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941.
复合金属氧化物Sn-Sb-Mn/陶瓷粒子电极体系的电催化性能 总被引:8,自引:1,他引:7
通过热分解法制备了复合金属氧化物Sn-Sb-Mn/陶瓷粒子电极, 分别采用扫描电子显微镜(SEM)、能量色散X 射线能谱(EDS)、X射线衍射(XRD)和N2吸附-脱附等技术对电极的形貌、晶相组成、比表面积和孔径分布进行了表征. 考察了该三维粒子电极系统的析氧特性, 采用循环伏安法分析了三维系统的电催化性能, 并且进行了电化学催化降解苯酚的试验. 结果表明, 制备的陶瓷粒子电极涂层比表面较大、孔结构发达, 有利于电催化反应; 电催化降解主要发生在电化学析氧区; 粒子电极系统对苯酚降解作用显著, 明显高于二维电极系统, 苯酚的去除率为92.3%, 总有机碳(TOC)的去除率为66.7%. 研究结果表明, 该三维粒子电极系统具有优良的电催化性能. 相似文献
942.
CeZrYLaO对Fe基整体式稀薄甲烷催化燃烧性能的影响 总被引:1,自引:0,他引:1
采用共沉淀法制备了高性能低铈储氧材料Ce0.35Zr0.55Y0.07La0.03O1.95(OSM,储氧材料)和胶溶法制备了耐高温、高比表面的La-Al2O3并以它们为载体,制备了一系列整体式铁基催化剂。考察了该系列催化剂对甲烷稀薄燃烧的催化性能,并用低温N2吸附-脱附,储氧能力(oxygen storage capacity,OSC),XRD,XPS和H2-TPR等测试手段对载体和催化剂进行了表征。活性测试结果表明所制得的整体式催化剂Fe/OSM+La-Al2O3可在50 000 h-1的高空速条件下使含量为1%的甲烷在474 ℃起燃,565 ℃完全转化;低温氮吸附-脱附测试结果表明,所制得的Ce0.35Zr0.55Y0.07La0.03O1.95经1 050 ℃焙烧5 h后的BET比表面积达33 m2·g-1,孔容为0.14 mL·g-1;La-Al2O3经1 050 ℃焙烧5 h后的BET比表面积达125 m2·g-1,孔容为0.46 mL·g-1,是优良的催化剂载体;OSC测试结果表明,加入储氧材料(oxygen storage material(OSM))能增加催化剂的储氧性能,有利于催化活性的提高;XRD测试结果表明,OSM以均一固溶体存在;XPS测试结果表明,Fe2O3与OSM载体之间的相互作用最强;H2-TPR测试结果表明,加入OSM能增加催化剂的还原性能,从而提高了催化活性。 相似文献
943.
制备了不同BaO含量的CeO2-ZrO2储氧材料,并以此材料为载体浸渍H2PdCl6制得三效催化剂.结果表明,不论新鲜还是1 000 ℃老化状态下,以10%BaO添加CeO2-ZrO2储氧材料制备的Pd三效催化剂活性最佳,起燃和完全转化温度最低.XPS结果证实,10%BaO添加.通过稳定PdO活性组分并改变其电子环境使得催化剂有最佳活性.而随着BaO含量持续增加,Pd活件组分相对处于较氧化状态.储氧量、低温N2吸附-脱附测试以及XRD测试结果均表明10%BaO添加的材料储氧量,比表面积以及孔容均最大,而且有适应三效催化的孔径.这些结果均有助于以其制备的Pd三效催化剂获得更好的活性以及热稳定性. 相似文献
944.
