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21.
Ross W. Mair David G. Cory Sharon Peled Ching-Hua Tseng Samuel Patz Ronald L. Walsworth 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,135(2):478-486
Pulsed-field-gradient NMR techniques are demonstrated for measurements of time-dependent gas diffusion. The standard PGSE technique and variants, applied to a free gas mixture of thermally polarized xenon and O2, are found to provide a reproducible measure of the xenon diffusion coefficient (5.71 × 10−6m2s−1for 1 atm of pure xenon), in excellent agreement with previous, non-NMR measurements. The utility of pulsed-field-gradient NMR techniques is demonstrated by the first measurement of time-dependent (i.e., restricted) gas diffusion inside a porous medium (a random pack of glass beads), with results that agree well with theory. Two modified NMR pulse sequences derived from the PGSE technique (named the Pulsed Gradient Echo, or PGE, and the Pulsed Gradient Multiple Spin Echo, or PGMSE) are also applied to measurements of time dependent diffusion of laser polarized xenon gas, with results in good agreement with previous measurements on thermally polarized gas. The PGMSE technique is found to be superior to the PGE method, and to standard PGSE techniques and variants, for efficiently measuring laser polarized noble gas diffusion over a wide range of diffusion times. 相似文献
22.
A study of body waves in fractured porous media saturated by two fluids is presented. We show the existence of four compressional and one rotational waves. The first and third compressional waves are analogous to the fast and slow compressional waves in Biot's theory. The second compressional wave arises because of fractures, whereas the fourth compressional wave is associated with the pressure difference between the fluid phases in the porous blocks. The effects of fractures on the phase velocity and attenuation coefficient of body waves are numerically investigated for a fractured sandstone saturated by air and water phases. All compressional waves except the first compressional wave are diffusive-type waves, i.e., highly attenuated and do not exist at low frequencies.Now at Izmir Institute of Technology, Faculty of Engineering, Gaziosmanpasa Bulvari, No.16, Cankaya, Izmir, Turkey. 相似文献
23.
24.
Arakawa R Shimomae Y Morikawa H Ohara K Okuno S 《Journal of mass spectrometry : JMS》2004,39(8):961-965
A low molecular mass polyester was analyzed by desorption/ionization on porous silicon (DIOS) mass spectrometry. The results were compared with those of matrix-assisted laser desorption ionization (MALDI) mass spectrometry using matrixes of alpha-cyano-4-hydroxycinnamic acid (CHCA) and 10,15,20-tetrakis(pentafluorophenyl)porphyrin (F20TPP). The CHCA matrix was not suitable for characterization of low molecular mass components of the polyester because the matrix-related ions interfered with the component ions. On the other hand, the F20TPP matrix showed no interference because no matrix-related ions appeared below m/z 822. However, the solvent selection for determining optimal conditions of sample preparation was limited, because F20TPP does not dissolve readily in any of the available organic solvents. In the DIOS spectra, the polymer ions were observed at high sensitivity without a contaminating ion. No matrix is needed for DIOS spectra of low molecular mass polyesters, facilitating sample preparation and selectivity of a precursor ion in post-source decay measurements. 相似文献
25.
Summary The paper deals with the use of controlled-porosity glasses (CPGs) as adsorbents for HPLC. The physicochemical and chromatographic properties of small-pore CPGs are compared to the analogous properties of silica gels. The results show good correlation between them and suggest the possibility of application of CPGs as adsorbents for liquid chromatography. 相似文献
26.
Raoul Kopelman 《Journal of statistical physics》1986,42(1-2):185-200
Heterogeneous kinetics are shown to differ drastically from homogeneous kinetics. For the elementary reaction A + A products we show that the diffusion-limited reaction rate is proportional tot
– h[A]2 or to [A]x, whereh=1- d
s/2, X=1+2/d
s
=(h-2)(h-1), andd
s
is the effective spectral dimension. We note that ford = d
s
=1, h =1/2 andX = 3, for percolating clustersd
s = 4/3,h = 1/3 andX = 5/2, while for dust ds <1, 1 >h > 1/2 and >X > 3. Scaling arguments, supercomputer simulations and experiments give a consistent picture. The interplay of energetic and geometric heterogeneity results in fractal-like kinetics and is relevant to excitation fusion experiments in porous membranes, films, and polymeric glasses. However, in isotopic mixed crystals, the geometric fractal nature (percolation clusters) dominates. 相似文献
27.
