Determination of Specific Refractive Index Increment （dn/dc）_μ at a Constant Chemical Potential,for Solutions of Polymer in Mixed Solvents by the GPC Method

A new chromatographic method is described for the determination of specific refractive index increment(dn/dc)μ at a constant chemical potential,for polymer/mixed solvent systems.In this method the(dn/dc)is obtained by measuring the areas of solvated-polymer peaks when the mixed solvent is used as an eluent.Values of(dn/dc)μ for the poly(dimethylsiloxane)(PDMS)-benzene-methanol system,determined by the proposed method are in good agreement with those determined by the conventional dialysis method.The new approach has the advantages of simplicity,fast speed,and high reproducibility.The experimental results for stearic acid-chloroform-methanol system show that this method can also be applied to nonpolymer/mixed solvent systems for the determination of(dn/dc)μ.     

Characterization of the transport properties of membranes of uncertain macroscopic structural homogeneity

The present paper confirms and extends previous applications of an original method of time-lag analysis to (concentration-independent) gas permeation through porous pellets produced by uniaxial compaction of fine graphite powder. It is shown that this approach to the study of membrane permeability enables one to (i) detect unambiguously a macroscopic structural inhomogeneity affecting transport across the membrane (often present as an unsuspected artifact of the membrane fabrication process); (ii) determine appropriate average values of the resulting space-dependent diffusion, D(x), and sorption, S(x), coefficients (without recourse to equililibrium sorption measurements); (iii) secure substantial information about the functional form, as well as the degree, of variability of D(x) and S(x); and ultimately (iv) link this information to the underlying membrane structural inhomogeneity. In the present context, the salient underlying structural feature is nonuniform porosity across the membrane, represented by (x), and the link between D(x), S(x) and (x) is provided by the simple dual-mode (intrapore gas-phase + adsorbed-phase) model of sorption and transport in porous media. The effect of increasing overall pellet porosity (_obs) by reducing applied compacting pressure, was specifically studied and found to entail marked enhancement of the degree of structural inhomogeneity without material changes in the functional form of D(x), S(x) and hence of (x). The conclusions drawn from time-lag analysis were shown to be consistent with the observed behavior of apparent diffusion coefficients derived from transient-state sorption or permeation measurements and with the results of dual-mode steady-state permeation analysis. The latter results showed additionally that, for a more complete interpretation of observed transport behavior, the variability across the pellet of the orientation of graphite particles should also be taken into account.     

高层束筒建筑板块法理论

本文给出了正交异性板在多种平面应力边界条件下的应力分布解析表达式，由此提出了多筒高层框筒（或剪力墙筒体）内力与位移计算的正变异性板板块法理论．该方法是基于力法体系及形变协调条件的半解析法，可方便地应用于多筒筒体或多室梯形箱梁等折板结构分析。     

常相关样本统计量公布的应用

本文利用来自正态总体的常相关样本的一个统计量的分布，对广东省和辽宁省的一些企业１９８８年一１９８９年的利润额增值进行了分析．     

弹性分析法程序及箱形梁剪力滞系数的影响参数分析

本文首先介绍弹性分析的力法基础,流程框图及编制计算程序过程。通过程序来分析箱形梁剪力滞系数的影响参数,这里包括静定结构参数分析,其中探讨宽跨比、固端截面剪力滞系数的变化,宽高比的影响。截面型式对λ的影响,悬臂长度的影响以及荷载型式(集中力与均布力)对沿梁为直线变截面,抛物线变截面及等截面的悬臂固端梁的变化及影响。     

BRITTLE-DAMAGE ANALYSIS OF CRACKS UNDER CONDITIONS OF PLANE-STRAIN TENSILE LOADING

An abrupt damage model, taking full account of finite geometrychanges, is used to study both the shapes of damage zones and the stress strain fieldsfor a plane-strain tensile crack under the small-scale yielding condition. Two typicalcrack-tip damage profiles are simulated by the element vanish technique. The fracturetoughness increment due to damage dissipation is evaluated in terms of the energyrelease rate.     

大范围市场系统的稳定性分析

本文利用 L iapunov泛函的加权研究具时间滞后效应的大范围市场系统的稳定性 ,得到系统的均衡价格为一致渐近稳定的充分条件 ,它们推广或改进了文献 [1,4 ,5 ]的相应结果     

A peak structure in isothermal luminescence signals in quartz: Origin and implications

Isothermal heating is commonly used in luminescence dosimetry and trap parameter studies. It is often observed that the isothermal luminescence signal has a peak shape instead of a monotonous decay form. We provide here evidence that this peak shape in quartz may equally result from a ‘thermal lag’ problem in contrast to the earlier propositions of non first-order kinetics. Temperature modelling suggests that the peak-shaped signal contains elements of both the ramped — and isothermal — thermoluminescence (TL). The modelled changes in the peak movement as a function of isothermal temperature and the ramp-rate show an excellent agreement with those obtained experimentally. This understanding of thermal lag is extended to optically stimulated luminescence (OSL) measurements for which the effects of isothermal TL contamination and changing thermal assistance during thermal equilibration are discussed. Appropriate methods are suggested to identify thermal lag on the basis of the peak structure, and to circumvent this effect in isothermal methods.     

How big are the increments of a multifractional Brownian motion?

In this paper, we study globle path behavior of a multifractional Brownian motion, which is a generalization of the fractional Brownian motion.     

Wiener过程局部时的(H一R)增量有多小

许多作者讨论了Wiener过程及其局部时的增量问题,Hanson和Russo在[4]中提出了一类新的Wiener过程增量(本文称之为H-R增量),笔者在[5]中把H-R增量引到了Wiener过程的局部时上,讨论了H-R增量有多大的一类问题,本文继续讨论了Wiener过程局部时的H-R增量,回答了Wiener过程局部时的HR增量有多小的问题,得到了与Wiener过程H-R增量有多小相应的结果.