长型浮置板轨道隔振系统理论分析(Ⅰ)——弥散曲线及临界速度

浮置板轨道结构是近年来减振降噪效果最好的轨道结构形式.将整个轨道结构看作一个隔振黑匣子,钢轨与浮置板分别用欧拉梁来模拟,推导动力方程,用傅氏变换将其转换到频率-波数域中,求得系统的弥散方程,并给出轨道结构临界速度计算方法.定义了反映浮置板轨道结构参数的质量比例ξ_(m)、刚度比例ξ_(h)及阻尼比例ξ_(c)等三个系数.在给定实际中板上结构物理参数的条件下,深入讨论了三个比例系数对于系统弥散曲线以及临界速度的影响,进而为浮置板轨道共振频率及临界速度的初步设计提供建议.     

Isolation of myo-inositol from a mixture of isomers

The transfer reaction of phosphatidylcholine and aqueous solutions of inositols that is catalyzed by phospholipase D is studied. Optimal conditions for synthesis of posphatidylinositol in a water—organicsolvent heterogeneous system are found. Addition of the alcoholic substrate methanol to the reaction medium is demonstrated to liberate myo-inositol from the phosphatidylinositol in hexane—water. Myo-inositol is isolated from a mixture of isomers by carrying out the double transfer reaction using phospholipase D.Mirzo Ulugbek National University of Uzbekistan. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 160–163, March–April, 2000.     

ClCu(η^2-O~2)与ClCuNN分子的基质隔离红外光谱和 理论研究

激光烧蚀CuCl~2或CuCl靶的产物与O~1或N~2共同沉积在11K的Ar基质中,在1175.0cm^-^1(O~2/Ar)和2296.3cm^-^1(N~2/Al)处观察到了新的红外吸收。通过同位素取代实验以及量子化学计算,可将1175.0cm^-^1归属为ClCu(η^2-O~2)的O－O伸缩振动,而将2296.3cm^-^1归属为ClCuNn的N－N伸缩振动。ClCu(η^2-O~2)和ClCuNN这两种新型配合物的确证,为进一步研究含O~2,N~2的过渡金属配合物提供了一种模型分子。     

阳极化膜用于等离子体电光开关放电腔绝缘模拟研究

 壳体金属化是等离子体电光开关实现阵列结构的必须,放电腔的绝缘是壳体金属化的技术关键和难点。分析了等离子体电极电光开关放电腔的主要放电过程和特性;介绍了几种厚度阳极化膜层的击穿电压和用于电光开关放电腔绝缘模拟实验的情况和结果。初步分析了影响阳极化膜用于等离子体电极电光开关放电腔绝缘的主要因素,实验表明60μm厚度的阳极化膜可以满足电光开关放电腔绝缘的实用要求。     

基于伪微分和加速度反馈的航空光电稳定平台控制方法

为了提高航空光电稳定平台的扰动隔离度,在传统平台的电流反馈、速度反馈、位置反馈的基础上增加了高增益加速度反馈,并利用伪微分反馈的控制技术设计出新的控制器来代替传统的速度反馈的PI控制器。实验结果表明,在模拟转台以1°、0~2.5 Hz的正弦干扰下,相对于传统的航空光电稳定平台,基于伪微分和加速度反馈控制的光电稳定平台的阶跃响应超调量减小了约7.8%,扰动隔离度提高了约8.7 d B;相对于基于PI控制器和加速度反馈控制的航空光电稳定平台,基于伪微分和加速度反馈控制的光电稳定平台的阶跃响应超调量减小了约2.6%,且平台的过渡过程加快。该控制系统能够有效地抑制扰动力矩的影响,具有较好的通用性和实用性。     

Cyclic M(SO2) (M=Zn,Cd) and its Anions: Matrix Infrared Spectra and DFT Calculations

Reaction of laser ablated zinc and cadmium atoms with SO₂ molecules was studied by low temperature matrix isolation infrared spectroscopy. Cyclic M(SO₂) and anion M(SO₂)^- (M=Zn, Cd) were produced in excess argon and neon, which were identified by ³⁴SO₂ and S¹⁸O₂ isotopic substitutions. The observed infrared spectra and molecular structures were confirmed by density functional theoretical calculations. Natural charge distributions indicated significant electron transfer from s orbitals of zinc or cadmium metal atom to SO₂ ligand and cyclic M(SO₂) complexes favored “ion pair” M⁺(SO₂)^- formation, which were trapped in low temperature matrices. In addition Zn-O or Cd-O bond in M(SO₂) exhibited strong polarized covalent character. Reaction of Hg atom with SO₂ was also investigated, but no reaction product was observed, due to the relativistic effect that resulted in the contraction of 6s valence shell and high ionization potential of Hg atom     

