furan diene was obtained by modifying a methacrylate polymer by its reaction with furfural, a first generation compound derived from renewable resources. Methacrylate-based complementary polymeric dienophiles were also prepared by introducing maleimide groups into the structure. The products obtained at different steps were characterized by FTIR, NMR and TGA techniques. The study of the rheological properties of the hydrogels proved the success of this green “click” synthetic strategy confirming the formation of chemically crosslinked networks by the use of the Diels–Alder reaction. Furthermore, SEM studies revealed promising morphological properties of the ensuing hydrogels in terms of biomedical applications.  相似文献   
13.
应用组合预测方法,对浙江省旅游业主要指标的统计数据建立数学模型,对旅游经济发展进行现状分析和前景预测,并探讨了旅游经济对社会经济发展的影响、研究表明所建模型具有很好的拟合精度,较好的刻画了浙江省旅游经济的发展过程,这将为研究和调控旅游经济发展趋势提供有益的参考依据.  相似文献   
14.
Starting from commonly available sugar derivatives, a single step protocol to access a small family of isohexide‐dioxalates ( 2a–c ) has been established. The synthetic competence of 2a–c has been demonstrated by subjecting them to condensation polymerization. Quite surprisingly, the proton NMR of poly(isomannide‐co‐hexane)oxalate revealed a 1:2 ratio between isomannide‐dioxalate ( 2a ) and 1,6‐hexanediol ( 3a ) in the polymer backbone. This intriguing reactivity was found to be an outcome of a cross metathesis reaction between 2a and 3a . The cross metathesis products 3a ”[2‐(2‐methoxyacetoxy)ethyl 2‐(2‐hydroxyethoxy)‐2‐(λ3‐oxydanylidene)acetate] and 2a ‘(3R,6R)‐6‐hydroxyhexahydrofuro[3,2‐b]‐furan‐3‐yl methyl oxalate were isolated in a control experiment. Based on direct and indirect evidence, and control experiments, an alternative polymerization mechanism is proposed. Polymerization conditions were optimized to obtain polyoxalates P1(2a‐3a)‐P9(2c‐3c) with molecular weights in the range of 14,000–68,000 g/mol, and narrow polydispersities. The identity of the polyoxalates was unambiguously established using 1‐2D NMR spectroscopy, MALDI‐ToF‐MS, and GPC measurements. The practical implication of these polymers is demonstrated by preparing transparent, mechanically robust films. The environmental footprint of the selected polyoxalates was investigated by subjecting them to solution and solid‐state degradation. The polyoxalates were found to be amenable to degradation. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 1584–1592  相似文献   
15.
基于1996-2013年莆田市旅游业收入与地区GDP的相关数据,研究莆田市旅游业的发展与区域经济增长的关系.考虑到这些数据是时间序列数据,首先对这些序列进行平稳性分析,然后应用协整理论和Granger因果检验进行实证研究,并且建立了误差修正模型.结果表明,莆田市旅游业的发展与区域经济增长存在着长期稳定的关系和单向的Granger因果原因,即区域经济带动旅游业的发展影响较小,而旅游业的发展促进区域经济发展的影响较明显.  相似文献   
16.
合理的油气资源税费能够引导企业优化开发决策,平衡当代与后代利益关系,实现跨期资源有效配置。从跨期油气资源最优分配的角度,通过最优控制理论构建寡头垄断市场中社会福利最大化和企业利润最大化目标下的油气资源开发决策模型,并以社会福利最大化目标下的资源开发决策为基准,研究从价、从量、储量三种不同形式的油气资源税费对资源开发决策的调节作用,研究发现:(1)征收从价税费,最优的从价税率为26.4%,政府既可以保障社会最优,还可以获得较多的税费收入;(2)征收从量税费,从量税率为1.77元/吨,政府可以保证社会福利最大化,但相比从价税费政府的税费收入较少;(3)征收储量税费,社会福利最大化下的储量税费为-0.13元/吨,也就是政府需向企业进行补贴才可以保证社会最优,会形成一定的财政压力。  相似文献   
17.
多层油资源运移聚集并行数值模拟,其功能是重建油气盆地的运移聚集演化史,对于油资源的评价,确度油藏位置,估计油藏贮量均具有重要的价值.从生产实际出发,提出数学模型,构造大规模精细并行计算的耦合算子分裂隐式迭代格式,设计了并行计算程序和并行计算的信息传递和交替方向网格剖分方法.并对不同的网格步长进行了并行计算和分析.对滩海地区进行精细数值模拟,计算结果在油田位置等方面和实际情况相吻合.对模型问题(非线型性耦合问题)进行数值分析,得到最佳阶L2误差估计,解决了这一计算渗流力学和石油地质的困难问题.  相似文献   
18.
The purpose of this paper is to learn from Complex Adaptive Systems (CAS) theory to inform the development of Problem Structuring Methods (PSMs) both in general and in the specific context of marine management. The focus on marine management is important because it is concerned with a CAS (formed through the interconnection between natural systems, designed systems and social systems) which exemplifies their particularly ‘wicked’ nature. Recognition of this compels us to take seriously the need to develop tools for knowledge elicitation and structuring which meet the demands of CAS. In marine management, chief among those tools is the DPSIR (Drivers – Pressures – State Changes – Impacts – Responses) model and, although widely applied, the extent to which it is appropriate for dealing with the demands of a CAS is questionable. Such questioning is particularly pertinent in the context of the marine environment where there is a need to not only recognise a broad range of stakeholders (a question of boundary critique) but also to manage competing knowledge (economic, local and scientific) and value claims. Hence this paper emphasises how a CAS perspective might add impetus to the development of a critical perspective on DPSIR and PSM theory and practice to promote a more systemic view of decision-making and policy development.  相似文献   
19.
基于图像学理论进一步阐释了旅游目的地形象的内涵和形成过程,提出了旅游目的地形象清晰度概念,以及形象清晰度测评指标体系,并以老牌旅游城市西安为案例地,对不同群体旅游者心目中的西安旅游形象清晰度进行了测评.研究表明:(1)旅游目的地形象是旅游者通过视觉、听觉等感觉器官,主动或被动地接收旅游目的地各种旅游信息,并在大脑已有的认知水平下,对所获取的旅游信息进行组合、拼接以及评价形成的目的地心理认知“图像”.(2)旅游者个体之间和群体之间均存在目的地形象清晰度差异.旅游者了解目的地的信息类型越多样、内容越丰富,目的地形象清晰度越高.反之,则清晰度越低.旅游目的地形象清晰度可划分为要素清晰度、维度清晰度和整体清晰度3种类型.(3)旅游目的地形象清晰度与O-D对距离有关.(4)旅游目的地形象清晰度可以用旅游目的地形象描述词汇的频率、多样性指数及词汇网络中心性指标等进行测评.  相似文献   
20.
An amphiphilic biodegradable polymer, poly(aspartic acid‐co‐lactic acid) (PAL), was synthesized by simply heating a mixture of aspartic acid (Asp) and L ‐lactide without additional catalysts or solvents. The unique branched architecture comprising succinimide units and lactic acid units was confirmed by IR and NMR spectroscopy. A copolymer of sodium aspartate and lactic acid (PALNa) was prepared by reacting PAL with an aqueous sodium hydroxide solution. The PAL was soluble in many organic solvents, while the PALNa was soluble in methanol and water. The hydrolytic degradation behavior of PAL varied with the copolymer composition. A higher Asp content resulted in a faster molecular weight decrease, and introducing glycolic acid units accelerated the degradation rate.

Microphotograph of microsphere of PAL‐1/5.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号