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91.
A completely automated flow-injection system was developed for the monitoring of biosorption studies of Cu(II) ion on vegetable waste by-products. The system employed flow-through Cu(II)-selective electrodes, of epoxy-resin-CuS/Ag2S heterogeneous crystalline type, and computer controlled pumps and valves for the flow operation. Computer automation was done through a specially devised virtual instrument, which commanded and periodically calibrated the system, allowing for the monitoring of Cu(II) ions between 0.6 and 6530 mg L−1 at a typical frequency of 15 h−1. Grape stalk wastes were used as biosorbent to remove Cu(II) ions in a fixed-bed column with a sorption capacity of 5.46 mg g−1, obtained by the developed flow system, while the reference determination performed by FAAS technique supplied a comparable value of 5.41 mg g−1. 相似文献
92.
《Journal of Polymer Science.Polymer Physics》2018,56(4):288-296
Although gas sorption in glassy polymers is a well‐studied phenomenon, no general microscopical model is developed which is able to describe the gas sorption in a wide temperature range using only characteristics of polymer and gas molecule. In this work, sorption isotherms and desorption kinetics of O2, Ar, and N2 for glassy poly(ethyl methacrylate) have been measured in the temperature range from 160 to 308 K. To describe both the phenomena, the model is developed which postulates that, in the frozen structure of glassy polymer, any cavities between macromolecules are the sorption sites for small molecules. The cavities of small size can expand elastically to accommodate a gas molecule. The sorption sites are considered to be the potential wells and their depths are distributed according to Gaussian law. The concentration of sorption sites, their mean depth and depths dispersion, and the frequency of molecules oscillations in the sorption sites are the only parameters which determine both the gas transport and sorption. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018 , 56, 288–296 相似文献
93.
S. I. Pechenyuk 《Russian Chemical Bulletin》1999,48(6):1017-1023
The modern theoretical views on the point of zero charge of the oxide hydroxide surface are considered. Methods for determination
of the pH of the point of zero charge and the use of this value to characterize the properties of oxide hydroxides are described.
Examples of using the pH of the point of zero charge in studies of oxide anodes and amorphous oxide hydroxide sorbents are
presented.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1029–1035, June, 1999. 相似文献
94.
The insect population in grain stores can be kept under control by maintaining a high concentration of CO2 gas (greater than 35%) throughout the grain bed. In this paper the initial phase of this process is considered, where the gas is introduced into the bed. The flow of CO2 through the grain bulk is modelled as fluid flow in a porous medium and the effect of advection, dispersion, sorption and curvilinear isobars and streamlines are considered. An analytic solution to this problem is developed using perturbation expansions and the analysis is restricted to the dominant term in each expansion. In curvilinear flow, a useful variable is the traverse time; the time taken for the gas to travel from the inlet duct. It is shown that lines of constant traverse time are also lines of constant CO2 concentration throughout the grain bed except in the narrow region called the front, where the concentration gradient is large. For most grain stores the isobars have a negative curvature and in these situations the front moves more slowly than in uniform flow and the width of the front increases more rapidly as it travels through the grain bed. It is shown that sorption has an effect on the CO2 concentration in the air for some grains such as canola but not for others such as wheat. 相似文献
95.
Sara Pintado Mercedes Ruiz Montoya José Miguel Rodríguez Mellado 《Comptes Rendus Chimie》2011,14(10):957-962
From UV-visible measurements and potentiometric titrations it follows that the lowest pK values (pK1) of imidazolinone herbicides correspond to the simultaneous protonation/dissociation equilibria of both the pyridinic (or quinolinic) nitrogen and the carboxyl group, the following pK (pK2) to the imminium nitrogen and the basic pK (pK3) to the dissociation of the imido nitrogen. Below pH 6 and down to pH c.a. 2.5, the dominant form of the herbicide is a double ion having both positive and negative charges, this being important in discussing the effect of pH in the natural dynamics of imidazolinone herbicides, especially in their soil sorption. Electrochemical studies of the reduction of the herbicides were made on mercury and carbon electrodes in strongly acidic media (0.1 to 2.7 M H2SO4) as well up to pH 7. The reduction signals were all attributed to the reduction of the imidazolinone ring except the second peak/wave that was found to have originated by the reduction of the pyridine/quinoline ring. A signal observed in strongly acidic media and at highly negative overpotentials was attributed to the reduction of the imidazolinone ring of the product of the previous reduction in a process consisting of two reversible electron transfers followed by a protonation reaction. 相似文献
96.
97.
Karen L. Mulfort Omar K. Farha Dr. Christos D. Malliakas Dr. Mercouri G. Kanatzidis Prof. Joseph T. Hupp Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(1):276-281
A new, twofold interpenetrated metal–organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X‐ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other. 相似文献
98.
Robens E. Keller J. U. Massen C. H. Staudt R. 《Journal of Thermal Analysis and Calorimetry》1999,55(2):383-387
In sorption measurements, volumetric or gravimetric procedures are commonly used to determine the amount adsorbed. At low
pressures, thermomolecular flow and pressure differences according to Knudsen's law disturb measurements. In volumetry, calibration
of the dead space is required; in gravimetry, the influence of buoyancy has to be taken into account. In both cases, adsorption
of the calibrating gas, usually helium, may disturb the measurements [1]. From the calibration measurements, the density of
the sample can in principle be calculated. However, it has been observed in many experiments that its value depends on the
calibrating gas.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
99.
G. N. Dalimova 《Chemistry of Natural Compounds》2006,42(4):479-482
The ability to form intermolecular coordination of lignin macromolecules and metal ions through both ionic and coordinative
metal—ligand bonds was shown by studying the sorption activity of hydrolyzed lignin from cotton seed husks (HLCSH) and its
aminated derivatives. The studied lignins exhibited high sorption activity for metal ions over the whole range of concentrations
used. The heavy-metal ions fell in the following order of decreasing lignin sorption activity: Fe > Pb > Cu > Cd > Zn.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 386–388, July–August, 2006. 相似文献
100.
Y. S. Hu R. Y. F. Liu M. Rogunova D. A. Schiraldi S. Nazarenko A. Hiltner E. Baer 《Journal of Polymer Science.Polymer Physics》2002,40(22):2489-2503
This study examined the oxygen‐transport properties of poly(ethylene terephthalate‐co‐bibenzoate) (PETBB55) crystallized from the melt (melt crystallization) or quenched to glass and subsequently isothermally crystallized by heating above the glass‐transition temperature (cold crystallization). The gauche–trans conformation of the glycol linkage was determined by infrared analysis, and the crystalline morphology was examined by atomic force microscopy. Oxygen solubility decreased linearly with volume fraction crystallinity. For melt‐crystallized PETBB55, extrapolation to zero solubility corresponded to an impermeable crystal with 100% trans glycol conformations, a density of 1.396 g cm?3, and a heat of melting of 83 J g?1. From the melt, PETBB55 crystallized as space‐filling spherulites with loosely organized lamellae and pronounced secondary crystallization. The morphological observations provided a structural model for permeability consisting of impermeable platelets randomly dispersed in a permeable matrix. In contrast, cold‐crystallized PETBB55 retained the granular texture of the quenched polymer despite the high level of crystallinity, as measured by the density and heat of melting. Oxygen solubility decreased linearly with volume fraction crystallinity, but zero solubility corresponded to an impermeable defective crystal with a trans fraction of 0.83 and a density of 1.381 g cm?3. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2489–2503, 2002 相似文献