大口径宽视场双波段扫描红外相机光学设计

通过分析计算,设计了一种大口径宽视场折射式红外相机光学系统。该系统设计用于超长线阵扫描红外相机的地面演示成像,它能同时对短波2μm—3μm、中波3μm—4.5μm双波段成像,且同时具有24°的大视场和150mm的宽口径,成像质量接近衍射极限。该系统在航天遥感领域应用广泛。     

Topological Aspects of Superconductors at Dual Point

We study the properties of the Ginzburg-Landau model at the dual point for the superconductors. By making use of the U（1） gauge potential decomposition and the φ-mapping theory, we investigate the topological inner structure of the Bogomol＇nyi equations and deduce a modified decoupled Bogomol＇nyi equation with a nontrivial topological term, which is ignored in conventional model. We find that the nontrivial topological term is closely related to the N-vortex, which arises from the zero points of the complex scalar field, Furthermore, we establish a relationship between Ginzburg Landau free energy and the winding number.     

诱惑态在“双探测器”准单光子光源量子密钥分发系统中的应用

现在诱惑态已被证明是一种可以大大提高量子密钥分发安全性能的现实可行的方法.由于考虑到现实应用中激光器在调制过程中的消光比不能做到100%，以及激光器固有的自发辐射因而使得制备真空态并不是一件容易的事情. 因此本文将对理想情况下准单光子光源量子密钥分发系统应用中的诱惑态结论作了补充和扩展，提出了两个弱光强态的诱惑态方案和一个弱光强诱惑态方案.最后，将“双探测器”的理论应用在准单光子源(HSPS)光源系统中，使系统的安全传输距离可达到2215km，比使用普通探测器的系统增加了约50km.     

Transesterification of an RNA model in buffer solutions in H2O and D2O

Transesterification of a phosphodiester bond of RNA models has been studied in various buffer solutions, under neutral and slightly alkaline conditions in H₂O and D₂O. The results show that imidazole is the only buffer system where a clear buffer catalysis on the cleavage of a phosphodiester bond is observed. The rate enhancement in sulphonic acid buffers is smaller, and a sulphonate base, particularly, is inactive as a catalyst. The rate‐enhancing effect of imidazole is, however, catalytic, and the catalytic inactivity of sulphonate buffers can be attributed to their structure and/or charge. The catalysis by imidazole is a complex system which, in addition to first‐order reactions, involves a process that shows a second‐order dependence in imidazole concentration. The latter reaction becomes significant in acidic imidazole buffers (pH < pK_a), as the buffer concentration increases. The kinetic solvent deuterium isotope effect k_H/k_D, referring to first‐order catalysis by imidazole base, is 2.3 ± 0.3. That referring to second‐order catalysis is most probably much larger, but an accurate value could not be obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

双波长高精度红外测温仪

利用双波长红外测温方法,通过黑体红外辐射曲线中双波长等比吸收的原理消除了由于辐射环境中水蒸气等外界吸收原因造成的单波长红外测温仪中的测量误差,实现更稳定的高精度红外测温.该方法绕开了传统红外测温方法中"辐射率修正困难"的问题.同时利用此红外测温仪器改进了金属钨电子逸出功测量实验.     

Spectrophotometric and spectrofluorimetric investigation of different equilibria of a recently synthesized Schiff base with the aid of chemometric methods

In this study ground and excited states acidic dissociation constants of a recently synthesized Schiff base was obtained in a DMF:water mixture of 30:70 (v/v) using absorption and fluorescent spectra of the Schiff base in different pH values with the aid of chemometric methods. In addition, the fluorescent of the two kinds of tautomers of this Schiff base was investigated and the rate of tautomerization was obtained using rank annihilation factor analysis (RAFA). The effect of different kinds of surfactants such as sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB) and Triton X-100 on fluorescence spectrum of the Schiff base in a DMF:water mixture of 2:98 (v/v) was investigated. CTAB increased the fluorescence intensity of the Schiff base while SDS and Triton X-100 had no significant effect on it. β-Cyclodextrin increased the fluorescence intensity of the Schiff base. Also the sensing behavior of this Schiff base toward metal ions was studied in DMF and ethanol by fluorescence spectroscopy. The Schiff base showed prominent fluorescent signal in the presence of Zn²⁺, whereas other metal ions failed to induce response and ground-state dissociation constant of the complex was determined by direct fluorimetric titration as a function of Zn²⁺ concentration.     

基底对亚波长金属双环结构太赫兹透射性质的影响

太赫兹波通过人工金属亚波长结构开口共振环(SRRs)可以产生共振吸收, 目前普遍采用LC振荡电路和线性振子模型来解释. 利用太赫兹时域光谱系统测得并无开口的亚波长金属双环和反双环结构阵列透射的太赫兹波, 结果仍然观察到在太赫兹透射谱中存在吸收峰. 分析得出此吸收峰的出现可以用线性振子模型解释. 此外, 研究发现若将此结构制作到石英基底上, 当以样品表面法线方向为轴旋转样品时其太赫兹透射时域波形和频谱均会随旋转角度出现明显的周期性变化, 而以硅为基底并不出现此现象. 本文将其原因归结为石英基底的双折射效应对亚波长金属双环结构太赫兹透射性质的影响. 本文主要目的是分析造成这种影响的物理过程.     

Improved performance of organic light-emitting diodes with dual electron transporting layers

In this study the performance of organic light-emitting diodes(OLEDs) are enhanced significantly,which is based on dual electron transporting layers(Bphen/CuPc).By adjusting the thicknesses of Bphen and CuPc,the maximal luminescence,the maximal current efficiency,and the maximal power efficiency of the device reach 17570 cd/m2 at 11 V,and 5.39 cd/A and 3.39 lm/W at 3.37 mA/cm2 respectively,which are enhanced approximately by 33.4%,39.3%,and 68.9%,respectively,compared with those of the device using Bphen only for an electron transporting layer.These results may provide some valuable references for improving the electron injection and the transportation of OLED.     

大型双反射面天线近轴区辐射FDTD-TDPO模拟

针对大型双反射面天线尺寸过大、使用单一的时域方法无法单独模拟其远区辐射特性,以及使用单一的高频近似技术无法给出准确结果的局限,给出了用于大型双反射面天线时域辐射模拟的并行时域有限差分(PFDTD)-并行时域物理光学(PTDPO)混合方法。先创建两个用于并行计算的进程组,一个用于PFDTD计算,另一个用于PTDPO计算; 再根据PFDTD方法计算出双反射面天线馈源的近磁场,同时根据这些磁场使用基尔霍夫表面积分表达式(KSIR)并行计算出次反射面上及其附近的磁场,再使用KSIR并行计算出主反射面上的磁场; 最后使用PTDPO方法计算出双反射面天线的远区辐射场的瞬态响应。同时,还给出主反射面口径为40个波长的Cassegrain双反射面天线的算例,并对馈源相同而口径尺寸不同的双反射面天线进行近轴区的时域辐射模拟。     

一个基于Multi-agent的决策支持系统的设计

在DSS开发中，引入agent技术，提出了一个基于Multi-agent的决策支持系统的框架结构设计并为该系统的造界面Aent、信息Agent，模型Agent和管理Agent，在实际使用中，取得了良好的效果。