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31.
Free induction decay (FID) signals in solid state NMR measurements performed with magic angle spinning can often be extended in time by factors on the order of 10 by a simple pulsed spin locking technique. The sensitivity of a structural measurement in which the structural information is contained in the dependence of the integrated FID amplitude on a preceding evolution period can therefore be enhanced substantially by pulsed spin locking in the signal detection period. We demonstrate sensitivity enhancements in a variety of solid state NMR techniques that are applicable to selectively isotopically labeled samples, including 13C-15N rotational echo double resonance (REDOR), 13C-13C dipolar recoupling measurements using the constant-time finite-pulse radio-frequency-driven recoupling (fpRFDR-CT) and constant-time double-quantum-filtered dipolar recoupling (CTDQFD) techniques, and torsion angle measurements using the double quantum chemical shift anisotropy (DQCSA) technique. Further, we demonstrate that the structural information in the solid state NMR data is not distorted by pulsed spin locking in the detection period. 相似文献
32.
Sameer Bargir Steve Dunn Bruce Jefferson Simon Parsons 《Applied Surface Science》2009,255(9):4873-4879
We have studied a series of solids using contact angle measurements; stainless steel, gold, aluminium, titanium nitride and PTFE that are frequently used in domestic water environments. It was found the influence of electron-donor (γ−) and electron-acceptor (γ+) free energies on material scaling rate was dominated by water wetting angles, providing materials exhibit an average roughness below 100 nm. The γ− component had the greatest influence on theoretical adhesion, while γLW, (Lifshitz-van der Waals) γ+ and γAB (acid-base) had little effect. From the materials analysed, amorphous carbon coatings were least adhesive, while ‘kettle coating’ and highly roughened steel the most adhesive. The size and distribution of asperities also influenced the polar free energies and subsequent adhesion due to fluctuations in the wetting angle. The results obtained indicate works of adhesion can be used as a complementary technique with Lewis acid-base theory to deliver useful information about the propensity of scale to deposit on solids. 相似文献
33.
Titanium dioxide (TiO2) films were fabricated on fluorine doped tin oxide (FTO) coated glass substrate using successive ionic layer adsorption and reaction (SILAR) method. The X-ray diffraction, scanning electron microscopy, transmission electron microscopy, optical absorption and contact angle measurement were applied to study the structural, surface morphological, optical and surface wettability properties of the as-deposited and annealed TiO2 films. The X-ray diffraction studies revealed both as-deposited and annealed TiO2 films are amorphous. Irregular shaped spherical grains of random size and well covered to the fluorine doped tin oxide coated glass substrates were observed from SEM studies with some cracks after annealing. The optical band gap values of virgin TiO2, annealed, methyl violet and rose bengal sensitized TiO2 were found to be 3.6, 3.5, 2.87 and 2.95 eV, respectively. Surface wettability studied in contact with liquid interface, showed hydrophobic nature as water contact angles were greater than 90°. The adsorption of dyes, as confirmed by the photographs, is one of the prime requirements for dye sensitized solar cells (DSSC). 相似文献
34.
本文利用平面角的概念讨论了均匀带电的直线微元和圆弧微元在圆心处的场强等价性,并将结论推广到一些均匀带电的线几何体;然后利用立体角的概念进一步讨论带电的平面微元和球面微元在球心处的场强等价关系,结果表明,只有非均匀的电荷面密度才能使两者等价. 相似文献
35.
We fabricate 2D–3D photonic crystal heterostructures based on the silicon [001]-diamond:1 square spiral geometry using glancing angle deposition. We compare the normal incidence reflection properties of the fabricated 2D–3D heterostructures to simulated spectra generated using finite-difference time-domain calculations. Reflection peaks are observed, resulting from the presence of a photonic band gap, and defect modes are created by the 2D layer. Deterioration of the reflectance peaks with increased number of vertical spiral periods is observed. A series of square spiral structures are fabricated with a varying number of vertical periods to quantify the degradation of reflection peaks. At normal light incidence, a maximum reflection peak is observed from the film with three vertical periods. Beyond three spiral rotations, deterioration of the substrate-plane periodicity causes scattering losses. 相似文献
36.
In this paper, we investigate the Berry phase and Hannay’s angle in the Born–Oppenheimer (BO) hybrid systems and obtain their algebraic expressions in terms of one form connection. The semiclassical relation of Berry phase and Hannay’s angle is discussed. We find that, besides the usual connection term, the Berry phase of quantum BO composite system also contains a novel term brought forth by the coupling induced effective gauge potential. This quantum modification can be viewed as an effective Aharonov–Bohm effect. Moreover, the similar phenomenon is founded in Hannay’s angle of classical BO composite system, which indicates that the Berry phase and Hannay’s angle possess the same relation as the usual one. An example is used to illustrate our theory. This scheme can be used to generate artificial gauge potentials for neutral atoms. Besides, the quantum–classical hybrid BO system is also studied to compare with the results in full quantum and full classical composite systems. 相似文献
37.
重金属铅离子胁迫下玉米叶片光谱弱差信息的DSAT甄别模型 总被引:2,自引:0,他引:2
光谱间微弱信息测度是当今高光谱遥感研究难点之一,传统光谱测度方法难以区分光谱信息的微弱差异。研究设计了不同浓度的铅(Pb)污染实验,并测量了不同浓度铅离子(Pb2+)胁迫下玉米叶片的高光谱反射率、叶绿素含量及Pb2+含量,但是从所测结果得出,不同浓度Pb2+胁迫下的光谱相似性相关系数均达到0.999,难以区分不同浓度Pb2+胁迫引发的光谱间微弱信息差异和污染程度。针对这一情况,基于光谱微分处理、正切函数增强、光谱角量度与波谱分段检测等,提出了一种新型的相似光谱测度方法,即微分光谱角正切(derivative spectral angle tangent,DSAT)法。为了验证DSAT在区分相关系数达0.99以上相似光谱的可行性和有效性,将DSAT用于不同浓度Pb2+胁迫玉米叶片的整体波形与光谱区间子波形的信息差异性度量与检测。实验结果得到,波形差异信息与玉米叶片中叶绿素相对浓度与Pb2+含量显著相关。进而也证明DSAT法在甄别较高相似性光谱间差异上具有更好的实用性和优越性。 相似文献
38.
Liangxia WAN 《Frontiers of Mathematics in China》2023,18(1):1
The alternating links give a classical class of links. They play an important role in Knot Theory. Ozsváth and Szabó introduced a quasi-alternating link which is a generalization of an alternating link. In this paper we review some results of alternating links and quasi-alternating links on the Jones polynomial and the Khovanov homology. Moreover, we introduce a long pass link. Several problems worthy of further study are provided. 相似文献
39.
根据位错的弹性理论,建立了9Ni钢中53°掺杂小角度晶界的原子模型,利用Recursion方法,计算了杂质在53°小角度晶界典型环境中的能量和电子结构,由此得出,钢中小角度晶界的强度敏感地依赖于隔离杂质的类型,S,P杂质使晶粒间结合减弱,从而导致晶界疏松 ;相反,B,C,N则会使晶界间的结合加强.在所有的杂质中,B显示出独特的性质,在钢中B 不仅能增强晶界的结合,而且由于占位竞争效应会使其他杂质远离晶界,具有净化晶界的作用.
关键词:
小角晶界
杂质
占位竞争
晶界隔离 相似文献
40.
对单摆运动进行了讨论。通过对单摆进行能量分析,得出了单摆角频率与角度的关系式,然后运用微元法,推导出了单摆的理论周期公式。计算结果表明,所得到的单摆运动周期的理论公式与展开公式符合得很好。 相似文献