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991.
Christensen O. F. Møller J. Waagepetersen R. P. 《Methodology and Computing in Applied Probability》2001,3(3):309-327
Conditional simulation is useful in connection with inference and prediction for a generalized linear mixed model. We consider random walk Metropolis and Langevin-Hastings algorithms for simulating the random effects given the observed data, when the joint distribution of the unobserved random effects is multivariate Gaussian. In particular we study the desirable property of geometric ergodicity, which ensures the validity of central limit theorems for Monte Carlo estimates. 相似文献
992.
非理想二元表面活性剂复配增效理论的进一步研究 总被引:3,自引:0,他引:3
在Rubingh与Rosen 提出非理想二元表面活性剂复配增效条件基础上,利用相分离模型和正规溶液理论,导出了体系降低表面张力的能力增效条件βs-βm<0,及最佳摩尔分数α1*、最低表面张力γ*cmc12和γ*cmc处对应的临界胶束浓度cmc*12.通过作三条γ~logc曲线或两条γ~logc曲线加上一个cmc值的方法,对C12NMe3Br~C12SO4Na、 C12NMe3Br~C8SO4N两种复配体系进行验证,计算结果与实验结果相符. 相似文献
993.
994.
利用浓盐酸脱苯基方法合成混合二烃基二氯化锡 总被引:1,自引:1,他引:0
利用RSnPh3(R= Me3SiCH2、EtMe2SiCH2、Bu)和浓盐酸直接混合加热反应,合成了三种混合二烃基二氯化锡,通过IR,1H NMR和MS的测定,对产物的结构进行了表征;并探讨了反应时间、温度和浓盐酸用量对该反应产率的影响.实验结果表明,该方法与其它方法比较,具有操作简单、反应速度快、环境污染小、产率较高等特点;当四烃基锡与浓盐酸的物质的量比为1:8,在97 ℃反应7 min,混合二烃基二氯化锡的产率大于70%. 相似文献
995.
混合交通OD分布与随机平衡分配组合模型及算法 总被引:4,自引:0,他引:4
罗文昌 《宁波大学学报(理工版)》2007,20(4):481-486
基于我国城市混合交通的特点,借助于Logit选择模型,建立了混合交通OD分布与随机平衡分配组合的数学规划模型,证明了模型最优解的等价性与唯一性,同时给出了算法和算例. 相似文献
996.
Huan Qing 《Entropy (Basel, Switzerland)》2022,24(8)
In network analysis, developing a unified theoretical framework that can compare methods under different models is an interesting problem. This paper proposes a partial solution to this problem. We summarize the idea of using a separation condition for a standard network and sharp threshold of the Erdös–Rényi random graph to study consistent estimation, and compare theoretical error rates and requirements on the network sparsity of spectral methods under models that can degenerate to a stochastic block model as a four-step criterion SCSTC. Using SCSTC, we find some inconsistent phenomena on separation condition and sharp threshold in community detection. In particular, we find that the original theoretical results of the SPACL algorithm introduced to estimate network memberships under the mixed membership stochastic blockmodel are sub-optimal. To find the formation mechanism of inconsistencies, we re-establish the theoretical convergence rate of this algorithm by applying recent techniques on row-wise eigenvector deviation. The results are further extended to the degree-corrected mixed membership model. By comparison, our results enjoy smaller error rates, lesser dependence on the number of communities, weaker requirements on network sparsity, and so forth. The separation condition and sharp threshold obtained from our theoretical results match the classical results, so the usefulness of this criterion on studying consistent estimation is guaranteed. Numerical results for computer-generated networks support our finding that spectral methods considered in this paper achieve the threshold of separation condition. 相似文献
997.
The Erd?s–Gallai Theorem states that every graph of average degree more than contains a path of order for . In this paper, we obtain a stability version of the Erd?s–Gallai Theorem in terms of minimum degree. Let be a connected graph of order and be disjoint paths of order respectively, where , , and . If the minimum degree , then except several classes of graphs for sufficiently large , which extends and strengths the results of Ali and Staton for an even path and Yuan and Nikiforov for an odd path. 相似文献
998.
This article is concerned with the Stokes system with nonhomogeneous source terms and nonhomogeneous Dirichlet boundary condition. First, we reformulate the problem in its dual mixed form, and then, we study its corresponding well-posedness. Next, in order to circumvent the well-known Babuška-Brezzi condition, we analyze a stabilized formulation of the resulting approach. Additionally, we endow the scheme with an a posteriori error estimator that is reliable and efficient. Finally, we provide numerical experiments that illustrate the performance of the corresponding adaptive algorithm and support its use in practice. 相似文献
999.
Sergiu Shova Vasile Tiron Angelica Vlad Ghenadie Novitchi Dan G. Dumitrescu Madalin Damoc Mirela-Fernanda Zaltariov Maria Cazacu 《应用有机金属化学》2020,34(12):e5957
A di-manganese(III) complex structure was built by an original approach consisting of a two-step procedure. First, the mononuclear complex of the manganese(III) with the Schiff base of the salen-type ligand (H2L) derived from 1,3-bis(3-aminopropyl)tetramethyldisiloxane and 3,5-di-tert-butyl-2-hydroxybenzaldehyde was prepared. The main feature of note is the 12-membered chelate ring formed upon coordination of the Schiff base to central atom, which adopts a distorted N2O4 octahedron environment. In the second step, the acetato co-ligand in this complex is replaced by the carboxylate anion of a dicarboxilic acid, namely adipic acid. This metathesis reaction leads to the formation of dinuclear structure by connecting two manganese centers. The structure, as was determined by X-ray single crystal diffractometry, elemental and spectral analysis, is permethylated dinuclear complex with long aliphatic bridge. Thermal and magnetic properties were studied. In addition, the formation of magnetically induced stripe-ordered domains was highlighted by the magnetic force microscopy (MFM) on films born from diluted solution. 相似文献
1000.
《Mendeleev Communications》2020,30(5):589-591
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