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81.
R. De
Lisi G. Lazzara S. Milioto N. Muratore 《Journal of Thermal Analysis and Calorimetry》2007,87(1):61-67
Macromolecule/laponite nanomaterials were
studied by DSC and X-ray diffraction techniques. The matrices are poly(ethylene)
glycols at various molecular masses and poly(ethylene oxides)-poly(propylene
oxides)-poly(ethylene oxides) tri-block copolymers. The latter were tuned
by modulating the molecular masses, at constant hydrophilic/hydrophobic ratio,
and the hydrophilicity. For all the investigated systems, the enthalpy of
melting (ΔH
m)
is nearly constant up to a given composition thereafter it increases monotonically
reaching the value of the pure macromolecule. We proposed a model to interpret
the DSC data.
Briefly, it was invoked a mechanism of interaction
following which some segments of the adsorbed macromolecule are anchored to
the laponite (RD) particles and the remaining segments are radiating away
from the surface. The portion of the macromolecule in contact with RD does
not contribute to ΔH
m
whereas that radiating away from the clay does. Once that the RD surface is
saturated, the excess of the macromolecule behaves like the pure one. The
proposed model allowed to compute successfully the ΔH
m
values. The X-ray diffraction experiments ruled out the polymer intercalation
between the silicate sheets. 相似文献
82.
Qing-de Chen Xing-hai Shen 《高分子科学》2005,(6):635-642
In the UV-Vis spectra of pure light-scattering systems, there is an exponential relationship between absorbance and wavelength (A = Kλ^-n). Here, the exponent n is named as flocculation-coagulation parameter. In the present paper, the effects of different additives on the stability of poly(N,N'-methylenebisacrylamide-co-4-vinylpyridine) (poly(Bis-co-4-VP)) microgel dispersion were studied in detail via this parameter. The results showed that the stability of the dispersion mainly comes from the ionization of pyridine groups, making the microgel positively charged on its surface. This was confirmed by the measurement of Zeta potential and the result of conductometric titration. The result of fluorescence analysis indicated that the hydrophobicity in the microgels is enhanced with the increase in total 4-VP unit content. 相似文献
83.
84.
J. Eisenlauer 《Colloid and polymer science》1984,262(11):906-910
Different results from recent communications on the hydrodynamic characterization of ultrasonicated silica (®Aerosil) hydrosols led to a critical reappraisal of the data.It can be concluded that the degree of dispersion achievable in pyrogenic (Aerosil) hydrosols by ultrasonication is highly sensitive to the detailed parameters of the dispersion process. Characterization in terms ofabsolute numbers of a limiting particle morphology, corresponding to minima of aggregate size, porosity and number of primary particles in the aggregate is not possible.The most straightforward approach for hydrodynamic characterization seems to be a combination of sedimentation and diffusion data.Other approaches using a combination of sedimentation and viscosity data underestimate the particle dimensions. Moreover, they are quite arbitrary since the final result depends upon the proper choice between several equations for fitting the viscosity concentration dependence; the most rigorous approach seems to be an extended Einstein equation which has recently been adapted to particle aggregates. 相似文献
85.
K. Asami 《Colloid and polymer science》1998,276(4):373-378
A dielectric imaging technique with a scanning dielectric microscope was applied to polystyrene microcapsules in an aqueous
environment to study the electrical properties of individual ones. The dielectric images obtained over a frequency range from
10 kHz to 10 MHz showed frequency dependence, which indicated dielectric dispersion (or relaxation) due to interfacial polarization
or the build up of charge on the boundaries between the microcapsule shell and the aqueous phases. The dielectric dispersion
was analyzed based on an equivalent electrical circuit model and a shell-sphere model in which a spherical core is covered
with an insulating shell.
Received: 26 September 1997 Accepted: 26 December 1997 相似文献
86.
