Study on patterns and chemical features of NO effect on marine phytoplankton growth

With supernatural bioactivation, nitric oxide (NO), which was first regarded as an endothelium- derived relaxing factor, was recognized by Science as the “Molecule of the Year” in 1992. The Nobel Prize of Physiology & Medicine in 1998 was awarded jointly to Furchgatt, Ignarro, and Murad for their discoveries concerning the NO effects in the cardiovascular sys- tem. From then on, researchers have paid more and more attention to the special and diverse functions of NO in organism[1―18].…     

Characteristics of selenium in australian marine biota

The occurrence, distribution and speciation of selenium in Australian marine biota is discussed. Biochemical pathways for the accumulation of selenium by marine organisms are also postulated. Comparison of the levels of selenium in macroalgae, fish, crustaceans and molluscs indicates that preferential accumulation of selenium by particular taxa does not occur. Phaeophyta have significantly lower selenium concentrations than Rhodophyta and Chlorophyta. Fish have lower selenium contents in muscle tissues than molluscs and crustaceans. Marine animals with different dietary intake (planktonic vs herbivorous vs carnivorous) are not observed to have significantly different levels of selenium (P>0.05). Selenium in all the organisms studied was predominantly associated with free amino-acids or protein residues and was not present as characterizable inorganic selenium species (SeO₃^2?, SeO₄^2?). These results indicate that selenium is probably only incorporated into biota for specific biochemical purposes with any exces selenium being excreted or eliminated.     

The chemical form and acute toxicity of arsenic compounds in marine organisms

A method for the separation and identification of inorganic and methylated arsenic compounds in marine organisms was constructed by using a hydride generation/cold trap/gas chromatography mass spectrometry (HG/CT/GC MS) measurement system. The chemical form of arsenic compounds in marine organisms was examined by the HG/CT/GC MS system after alkaline digestion. It was observed that trimethylarsenic compounds were distributed mainly in the water-soluble fraction of muscle of carnivorous gastropods, crustaceans and fish. Also, dimethylated arsenic compounds were distributed in the water-soluble fraction of Phaeophyceae. It is thought that most of the trimethylated arsenic is likely to be arsenobetaine since this compound released trimethylarsine by alkaline digestion and subsequent reduction with sodium borohydride. The major arsenic compound isolated from the water-soluble fraction in the muscle and liver of sharks was identified as arsenobetaine from IR, FAB Ms data, NMR spectra and TLC behaviour. The acute toxicity of arsenobetaine was studied in male mice. The LD₅₀ value was higher than 10 g kg⁻¹. This compound was found in urine in the non-metabolized form. No particular toxic symptoms were observed following administration. These results suggest that arsenobetaine has low toxicity and is not metabolized in mice. The LD₅₀ values of other minor arsenicals in marine organisms, trimethylarsine oxide, arsenocholine and tetramethylarsonium salt, were also examined in mice.     

Formation of Amphiphilic Molecules from the Most Common Marine Polysaccharides,toward a Sustainable Alternative?

Marine polysaccharides are part of the huge seaweeds resources and present many applications for several industries. In order to widen their potential as additives or bioactive compounds, some structural modifications have been studied. Among them, simple hydrophobization reactions have been developed in order to yield to grafted polysaccharides bearing acyl-, aryl-, alkyl-, and alkenyl-groups or fatty acid chains. The resulting polymers are able to present modified physicochemical and/or biological properties of interest in the current pharmaceutical, cosmetics, or food fields. This review covers the chemical structures of the main marine polysaccharides, and then focuses on their structural modifications, and especially on hydrophobization reactions mainly esterification, acylation, alkylation, amidation, or even cross-linking reaction on native hydroxyl-, amine, or carboxylic acid functions. Finally, the question of the necessary requirement for more sustainable processes around these structural modulations of marine polysaccharides is addressed, considering the development of greener technologies applied to traditional polysaccharides.     

Decay and nonexistence of global solutions of a quasilinear riser equation

We study qualitative properties of a quasilinear wave equation of fourth order that models the mechanical vibrations of a marine riser. Our analysis characterizes global and nonglobal solutions with respect to the norm of some Hilbert space, if energy is strictly less than the potential well depth. We employ invariant sets to show our results. In particular, we show that globality implies exponential decay to zero, and nonglobality is due to blow up. Both results are shown with respect to the norm of the solution in the Hilbert space. Copyright © 2009 John Wiley & Sons, Ltd.     