Marisa Freitas 《Analytica chimica acta》2009,649(1):8-8272
Neutrophils, also known as polymorphonuclear leukocytes (PMN), are the most common type of white blood cells, comprising about 50-70% of all white blood cells. In the event of inflammatory processes, neutrophils display increased mobility, tissue influx ability, prolonged life span, and an increased phagocytic capacity, constituting the initial participants in the cellular defense of the organism. One of the most important defense systems of neutrophils corresponds to their ability to mediate a strong oxidative burst through the formation of reactive oxygen species (ROS) and reactive nitrogen species (RNS). While oxidative burst is important for the elimination of invading microorganisms, the overproduction of ROS and RNS or the impairment of endogenous antioxidant defenses may result to detrimental effects to the host. The nature and the extent of ROS and RNS production by neutrophils in response to different stimuli is, consequently, a matter of extensive research, with scientific reports showing an enormous variability on the detection methodologies employed. This review attempts to provide a critical assessment of the most common approaches to identify and quantify reactive species formed during the neutrophils’ oxidative burst. The detection mechanisms and performance, as well as advantages and limitations of the different methodologies, are scrutinized, focusing on the use of fluorimetric, chemiluminometric and colorimetric probes. 相似文献
945.
F. Raposo M.A. de la Rubia M. Alaiz C. Cavinato G. Demirer B. Helmreich N. Martí J. Noguerol S. Picard 《Talanta》2009,80(1):329-337
In 2008, the first Proficiency Testing Scheme of Chemical Oxygen Demand (1stCOD-PTADG) was conducted to assess the results obtained for different research groups whose field work is mainly anaerobic digestion. This study was performed using four samples, two solid samples as raw materials and two solid samples to prepare high concentration suspended solid solutions. Invitations were sent to a large number of laboratories, mainly to anaerobic digestion research groups. Finally, thirty labs from sixteen countries agreed to participate, but for different reasons four participants could not send any data. In total, twenty-six results were reported to the COD-PT coordinator.This study showed the importance of continuous participation in proficiency testing (PT) schemes in order to compare the results obtained. Taking into account the lack of a general standard method and high quality certified reference materials (CRMs), the traceability of COD determination is not currently easy to check. In addition, the spread of participants’ results obtained was high and pointed to the advisability of using consensus values due to their unreliability. Therefore, the theoretical oxygen demand (ThOD) values were considered as assigned values for all the samples analysed. On the other hand, in this PT the established standard deviation (ESD) has been determined by the Horwitz modified function.Participants of this 1stCOD-PTADG were asked to give a short report on the analytical method used. Although all the participants used potassium dichromate as their oxidant reagent, their experimental procedures were very different. With the purpose of comparing the results obtained, the different experimental conditions used were classified into five methods, corresponding to two main categories, open and closed reflux. The performance of laboratories was expressed by the z-score, whose value is considered satisfactory when z-score ≤±2. The overall analytical data evaluation showed that 64% of z-scores obtained were outside the accepted limits. 相似文献
946.
We developed the detection apparatus that equipped with the two-photomultiplier tubes for chemiluminescence from singlet oxygen. Singlet oxygen was generated with reaction between sodium hypochlorite and hydrogen peroxide. The chemiluminescence from singlet oxygen, the dimol light emission (ca. 634 nm) and the monomol light emission (ca. 1270 nm), was observed simultaneously for the same reaction cell. The effects of sodium azide as an antioxidant, human serum albumin, and α-amino acids on the chemiluminescence based on the both emissions were examined; the observed chemiluminescence could provide direct information with regard to the reaction between singlet oxygen and antioxidant/biomolecules. The apparent rate constants for quenching singlet oxygen in the presence of human serum albumin were calculated to be ca. 3.3 × 109 and ca. 8.8 × 108 M−1 s−1 for the dimol and monomol light emissions, respectively, under the present conditions. The chemiluminescence intensities of the dimol emission decreased in the presence of His, Asp, Phe, Ser, and Tyr, and that of the monomol decreased in the presence of Cys and Trp. The chemiluminescence observed in the presence of biomolcules was discussed together with the reactivities of sodium hypochlorite and hydrogen peroxide to biomolecules. 相似文献
947.
