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81.
82.
Remko Achten Arie Koudijs Marcel Giesbers Antonius T. M. Marcelis Corresponding author Ernst J. R. Sudhölter 《Liquid crystals》2013,40(3):277-285
Two series of non‐symmetric banana‐shaped compounds, both with one alkyl and one alkenyl terminal tail, have been synthesized and studied. Both series were compared with the corresponding series with two saturated terminal alkyl tails. All the compounds have a bent central 1,3‐phenylene bis(4‐benzoyloxy)benzoate core; their mesophases were characterized by polarizing optical microscopy, differential scanning calorimetry, X‐ray diffraction and switching current response experiments. In all four series one of the terminal tails is varied from OC8H17 to OC16H33. The other terminal tails are OC11H23, O(CH2)9CH?=?CH2, OC10H21 and O(CH2)8CH?=?CH2. The short‐tailed compounds show monotropic or enantiotropic B1 phases and the long‐tailed compounds the B2 phase. The introduction of one terminal vinyl group slightly lowers the transition temperatures. The introduction of a second terminal vinyl group further suppresses the liquid crystalline properties. All compounds with B2 phases have layer spacings that suggest a tilt of ~45° of the bent molecules in the layers, and their switching behaviour is antiferroelectric. 相似文献
83.
Ionic liquids as stationary phases in gas chromatography: Determination of chlorobenzenes in soils
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Rosa María González Paredes Carmelo García Pinto José Luis Pérez Pavón Bernardo Moreno Cordero 《Journal of separation science》2014,37(12):1448-1455
The present research focuses on the evaluation of different ionic liquid (IL) stationary phases in gas chromatography. The different IL columns were evaluated in terms of peak resolution (Rs) and peak symmetry for the separation of the chlorobenzenes. The determination of chlorobenzenes in soil samples by means of the optimal IL stationary phase (SLB‐IL82) is proposed as an application. Soil pretreatment was based on a simplified quick, easy, cheap, effective, rugged, and safe extraction procedure and a large injection volume via a programed temperature vaporizer working in solvent vent mode. The retention time of the chlorobenzenes increased as the polarity of the IL column decreased. SLB‐IL82 is the stationary phase that provides the best values as regards Rs and asymmetry factor. Soil sample blanks were spiked with the analytes before subjecting the sample to the extraction process. The existence of a matrix effect was checked and the analytical characteristics of the method were determined in a fortified garden soil sample. The method provided good linearity, good repeatability and reproducibility values, and the LODs were in the 0.1–4.7 μg/kg range. Two fortified soil samples were applied to validate the proposed methodology. 相似文献
84.
电沉积作为一种在温和条件下从溶液中合成材料的技术已被广泛应用于在导体和半导体基底表面合成各种功能材料。电沉积一般由人为施加于基底的电刺激(如:施加电位/电流)来触发。这种电刺激通过氧化或还原靠近基底表面的溶液层内部的离子、 分子或配合物从而使该溶液层偏离其热力学平衡状态,随后引起目标产物在基底表面的沉积。在电沉积过程中, 许多实验参数都可能从不同的方面对沉积物的物化性质造成影响。迄今为止,已通过电沉积制备出多种单质(包括金属和非金属单质)、 化合物(例如:金属氧化物、金属氢氧化物、 金属硫化物等)以及复合材料。电沉积制备的这些材料大多为多晶、 织构或外延薄膜的形式。其中, 外延薄膜是一种具有特定的面外和面内晶体生长取向且其晶体取向受基底控制的类单晶薄膜。由于外延薄膜中高度有序的原子排列,它们常呈现出独特的电磁性质。本文总结了常见的电沉积合成路线及影响沉积物外延生长的关键实验因素。此外, 本文简要介绍了用于表征外延薄膜的技术。最后, 本文还讨论了一些采用电沉积制备的具有特殊电子、 电磁及光电特性的功能外延薄膜。 相似文献
85.
D. Vignolles A. Audouard V. N. Laukhin J. Béard E. Canadell N. G. Spitsina E. B. Yagubskii 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(4):383-388
The oscillatory magnetoresistance spectrum of the
organic metal (BEDO)5Ni(CN)4. 3C2H4(OH)2 has
been studied up to 50 T, in the temperature range from 1.5 K to
4.2 K. In high magnetic field, its Fermi surface corresponds to a
linear chain of quasi-two-dimensional orbits coupled by magnetic
breakdown (MB). The scattering rate consistently deduced from the
data relevant to the basic α and the MB-induced β
orbits is very large which points to a significant reduction of
the chemical potential oscillation. Despite of this feature, the
oscillations spectrum exhibits many frequency combinations. Their
effective masses and (or) Dingle temperature are not in agreement
with either the predictions of the quantum interference model or
the semiclassical model of Falicov and Stachowiak. 相似文献
86.
Roberto Pittau 《Fortschritte der Physik》2015,63(2):132-141
Following a Four Dimensional Renormalization approach to ultraviolet divergences (FDR), we extend the concept of predictivity to non‐renormalizable quantum field theories at arbitrarily large perturbative orders. The idea of topological renormalization is introduced, which keeps a finite value for the parameters of the theory by trading the usual order‐by‐order renormalization procedure for an order‐by‐order redefinition of the perturbative vacuum. One additional measurement is then sufficient to systematically compute quantum corrections at any loop order, with no need of absorbing ultraviolet infinities in the Lagrangian. 相似文献
87.
采用改进的线性组合算符和幺正变换相结合的方法研究了Rashba效应对抛物量子线中强耦合束缚磁极化子性质的影响.计算了抛物量子线中强耦合束缚磁极化子的有效质量和振动频率,对Rb Cl材料的数值计算结果表明:量子线中强耦合束缚磁极化子的振动频率随受限强度和回旋频率的增加而增大;有效质量与磁极化子的受限强度、回旋频率和电子面密度有关,在Rashba效应影响下有效质量随上述各量的变化曲线都发生了分裂. 相似文献
88.
89.
90.
新型高色纯度弱电流猝灭性蓝色有机发光器件 总被引:1,自引:0,他引:1
以ADN为基质,分别以不同掺杂剂制备了四种蓝色有机发光器件,器件结构为:CuPc(12 nm)/NPB(40 nm)/AND∶Dopant(50 nm)/Alq(12 nm)/LiF(4 nm)/Al。掺杂剂有:BCzVB(amino-substituted distyrylarylenederivatives)、TBPe、BCzVBi和DSA-ph四种。研究了最佳掺杂浓度以及器件的亮度、电流密度、效率和色坐标等电学特性和光学特性。其中掺杂BCzVB制备了色纯度高、低电流猝灭性的蓝色有机发光器件,色坐标达到x=0.146,y=0.162,最大亮度为11600 cd/m2(15 V),电流效率为2.8 cd/A,流明效率为1.79 lm/W;以ADN为基质,分别以TBPe、BCzVBi和DSA-ph为掺杂剂,制备了另外三种对比器件。器件ADN∶TBPe色坐标为x=0.162,y=0.222(蓝绿光),效率随电流的增加而降低很快;器件ADN∶BczVBi有较好的色纯度(色坐标:x=0.164,y=0.146),但电流效率较低:2.03 cd/A,效率随电流的增加降低幅度也较快。器件ADN∶DSA-ph效率较高为8 cd/A,效率随电流增加变化幅度不大,但色纯度比较差(x=0.153,y=0.306),适合于做白色有机发光器件。 相似文献