J. M. Ginés M. J. Arias J. R. Moyano Cs. Novak G. Pokol P. J. Sánchez-Soto 《Journal of Thermal Analysis and Calorimetry》1996,47(6):1743-1753
A thermal study using DSC and Hot Stage Microscopy (HSM) was carried out to investigate the interaction in solid state of the binary system PEG 4000 — oxazepam, and to establish their phase diagram. The eutectic composition, which melting occurs at lower temperature as compared with the pure components, has been determined. The results obtained by DSC and HSM have indicated that PEG 4000 — oxazepam mixtures displays no obvious incompatibilities, and that the system shows a typical eutectic behaviour. However because of the closeness of the melting of PEG 4000 to the eutectic temperature, it was difficult to determine precisely the eutectic composition and temperature on the basis of DSC measurements alone. The use of heats of fusion corresponding to physical mixtures allowed an estimation of the eutectic composition at 6% w/w oxazepam. Additional information of temperature (57.6C) and composition (5–10% w/w oxazepam) of the eutectic was obtained by HSM using the contact method. This low melting temperature in this range of compositions offers advantages in terms of drug stability and easy manufacture. 相似文献
87.
The phonon dispersion curves, phonon frequency distribution function as well as the lattice specific heat of body-centred
tetragonal indium have been deduced using a lattice dynamical model which includes central, angular and volume forces. Six
elastic constants, four zone boundary frequencies and an equilibrium condition were used in the evaluation of the force constants.
It is shown that this model is elastically consistent and satisfies the symmetry requirements of the lattice, the phonon frequencies
of indium deduced from it are in very good agreement with the experimental values of Reichardt and Smith and the theoretical
values of Garrett and Swihart, and theθ
D values compare well with the experimental values over a wide temperature range. The apparent discrepancies in the phonon
dispersion curves and theθ
D-T curves obtained from deficient models, importance of umklapp processes and the significance of angular forces in the lattice
dynamical models are discussed. 相似文献
88.
TiO2-双亲共聚物复合纳米粒子的合成与紫外光敏特性 总被引:3,自引:0,他引:3
用偶联剂乙烯基三乙氧基硅烷改性纳米粒子TiO2, 应用超声技术将TiO2 纳米粒子分散在甲醇介质中, 然后用苯乙烯(ST)原位聚合包封, 再用丙烯酰胺或乙烯基吡咯烷酮(VP)共聚, 两步原位分散聚合得到了有机聚合物为壳、TiO2为核的有机/无机复合粒子. 用红外光谱、紫外-可见光谱、透射电子显微镜等检测手段进行表征. 结果显示: 由于双亲共聚物对TiO2纳米粒子的敏化作用, 紫外-可见光谱图上两种纳米复合粒子的最大吸收峰均有明显红移, 并且吸收光谱的范围扩大了, 其中尤以TiO2/(PST-co-PVP)为甚. 意味着光敏化活性的提高, 特别是在可见光谱的范围内. 这种情形对宽带隙半导体材料如TiO2纳米粒子的光催化特性是有利的, 表明这类材料的应用空间得到了拓展. 相似文献
89.
Lars Rummel Jan M. Schümann Prof. Dr. Peter R. Schreiner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(55):13699-13702
We present a computational analysis of hexaphenylethane derivatives with heavier tetrels comprising the central bond. In stark contrast to parent hexaphenylethane, the heavier tetrel derivatives can readily be prepared. In order to determine the origin of their apparent thermodynamic stability against dissociation as compared to the carbon case, we employed local energy decomposition analysis (LED) and symmetry-adapted perturbation theory (SAPT) at the DLPNO-CCSD(T)/def2-TZVP and sSAPT0/def2-TZVP levels of theory. We identified London dispersion (LD) interactions as the decisive factor for the molecular stability of heavier tetrel derivatives. This stability is made possible owing to the longer (than C−C) central bonds that move the phenyl groups out of the heavily repulsive regime so they can optimally benefit from LD interactions. 相似文献
90.