0引言一直以来,钙磷生物材料如羟基磷灰石(hy-droxyapatite,HA)由于其成份与骨的无机成份相似,具有良好的生物相容性,作为骨修复材料引起了人们广泛的兴趣。磷酸钙骨水泥是一类可在生理条件下自固化的非陶瓷型类HA人工骨材料,这种由磷酸钙骨水泥(calcium phosphate cement,CPC)转变而成的HA,与天然骨磷灰石有类似的组成结构,植入人体后可参与新陈代谢,促进骨组织生长[1,2]。一些研究显示,CPC具有成骨活性和生物降解性,在体内被吸收的同时可引导新骨的生成,从而可克服自体骨、磷酸三钙陶瓷因吸收降解过快造成的局部缺陷以及陶瓷型HA长… 相似文献
28.
以互通多孔碳(IPC)为载体,水热条件下在碳表面原位反应生成纳米结构的二氧化锰(MnO2),制备互通多孔碳/二氧化锰纳米(IPC/MnO2)复合电极材料. 采用扫描电镜(SEM),透射电镜(TEM),X射线衍射(XRD),热重分析(TGA)对其结构进行表征;采用循环伏安法、恒流充放电和交流阻抗对其电化学性能进行研究. 结果表明:生成的MnO2均匀地负载在碳的表面,形成多层次结构,并且随着温度的升高IPC表面负载的MnO2由纳米颗粒变为纳米片状结构;MnO2纳米片具有典型的K-Birnessite 型晶体结构;复合物中MnO2的含量约为34%(w). 在100 ℃制备的IPC/MnO2复合材料在三电极系统中最高比电容达到了411 F·g-1;随着反应温度的升高,比容量先增长后基本保持不变. 以IPC/MnO2为正极,活性炭(AC)为负极,1 mol·L-1 Na2SO4溶液为电解液组装成IPC/MnO2//AC 混合超级电容器,发现IPC/MnO2电极的电容器其电位窗口从1 V扩展到1.8 V,容量可达86F·g-1,且表现出良好的电容特性和大电流放电性能. 相似文献
29.
A need for an elaboration of the methods for synthesis and characterization of activated carbons with a requisite porous structure has existed for a long time. One of the methods giving possibility for creating controlled mesopore and micropore structures deals with the steam gasification of various carbon materials. In this work the effects of calcium catalyst on the catalytic steam gasification of active carbons from plum stones and porous polymers are presented. Determination of micropores capacity and specific adsorption in mesopores have been performed by means of the
s
method, but adsorption on the heterogeneous solids was described by the integral equation with various local isotherms. This equation has been solved by the regularization method. Based on this method the changes in structural parameters of active carbons depending on the amount of calcium catalyst were estimated.Nomenclature
d
width of slit-like micropore
-
F(x)
distribution function of the half-width
-
p
vapor pressure of sorbate
-
p/p
N
relative pressure
- PSAC
Plum Stone Active Carbon
-
average pore radius, nm
-
S
1
relative limit of the validity of experimental point on the adsorption isotherm in the computations by means of regularization method
- SAC
Synthetic Active Carbon
-
S
BET
specific surface area calculated by means of BET method, m2/g
-
S
mes
mesopore surface area, m2/g
-
S
mic
micropore surface area, m2/g
-
T
absolute temperature, K
-
V
mes
sorption capacity of mesopores, cm3/g
-
V
mic
sorption capacity of micropores, cm3/g
-
V
p
sorption capacity of pores, cm3/g
- w/w
weight in weight concentration
-
x
half-width of slit-like micropore, nm
-
x
1
maximum of half-width of micropore slit, nm
-
average half-width of slit-like micropore, nm
-
X
min-X
max
integration limits of thex
Greek Letters Greek Letters
variance of average half-width of slit-like micropore, nm2
-
local relative filling of micropores
-
total relative filling of micropores 相似文献
30.
The nano-ZnFe2O4/TiO2 films possess the functions of desulfurization and degradation for organic pollutants. The sols of ZnFe2O4/TiO2 were prepared by sol-gel method and coated on glass and porous ceramic by vertical coating and dipping-lift processes, respectively, and the samples were obtained after drying and sintering. The composition, appearance, absorption spectrum of the films, and the influence of the film on porous ceramic performances were analyzed using SEM, AFM, UV-Vis spectrometer, and mercury porosimeter, respectively, to determine the operation parameters of the multifunction porous ceramic elements for gas-purification. 相似文献