用改进的传输线算法计算水平层状横向同性地层中海洋可控源电磁响应

利用二维Fourier变换与电磁场分解技术将层状横向同性地层中Maxwell方程转化成两个独立的关于横磁(TM)波和横电(TE)波的传输线方程; 借助传输线理论与叠加原理, 仅利用电流源传输线Green函数得到TM波和TE波的解, 改进传输线算法, 建立横向同性地层中频率-波数域电流源电场和磁场并矢Green函数的新算法与新的解析表达式, 提高海洋可控源电磁响应数值模拟效率. 在此基础上, 利用传输线Green函数的基本解以及边界条件, 推导出广义反射系数与振幅递推公式, 得到各个地层中传输线Green函数的解析解; 然后利用Fourier逆变换与Bessel公式将海洋可控源电磁响应表示为Sommerfeld形式的积分, 借助三次样条插值与Lommel积分公式快速计算其数值解. 通过数值模拟结果考察工作频率以及地层各向异性电阻率变化等对海洋电磁响应的影响. 关键词： 传输线法 横向同性地层 海洋可控源电磁 Sommerfeld积分     

Friction and Wear Behaviors of the Polydimethylsiloxane Bishydroxyalkyl-Terminated Modified Polyurethane Composites Filled with the Barium Sulfate in Dry Friction and Water Lubrication

The addition of less than 20 wt% of approximate 1 micron barium sulfate (BaSO₄) into polyurethane (PU) composites modified by bishydroxyalkyl-terminated polydimethylsiloxane (PDMSBH) resulted in increases in mechanical strength and thermal conductivity and, at the same time, resulted in improvements in the friction and wear properties of the polyurethane composites. These polyurethane composites were suitable for marine use for bearings at high load under dry friction and at fast sliding speed under water lubrication. Characterization with Fourier transform infrared (FTIR) spectroscopy, thermogravimetry analysis (TGA), scanning electron microscope (SEM), and an MRH-3 ring-on-block wear tester indicated that the addition of BaSO₄ disrupts the organic phase separation in the polyurethane, resulting in better tribological properties, but there is no special chemical reaction between the particles and polyurethane. Adding too much BaSO₄ resulted in higher wear rate because of inorganic–organic phase separation.     

MARINE PROTECTED AREAS IN THE HIGH SEAS AND THEIR IMPACT ON INTERNATIONAL FISHING AGREEMENTS

Abstract Marine protected areas (MPAs) are gaining momentum as tools within fisheries management. Although many studies have been conducted to their use and potential, only few authors have considered their use in the High Seas. In this paper, we investigate the effects of fish growth enhancing MPAs on the formation of regional fisheries management organisations (RFMOs) for highly migratory fish stocks. We argue that in absence of enforcement MPAs constitute a weakest‐link public good, which can only be realized if everyone agrees. We combine this notion with a game theoretic model of RFMO formation to derive potentially stable RFMOs with and without MPAs. We find that MPAs generally increase the parameter range over which RFMOs are stable, and that they increase stability in a number of cases as compared to the case without MPAs. They do not necessarily induce a fully cooperative solution among all fishing nations. In summary, results of this paper suggest a positive role for MPAs in the High Seas.     

Characterising the near-wake of a cross-flow turbine

The performance and detailed near-wake characteristics of a vertical axis, cross-flow turbine (CFT) of aspect ratio 1 were measured in a large cross-section towing tank. The near-wake at one turbine diameter downstream was examined using acoustic Doppler velocimetry, where essential features regarding momentum, energy, and vorticity are highlighted. Dominant scales and their relative importance were investigated and compared at various locations in the measurement plane. Estimates for the terms in the mean streamwise momentum and mean kinetic energy equation were computed, showing that the unique mean vertical velocity field of this wake, characterised by counter-rotating swirling motion, contributes significantly more to recovery than the turbulent transport. This result sheds light on previous CFT studies showing relatively fast downstream wake recovery compared to axial-flow turbines. Finally, predictions from a Reynolds-averaged Navier–Stokes simulation with the commonly used actuator disk model were compared with the experimental results, evaluating its use as an engineering tool for studying flow in CFT arrays. Unsurprisingly, the model was not able to predict the near-wake structure accurately. This comparison highlights the need for improved parameterised engineering models to accurately predict the near-wake physics of CFTs.     

Determination of halogen levels in marine geological samples

ABSTRACT

A method for determining levels of fluorine (F), chlorine (Cl), bromine (Br), and iodine (I) in marine geological samples using wavelength dispersive X-ray fluorescence is presented here. Samples are prepared as pressed powder pellets. The method makes full use of the advantages of the ability of the modern X-ray fluorescence spectrometer to detect ultra-light elements and high-powered X-rays. A series of calibration standards with an appropriate concentration range was developed using a standard addition method. Empirical coefficients were used to correct for matrix effects in the case of F and Cl, the rhodium Kα -Compton peak was used as internal standard for Br matrix corrections, and the rhodium Kb-Compton peak was used to correct for the matrix effect on I. For % concentration of the analyte, the precision (relative standard deviation) of the method was <5%. For concentrations <0.1%, the relative standard deviation depended heavily on the count rates (or concentration). The accuracy of the method was validated by comparison of the results to similar reference materials. The detection levels of this method (counting time100 s) were 100, 5, 0.5, and 10 µg g^?1 for F, Cl, Br, and I, respectively. The method was here used to determine the levels of halogens in samples of 19 marine sediments (China, Russia, Canada, American), 10 marine manganese nodules (China, Russia, American, Germany, India, Japan), 4 cobalt-rich crust reference materials (Russia, China), reference materials, and 3 phosphorites.