One-step synthesis of monodispersed Pt nanoparticles anchored on 3D graphene foams and its application for electrocatalytic hydrogen evolution

Although platinum-based materials are regarded as the state-of-the-art electro-catalysts for hydrogen evolution reaction(HER),high cost and quantity scarcity hamper their scale-up utilization in industrial deployment.Herein,a one-step strategy was developed to synthesize multi-walled carbon nanotubes and reduced graphene oxide supported Pt nanoparticle hydrogel(PtNP/rGO-MWCNT),in which only ascorbic acid was used as the reductant for one-pot reduction of both GO and chloroplatinic acid.The hydrogel can be directly used as a flexible binder-free catalytic electrode to achieve high performance of HER.Compared to conventional strategies,the current strategy not only significantly reduces the Pt loading to 3.48 wt%,simplifies the synthesis process,but also eliminates the use of any polymer binders,thus decreasing the series resistance and improving catalytic activity.An overpotential of only 11 mV was achieved on as-prepared PtNP/rGO-MWCNT to drive a geometrical current density of 10 mA/cm2 in0.5 mol/L H2 SO4,with its catalytic activity being kept over 15 h.In acidic medium,the HER activity of the PtNP/rGO-MWCNT catalyst exceeds most of the reported Pt-based electro-catalysts and is 3-fold higher than that obtained on commercial Pt/C electrode.     

An empirical re-examination of natural resource scarcity and economic growth

This paper is concerned with the effect of natural resource scarcity on economic growth in the United States. After defining the notion of scarcity and introducing two measures of scarcity—unit costs and relative resource price—changes in resource scarcity trends for lead, zinc, nickel, aluminium, silver, iron and copper over the most recent three decades are investigated. Only for silver and iron is there any indication that such a change has occurred. For silver, the change is transitory. To the extent that change takes place, it has implications for future economic growth, i.e. natural resource scarcity and economic growth are interrelated. To see whether this is a relevant concern, subsequent to the examination of changing resource scarcity trends an objective effort is made to identify a long-run equilibrium relationship between natural resource scarcity and economic growth. Relying on cointegration techniques, only for the unit cost measure for lead and copper for one of the measures of cointegration is there a suggestion that natural resource scarcity has affected economic growth in the United States over the period 1889–1992.     

斯特林制冷机通用化和系列化的技术经济效益分析

以实际数据分析了斯特林制冷机实行通用化、系列化所取得的和可以取得的技术、经济效益,阐明了在斯特林制冷机研制、生产中实施通用化、系列化的重要性。     

汇率变动对进出口影响的实证分析

本文研究了汇率变动对中国进出口的影响,在间接标价法下对论文中所用到的汇率贬值改善国际收支的三个必要条件给出了结论和证明(弹性法);在经济理论及经验研究的基础上,建立了论文中所需要的所有模型并且根据模型对相关经济问题利用现代计量经济学方法进行了实证研究.通过实证研究我们得到的结论是:我国满足汇率贬值改善国际收支的必要条件;出口增加有助于GDP的增长,进口增加对GDP的影响是反向的且随着进口增加这种影响逐渐减弱最终趋于零.     

相对性区域创新指数与经济周期挖掘

提出了一类新的相对性区域创新指数,并采用世界专利申请数据对其进行了具体计算.基于区域创新同经济发展水平之间的超线性关系,该指数消除了经济发展水平对创新能力的影响,可以实现对不同发展水平的经济体之间进行有效的创新能力横纵对比.该创新指数尽管极其简单,却揭示出一系列迥异于传统认知的现象,例如中国大陆地区的技术创新能力在1980年代就已经位居世界前列.采用该指数,不但可以在较高水平上解释世界各国的经济增长,还发现它同经济增长率之间的相关性存在一个20年的经济周期.这些结果显示,该指数作为一个单一性指标,以极小的数据依赖就实现了较高程度的解释性,不但重新定位了世界各经济体的创新能力,对深入理解创新同经济发展之间的关系提供了新的角度,而且暗示着这类相对性经济指标的发展潜力与应用空间.     

Development of low concentrated solar photovoltaic system with lead acid battery as storage device

Energy storage system powered by renewable energies is a viable option to meet energy requirement without addition of carbon footprints to the environment. This study involves development of theoretical and computational models for a solar photovoltaic (PV) system coupled with a lead acid battery. The study commenced with selection of most appropriate lead acid battery and PV system for installation in a representative location in Riyadh, Kingdom of Saudi Arabia. Various technical and economic parameters were assessed and calculated by computational approach. The optimized lead acid battery was integrated with low concentration solar PV panels (CPV) followed by a feasibility study. Theoretical model was developed for the integrated system to calculate various parameters of the CPV and lead acid battery. Technical and economic assessment of this coupled unit was calculated using a theoretical approach. The developed model was then subjected to computational approach for verification and validation analysis of the integrated system. The detailed assessment of batteries and integrated system show the applicability of this system in Riyadh region. The research will be extended to develop energy storage systems for remote areas using lead acid batteries.     

数学建模融入经济数学教学中的案例及分析

经济数学是财经类专业的重要基础课程,在经济数学教学中讲授数学的基本概念和定理的同时,怎样引入数学模型进行教学,培养和激发学生学习数学的兴趣,是我们从事经济数学教学的教师都应该探讨的问题.本文结合经济数学教学的实践,介绍了经济数学教学中的几个经典经济模型案例,将数学与经济学有机地联系起来,让数学变得既生动又符合实际,取得了很好的教学效果.     

Linear stability analysis of a boundary crisis in a minimal chaotic flow

We present a mechanism that explains the boundary crisis presented by the first Malasoma class P minimal chaotic flow, which is equivalent to the simplest Sprott flow. The treatment followed resorts to the existence of two invariant sets of points of the flow, in addition to the chaotic attractor, to which linear stability theory is applied.     

Critical comparison of several order-book models for stock-market fluctuations

Far-from-equilibrium models of interacting particles in one dimension are used as a basis for modelling the stock-market fluctuations. Particle types and their positions are interpreted as buy and sel orders placed on a price axis in the order book. We revisit some modifications of well-known models, starting with the Bak-Paczuski-Shubik model. We look at the four decades old Stigler model and investigate its variants. One of them is the simplified version of the Genoa artificial market. The list of studied models is completed by the models of Maslov and Daniels et al. Generically, in all cases we compare the return distribution, absolute return autocorrelation and the value of the Hurst exponent. It turns out that none of the models reproduces satisfactorily all the empirical data, but the most promising candidates for further development are the Genoa artificial market and the Maslov model with moderate order evaporation.