We reported a simple and effective green chemistry route for facile synthesis of nanowire-like Pt nanostructures at one step. In the reaction, dextran acted as a reductive agent as well as a protective agent for the synthesis of Pt nanostructures. Simple mixing of precursor aqueous solutions of dextran and K2PtCl4 at 80 °C could result in spontaneous formation of the Pt nanostructures. Optimization of the experiment condition could yield nanowire-like Pt nanostructures at 23:1 molar ratio of the dextran repeat unit to K2PtCl4. Transmission electron microscopy results revealed that as-prepared nanowire-like Pt nanostructures consisted of individual Pt nanoparticles with the size range from 1.7 to 2.5 nm. Dynamic light scattering analysis indicated that as-prepared nanowire-like nanostructures have already formed in solution. The as-prepared nanowire-like Pt nanostructures were further characterized by UV-vis spectroscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. In addition, the ratio dependence and temperature dependence of this reaction have also been investigated. The as-prepared nanowire-like Pt nanostructures can be immobilized on glassy carbon electrodes using an electrochemical coupling strategy, and the resulting nanowire-like Pt nanostructures modified film exhibited an excellent electrocatalytic activity for the reduction of oxygen and the oxidation of NADH. 相似文献
948.
自2001年以来,双光子敏化产生单重态氧的三重态光敏剂的研究取得了一定的进展。双光子三重态光敏剂对肿瘤组织的近红外激光和红外激光的光动力治疗作用具有广阔的应用前景。本文重点分析了近些年已报道的双光子三重态光敏剂种类,如疏水性、水溶性等不同的敏化剂;介绍了可以根据分子的激发态性质、利用化学手段对双光子三重态敏化剂的性质以及光敏产生单重态氧的量子产率进行调控;概括了双光子三重态敏化剂的相对和绝对双光子横截面的测量方法;总结了双光子三重态敏化剂发展中面临的一些关键问题,并展望了双光子三重态敏化剂的发展方向。 相似文献
949.
Shiho Hirohara Makoto Obata Hiroki Alitomo Kohei Sharyo Tsuyoshi Ando Masao Tanihara Shigenobu Yano 《Journal of photochemistry and photobiology. B, Biology》2009,97(1):22-33
Eight S-glycosylated 5,10,15,20-tetrakis(tetrafluorophenyl)porphyrins (1a′, 1b′, 1a and 1b (a: S-glucosylated, b: S-galactosylated)) and their 1,3-dipolar cycloadducts, i.e. chlorins 2a′, 2b′, 2a and 2b were prepared by nucleophilic substitution of the pentafluorophenyl groups with S-glycoside. These photosensitizers were characterized by 1H, 13C and 19F NMR spectroscopies and elemental analysis. The photocytotoxicity of the S-glycosylated photosensitizers and the parent porphyrin (1) and chlorin (2) was examined in HeLa cells. Photosensitizers 1, 2, 1a′, 1b′, 2a′ and 2b′ showed no significant photocytotoxicity at the concentration of 0.5 μM, while the deprotected photosensitizers 1a, 1b, 2a and 2b were photocytotoxic. The strong inhibition by sodium azide of the photocytotoxicity of these photosensitizers suggested that 1O2 is the main mediator. The S-glucosylated photosensitizers 1a and 2a showed higher photocytotoxicity than S-galactosylated 1b and 2b, respectively. The cellular uptake of 1a and 2a increased up to 24 h, while that of 1b and 2b was saturated by 12 h. 相似文献
950.
A. V. Smolin B. I. Podlovchenko Yu. M. Maksimov 《Russian Journal of Electrochemistry》2009,45(3):246-251
The open circuit potential transients and cathodic potentiodynamic pulses were measured upon formaldehyde (methylene glycol) interaction with pre-adsorbed oxygen (Oads) on Pt/Pt and pc Pt electrodes in aqueous sulfuric acid solutions. The slowest interaction of CH2(OH)2 with Oads was observed in the high coverage range of the electrode surface (θO ~ 0.2 0.8 to 1). The process rate in this range is determined by the direct reaction of Oads with CH2(OH)2 molecules from the bulk solution. In the middle surface oxygen coverage range (θO 0.2 to 0.8), CH2(OH)2 interaction with Oads takes place by the mechanism of “conjugated reactions”. The kinetic parameters of reactions for CH2(OH)2, HCOOH, and CH3 OH were compared. The rate of CH2(OH)2-Oads interaction on Pt electrodes in the high oxygen coverage range was found higher by an order of magnitude than that of HCOOH and by two orders of magnitude than in the case of CH3OH. 相似文献