超导低电阻接头衰减法测试过程中的拟合偏差控制

超导技术在许多高新技术领域有着广泛而深远的应用前景,其中超导导体接头技术是超导发展过程中必不可少的关键环节之一,快速而又准确地评估低电阻接头显得尤为重要.本文在考虑超导体的E-J特性后,针对目前低电阻接头采用的衰减法测量,计算得出感应电流完整的衰减曲线方程-幂函数方程.对比目前广泛采用的指数方程拟合与采用幂函数方程拟合的偏差,指出采用指数方程代替幂函数方程拟合的必要条件,为接头电阻衰减法测试,尤其是低电阻接头情况下的测量提供参考.     

时频分析在旋转机械状态监测及故障诊断中的应用

本文简要介绍了时频分析方法的发展及其在旋转机械状态监测、故障诊断领域中的应用。并以一个实际监测系统为例，对其检测信号应用时频分析的方法进行了数据处理，对用传统傅立叶变换处理的结果与采用时频分析方法处理的结果进行了对比分析．     

Synthesis,spectroscopic characterization (IR, 1H, 13C and 119Sn NMR,electrospray mass spectrometry) and toxicity of new organotin(IV) complexes with N,N′,O‐ and N,N′,S‐scorpionate ligands

New organotin(IV) derivatives containing the anionic ligands bis(3,5‐dimethylpyrazol‐1‐yl)dithioacetate [LCS₂]⁻ and bis(3,5‐dimethylpyrazol‐1‐yl)acetate [LCO₂]⁻ have been synthesized from reaction between (CH₃)₂SnCl₂ and lithium salts of the ligands. Mononuclear complexes of the type {[LCX₂](CH₃)₂SnCl} (X = S or O) have been obtained and fully characterized by elemental analyses and FT‐IR in the solid state and by NMR (¹H, ¹³C and ¹¹⁹Sn) spectroscopy, conductivity measurements and electrospray ionization mass spectrometry in solution. The acute toxicity of new organotin(IV) derivatives on rat was studied, comparing their effect with those of dimethyltin chloride (CH₃)₂SnCl₂. The comparison of LD₅₀ of organotin(IV) complexes and (CH₃)₂SnCl₂ administered intraperitoneally, as a single dose, evaluated in vivo on rats, showed that toxicity decreases as follows: (CH₃)₂SnCl₂ > LCO₂ > LCS₂. The effect of these organotin(IV) complexes on DNA was evaluated in vitro and in vivo on rats treated with different doses of these compounds (1/20 LD₅₀ and 1/100 LD₅₀). The lymphocyte DNA status was assessed by the comet assay, a rapid and sensitive single‐cell electrophoresis technique, used to detect primary DNA damage in individual cells. After 36 h from the start of treatment the two new organotin(IV) derivatives induced a significant rise in comet assay parameters, indicating an increasing presence of damaged DNA. Copyright © 2005 John Wiley & Sons, Ltd.     

Investigation of the manganese stress on wheat plant by attenuated total reflectance Fourier transform infrared spectroscopy

ABSTRACT

The present paper deals with the investigation of the changes in chemical contents of the leaf of wheat seedling stressed by excess manganese using attenuated total reflectance Fourier transform infrared spectroscopy (FTIR) technique. The infrared spectra of the leaves of control and manganese-treated wheat plants have been recorded in the spectral region 485–4000?cm^?1 at a resolution of 4?cm^?1. The recorded spectrum has been analyzed with the help of curve-fitting method for the quantitative estimation of chemical contents and conformational changes. The study indicated changes arising in the polysaccharide, lignin, amino acid, secondary structure of protein, and lipid in the leaves of control and manganese-treated wheat plants. Manganese treatment increased the amount of cellulose, lignin, and amide II till 200?μM concentration, while a decrease was observed at 1000?µM concentration. Manganese induced conformational changes in the secondary structure of protein which was indicated by shifting of the bands to the higher wavenumber and change in the β sheet/α helix ratio. In addition, manganese stress decreased lipid content in the leaves of the wheat seedlings. The study demonstrates the potential of attenuated total reflectance FTIR for the non-invasive and rapid monitoring of the plants stressed with heavy metals.     

Observation of dimethylaminoethyl methacrylate–myoglobin binding reaction using laser spray mass spectrometry

Covalent bonds are often created by a reaction between chemicals and protein before causing various adverse effects in a cell. Dimethylaminoethyl methacrylate (DMAEMA), which has moderate toxicity, causes skin inflammation and throat irritation. For this study, we investigated a reaction mechanism between myoglobin and (DMAEMA) using a new analytical tool developed at our laboratory: laser spray mass spectrometry technique. It was found that initially DMAEMA was added to the amino group of protein by the Michael addition mechanism; the added DMAEMA was hydrolyzed to methacrylic acid using an autocatalytic system. The results of this study indicate the feasibility of the laser spray technique in analyses of reaction dynamics. Copyright © 2012 John Wiley & Sons, Ltd.     

Cohen–Macaulay Multi–Rees Algebras

Let A be a local ring, and let I ₁,...,I _r A be ideals of positive height. In this article we compare the Cohen–Macaulay property of the multi–Rees algebra R _A (I ₁,...,I _r ) to that of the usual Rees algebra R _A (I ₁ ··· I _r ) of the product I ₁ ··· I _r . In particular, when the analytic spread of I ₁ ··· I _r is small, this leads to necessary and sufficient conditions for the Cohen–Macaulayness of R _A (I ₁,...,I _r ). We apply our results to the theory of joint reductions and mixed multiplicities.     

The independence of initial vectors in the subdivision schemes

Starting with an initial vector λ = (λ(κ))κ∈z ∈ ep(Z), the subdivision scheme generates asequence (Snaλ)∞n=1 of vectors by the subdivision operator Saλ(κ) = ∑λ(j)a(k - 2j), k ∈ Z. j∈zSubdivision schemes play an important role in computer graphics and wavelet analysis. It is very interesting tounderstand under what conditions the sequence (Snaλ)∞n=1 converges to an Lp-function in an appropriate sense.This problem has been studied extensively. In this paper we show that the subdivision scheme converges forany initial vector in ep(Z) provided that it does for one nonzero vector in that space. Moreover, if the integertranslates of the refinable function are stable, the smoothness of the limit function corresponding to the vectorλ is also independent of λ.     

The Bell inequalities and the joint measurement of incompatible observables

A quantum-mechanical theory of joint nonideal measurement of incompatible polarization observables is applied to an EPR-like experiment. It is demonstrated that this experiment yields both information satisfying and information violating the Bell inequalities. The measurement is also discussed in the context of a local hidden-variables theory. It is argued that the violation of an additional assumption of reproducibility of the hidden variable rather than violation of locality may be responsible for the violation of the Bell inequalities.     

铈和钆对体外培养正常二倍体细胞的作用

采用同位素示踪、细胞周期分析和组化等技术，研究Ｃｅ３＋和Ｇｄ３＋对动物正常二倍体细胞的生物学作用。结果表明，Ｃｅ３＋和Ｇｄ３＋仅在一个狭窄的剂量范围（１×１０－６～１×１０－５ｍｏｌ／Ｌ）可促进正常二倍体细胞增殖，有明显的剂量—效应关系。Ｃｅ３＋和Ｇｄ３＋在高浓度时（１×１０－３ｍｏｌ／Ｌ），对细胞具有毒性，可使细胞坏死、增殖缓慢并诱导细胞凋亡。