Structural studies on banana oil,isoamyl acetate,by means of microwave spectroscopy and quantum chemical calculations

The rotational spectrum of isoamyl acetate, H₃C–COO–(CH₂)₂–CH(CH₃)₂, has been recorded and assigned using a molecular beam Fourier transform microwave (MB-FTMW) spectrometer in the frequency range of 3–26.5?GHz. One conformer has been observed. By comparing the spectroscopic data with the quantum chemical data, it was found that the conformer observed does not have C_s symmetry. The rotational and centrifugal distortion constants were determined. The barrier to internal rotation of the acetate methyl group was found to be 93.98?cm^?1. Due to the high number of the conformers, a systematic nomenclature will be presented.     

波导管中微波波长测量方法的研究

基于微波测量线中驻波分布公式,采用测量驻波强度沿着 x轴分布的数据,拟合得到了波导管中微波的波长,不仅误差得到减小,而且可以绕过驻波比测量,用拟合参量计算微波反射率。     

Use of Microwave Maceration in Red Winemaking: Effect on Fermentation and Chemical Composition of Red Wines

The objective of this study was to evaluate the effect of microwave treatment of crushed grapes on the yeast population of the must and on the development of alcoholic fermentation, as well as on the extraction of different compounds from the grapes such as polysaccharides and amino acids that can affect the organoleptic quality and stability of the wine. This study demonstrated for the first time the effect of the microwave treatment of grapes on native yeast species and their diversity, producing an increase in fermentation kinetics and a decrease in the lag phase. The microwave treatment produced a positive effect on the extraction of amino acids and polysaccharides from the grapes, resulting in significantly higher amounts of the main amino acids of the must and some major volatile compounds in the treated samples. The polysaccharides most affected by the microwave treatment were the PRAGs, the main polysaccharides liberated from grapes during the maceration.     

微波放电解离氯分子解离效率的测量

以Cl/Cl2/HN3/He为基础的NCl(a1Δ)/I作为一种化学激光新的体系,氯原子产生的多少对该体系的研究是至关重要的。利用滴定法研究了微波解离氯分子的解离效率。用HN3/He滴定Cl,由光学多通道分析仪监测NCl(a1Δ)和NCl(b1Σ)辐射的荧光。发现微波解离氯分子的效率并不是想象的那样低,在较小的氯流量下,最高的解离效率可以达到100％。     

预脉冲对相对论磁控管工作性能的影响分析

在阐述预脉冲产生的基础上,分析了预脉冲带来的一系列影响,包括工和电压波形变化,提前生成等离子体,以及预脉冲阶段放大竞争模式等,这些影响与相对论磁控管起振工作频率相联系,从而直接造成了相对论磁控管的基本性能参数,如脉宽、工作频率及输出功率等变化。结合具体实验,对比了有、无预脉冲条件下相对论磁控管工作性能的差异,对预脉冲的影响因素与相对论磁控管性能之间的联系进行了详细的分析。     

阵列馈源偏置抛物面天线合成高功率微波的研究

 运用物理光学分析方法，对使用7单元的扇形喇叭一维阵列和角锥喇叭或圆锥喇叭三角形阵列喇叭束作为单偏置抛物面天线的馈源，空间合成高功率微波进行了比较研究，数值分析表明在阵元输入功率、口面最大场强、天线口径、净空间及天线边缘照度相同,且阵列馈源具有准轴对称主瓣条件下，扇形喇叭构成的一维阵列馈源与单偏置抛物面组成的天线系统的方向性系数和溢出效率优于采用角锥喇叭三角形阵列馈源或圆锥喇叭三角形阵列馈源的天线系统。若将喇叭束直接作为辐射天线使用，由于圆锥喇叭三角形阵列方向性系数对阵元间相位波动的稳定性较好，而更具优势。     

X波段新型低阻抗高功率微波源的模拟研究

提出了一种新型低阻抗高功率微波源,能在单个器件内产生两束锁相的相干高功率微波,对两束相干微波进行功率合成有望在单个高功率微波器件中实现更高的功率输出.粒子模拟结果显示,在电压687 k V、磁场0.8 T时,该微波源整体阻抗36?,两束微波的频率都为9.72 GHz,输出功率分别为1.20 GW和2.58 GW,功率效率分别为28%和30%;两束输出微波之间频率抖动小于±3 MHz,相位差抖动小于±3?.     

高功率微波高斯馈源口面场分析

 用波导本征模展开方法对用于高功率微波发射系统的方角锥高斯馈源口面场进行分析，提出结合馈源远场辐射特性和避免高功率击穿折衷选定相应的高斯模注腰半径，进而确定多个波导模幅值，从而为运用模匹配或耦合波理论设计高斯馈源提供依据。     

Determination of Cadmium in Plant Tissues by Electrothermal Atomisation Atomic Absorption Spectrometry with Matrix/Analyte Modification and Smith-Hieftje Background Correction

Abstract

Pressure decomposition in a microwave oven provides a rapid means of sample preparation for plant tissue analyses. The use of delayed atomisation cuvettes, Smith-Hieftje background correction and matrix/analyte modification enables accurate determinations of cadmium concentrations in plant materials to be made. However, care should be taken to restrict the concentrations of modifier used, as too high a concentration may lead to problems with both tube life and over-correction by the Smith-Hieftje background correction system.     

微波吸收法研究Mn,Cu掺杂对ZnS:Mn,Cu光生载流子复合过程的影响

采用微波吸收法，测量了ZnS:Mn,Cu粉末材料受到超短脉冲激光激发后，其光生电子和浅束缚态电子的衰减过程.发现Mn,Cu的浓度对导带电子的寿命有明显的影响，提高掺杂浓度会使光生电子的寿命大大缩短，还研究了掺杂浓度对光致发光强度的影响. 关键词： 发光材料 硫化锌 光电子 微波吸收技术