The impact of coal-burning emission on sulfur in camphor leaves was investigated using Proton Induced X-ray Emission (PIXE) and synchrotron radiation technique X-ray Absorption Near-Edge Structure (XANES) spectroscopy. The PIXE results show that the sulfur concentrations in the leaves collected at the polluted site are significantly higher than those in controls. The Sulfur XANES spectra show the presence of organic (disulfides, thiols, thioethers, sulfonates and sulfoxides) and inorganic sulfur (sulfates) in the leaves. The inorganic sulfur in the leaves of camphor tree polluted by coal combustion is 15% more than that of the control site. The results suggest that the long-term coal-burning pollution resulted in an enhanced content of the total sulfur and sulfate in the leaves, and the uptake of sulfur by leaves had exceeded the metabolic requirement of plants and the excess of sulfur was stored as SO42-. It can monitor the sulfur pollution in atmosphere.
Results of laboratory simulation experiments on the influence of H2SO4 solutions on the optical characteristics of the radiation reflected from Rhododendron smirnovii leaves illuminated at an angle of 55° by He–Ne laser radiation ( = 0.63 m) linearly polarized in the plane of incidence are presented. The coefficients of correlation between the optical characteristics of the reflected radiation, the concentration of the acid, and the pigment composition of the leaves have been calculated. It is shown that the influence of acidic stresses on the polarization characteristics of the radiation reflected from a leaf manifests itself indirectly as changes in the concentration of chlorophyll a and chlorophyll b and changes in their ratio in the leaf when observation is performed at angles of 50–60°. 相似文献
A series of ubiquitously occurring saturated and monounsaturated six-carbon aldehydes, alcohols and esters thereof is summarised as ‘green leaf volatiles’ (GLVs). The present study gives a comprehensive data collection of retention indices of 35 GLVs on commonly used non-polar DB-5, mid-polar DB-1701, and polar DB-Wax stationary phases. Seventeen commercially not available compounds were synthesised. Thus, the present study allows reliable identification of most known GLV in natural plant volatile samples. Applications revealed the presence of several seldom reported GLVs in headspace samples of mechanically damaged plant leaves of Carpinus betulus and Fagus sylvatica. 相似文献