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101.
The molecular structure and absorption spectra of monothio- and dithio-naphthalimides were compared to their naphthalimide analogues using AM1, PM3 and ZINDO/S semiempirical quantum chemical methods. The substitution of the 4R-naphthalimide oxygen atoms by sulphur atoms resulted in a red-shift of the absorption spectra by Δλmax60-65 and 100-140 nm, respectively. The thionated naphthalimide derivatives do not show observable fluorescence due to intersystem crossing to the triplet -states localised at the CS groups. The -absorption bands of monothioimides are located at 525-580 nm (ε=60-80) and those for dithioimides at 535-560 nm (ε=140-390) and 628-686 nm (ε=34-68). None of these transitions are solvent sensitive. The -transitions of N-phenylthioimides have also a small contribution from -states due to a partial conjugation between CS group and π-electronic system of the N-phenyl ring. As a result, the bands of aromatic substituted N-phenylthioimides are red-shifted as compared to those of the aliphatic N-methyl-thioimides.  相似文献   
102.
FTO客体3m闪光照相的Monte Carlo研究   总被引:1,自引:14,他引:1       下载免费PDF全文
 研究了客体模型FTO的闪光照相系统X光输运过程,给出了直穿照射量、散射照射量、直散比、直穿照射量能谱、散射照射量能谱、直穿X光通量能谱和散射X光通量能谱在记录平面的空间分布。结果表明:后锥是照射量散射成分的主要来源,后锥照射量占总散射量97%;后锥也是造成散射的空间分布不均匀的主要器件,这一不均匀性高达58%。照相系统的最小直散比非常小,表明锥造成的散射已经严重地淹没了直穿(轫致辐射)信号。计算中使用高空间分辨率记录法进行分点,合成图像对吸收系数的复原结果与国外报道的结果相符。  相似文献   
103.
Investigations have been performed on convective heat transfer in water flowing through mini-channels using the non intrusive technique of laser interferometry coupled with digital image processing. Optical glass channels, fabricated with metallic heating surfaces, were studied using a Mach-Zehnder interferometer configuration. Fringe patterns captured using a high-sensitivity CCD camera were analyzed digitally based on a calculation method developed for the liquid medium. Results of parametric studies were compared and contrasted with relevant theoretical solutions from the literature. Indication of the onset of turbulence at Reynolds numbers smaller than the conventional transition Reynolds number for large channels has also been noticed in the experimental investigation.  相似文献   
104.
航空遥感监测中变焦镜头的广泛应用以及飞行高度的变化会获得不同地面分辨率的航空影像,因此为了实时监控到飞行区域的整体情况,需要对不同地面分辨率的图像进行拼接。提出了针对不同地面分辨率图像进行拼接的方法。首先用四分法对图像进行分割,检测变化倍率,选择配准策略;然后用基于加速鲁棒性特征(Speeded-Up Robust Features,SURF)的算法对相邻图像进行拼接。获得了焦距变化从高倍过渡到低倍,或从低倍过渡到高倍的拼接图像。通过航空变焦模拟影像的拼接实验和地面变焦影像的拼接实验表明,该方法能够对不同地面分辨率的图像进行拼接,且拼接结果均以高分辨率为基准。  相似文献   
105.
In this note, we point out two errors in the article “On the Neumann function and the method of images in spherical and ellipsoidal geometry” by Dassios and Sten. Two corrections are then proposed.  相似文献   
106.
The necessity of odor sensing has been increasing from environmental and health standpoints. Here, we propose the novel concept of a small device which can select odor molecules based on electrostatic spraying. For high selectivity of the target gas or odor, we conducted computational fluid dynamics coupled with an electrostatic field, as well as measurements by particle image velocimetry and anemometry. The computational model successfully reproduced characteristic features of ionic wind. Different trajectories of charged particles were computationally obtained owing to their electrical mobility. The results imply that different materials might be separated by the arrangement of the collecting electrode.  相似文献   
107.
108.
In several recent investigations dealing with the economic order quantity with permissible delay in payments, the following assumptions are made:  相似文献   
109.
The migration of a downsized crescent-shaped dune was investigated in a wind tunnel experiment.Quantified upwind influx and vertical oscillation of the sand bed were introduced to modulate the saturation level of the sand flux above the dune surface to affect dune evolution.The evolution was recorded by top-view photography and then abstracted as the evolution of self-defined characteristic quantities using a digital image processing algorithm.The results showed that,in contrast to the case for spanwise quantities,the evolution of streamwise quantities corresponds to a linear increase in the modulation magnitude more positively and in a monotonic and convergent manner.In contrast with quantities on the windward face,the changes in quantities with respect to the horns were nonmonotonic with time and almost uncorrelated with the variation in modulation strength,which reveals the distinctiveness of leeside evolution.  相似文献   
110.
《Optik》2014,125(24):7143-7148
We propose a retinex improvement for nighttime image enhancement. Retinex is often used on images under non-uniform illumination in terms of either color or lightness and has satisfactory results to achieve color constancy and dynamic range compression. Few studies focus retinex on nighttime images, especially those under extreme conditions (i.e., images with over-lighted or extremely under-lighted areas or with noise speckles), on which retinex operation can perform badly. Original multi-scale retinex (MSR) is extremely sensitive to noise speckles that cameras produce in low light areas, and it has unsatisfactory effect on areas with normal or intensive illumination. Moreover, original MSR uses a gain-offset method for prior-to-display treatment and can lead to apparent data loss on nighttime images. This paper replaces the logarithm function in MSR with a customized sigmoid function to minimize data loss, and adapts MSR to nighttime images by merging results from sigmoid-MSR with original images. Experiments show our framework, when applied to nighttime images, can preserve areas with normal or intensive lighting and suppress noise speckles in extreme low light areas.  相似文献   
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