一类分段光滑隔振系统的非线性动力学设计方法

分段光滑隔振系统是一类具备分段刚度或阻尼的非线性动力学系统,在振动控制领域中具有广泛代表性,诸如限位隔振系统、分级汽车悬挂等. 分段光滑的刚度或阻尼特性能够实现隔振系统的特定动力学性能及提升隔振性能,如抑制共振响应、提升共振区隔振性能等,但是亦会给隔振系统的动力学行为带来诸多不利影响. 以分段双线性分段光滑隔振系统为理论模型,系统研究了摒除不利于隔振的非线性动力学现象设计方法,包括幅值跳跃、周期运动的倍周期分岔等. 首先,利用平均法与奇异性理论给出了主共振频响曲线拓扑特征的完整拼图. 研究结果表明,参数空间分为4 个区域,其中2 个区域存在幅值跳跃,而其产生跳跃原因分别由鞍结分岔与擦边分岔所导致;基于此提出避免主共振跳跃的设计方法. 其次,建立了隔振有效区内周期运动的庞加莱映射,通过特征值分析给出了避免倍周期分岔发生的条件,证实增大阻尼可以抑制倍周期分岔的发生. 最后通过数值仿真分析了噪声对多稳态运动的影响. 研究结果发现在噪声影响下,分段光滑隔振系统的响应会在不同稳态间跃迁,非常不利于隔振. 因此,在完成跳跃与倍周期分岔的防治设计后,应采用数值仿真校验系统是否存在多稳态运动.      

Self-synchronization theory of dual motor driven vibration system with two-stage vibration isolation frame

This paper studies self-synchronization and stability of a dual-motor driven vibration system with a two-stage vibration isolation frame. Oscillation amplitude of the material box large enough can be ensured on the vibration system in order to screen materials. Reduction of the dynamic load transmitted to the foundation can also be achieved for the vibration system. A Lagrange equation is used to set up the motion differential equations of the system, and a dimensionless coupled equation of the eccentric rotors is obtained using a method of modified average small parameter. According to the existence condition of zero solution in the dimensionless coupled equation of the eccentric rotors, the precondition for commencing self-synchronization motion is achieved.The stability condition of self-synchronization is obtained based on the Routh-Hurwitz criterion. The theoretical analysis is validated by simulations and experiments.     

惯容器对隔振系统动态性能影响研究

本文设计了一种滚珠丝杠惯容器及ISD隔振系统,通过实验研究了惯性轮的转动惯量对惯容值的影响;同时,分析了滚珠丝杠惯容器的机械动力学特性,推导了ISD隔振系统的振动传递率计算公式,探讨了惯容器对ISD隔振系统动态特性的影响。在电机被动、主动和混合隔振工况下,开展了弹簧阻尼系统和ISD隔振系统的振动性能对比实验,验证了惯容器对振动系统固有频率和减振效果的影响规律。研究结果表明,惯容器可降低振动系统的固有频率,使共振频率向低频移动,共振振幅降低;在共振频率附近,惯容器可抑制共振振幅,惯容值越高,抑制效果越明显;ISD隔振系统在低频的减振效果优于传统的弹簧阻尼系统;随着频率比的增加,ISD隔振系统的传递率趋于稳定值,惯容器会引起高频隔振性能降低。     

千里光中几种黄酮和酚酸类成分的分离与鉴定

对千里光(Senecio scandens Buch.-Ham.)全草的乙酸乙酯提取部位进一步分离,得到4个黄酮类化合物和2个酚酸类化合物,经理化性质和NMR及MS谱学数据鉴定分别为槲皮素3-O-β-D-葡萄糖苷（Ⅰ）、金丝桃苷（Ⅱ）、槲皮素（Ⅴ）、异鼠李素（Ⅵ）、绿原酸（Ⅲ）和咖啡酸（Ⅳ）。 其中化合物Ⅰ~Ⅵ均为首次从千里光属植物中分离鉴定。