Improved Si NMR detection of sterically protected fluorosilanes using the Si(F)-INEPT technique

The ²⁹Si-¹⁹F INEPT NMR method has been applied to significantly reduce the recording time of ²⁹Si NMR spectra of sterically shielded fluorosilanes. This technique furthermore improves the signal to noise ratio to a degree which allows the simultaneous detection of minor byproducts which are below the detection limit using direct acquisition.     

D－木呋喃糖1，2，5位羟基的选择性保护

本文介绍了Ｄ－木呋喃糖１，２，５位羟基的选择性保护的两种途径，对其优越性进行了对比，改进了实验条件，提高了产率，所得化合物的物理数据均与文献值相吻合．     

降雨冲刷对黄土公路边坡植物防护影响的试验研究

通过对裸露黄土公路边坡、厚层基材植草公路边坡、三维网植草公路边坡以及平台植树公路边坡的现场降雨冲刷试验,阐述了不同防护型式的公路黄土边坡在降雨条件下的坡面径流、含泥量以及坡面冲刷情况,得出了"降雨对边坡坡面的侵蚀过程,首先是从雨滴直接打击土体开始,进而引起溅蚀,分散土粒,紧接着发生超渗径流造成坡面冲刷。"以及"对坡面破坏最大的是坡顶上方来水"等重要结论。验证了坡面植物防护以及平台植树等防护方法可以有效降低降雨冲刷对坡面的侵蚀破坏,为黄土地区公路边坡植物防护的设计施工以提供了可靠的依据。     

波长校准用低压石英汞灯驱动电源的研制

研制波长校准用低压石英汞灯电源,用于驱动汞灯起辉并维持稳态发光。电路由EMI滤波电路、桥式整流电路、LCC半桥谐振逆变电路、控制电路和保护电路5部分组成。采用系统建模与仿真验证电路的可行性并计算电路参数理论值,利用示波器和功率表验证电源输出参数,功率输出稳定性不大于0.03 W。根据紫外可见近红外分光光度计国防最高计量标准对研制的电源驱动汞灯的工作效果进行评价。结果表明,汞灯能够输出系列特征谱线,谱线相对强度稳定性不大于5.16%;汞灯工作3 h后,灯管外壳表面温度为43℃。该驱动电源的性能参数满足JJG112–2015《低压石英汞灯波长标准器检定规程》的要求。     

Contaminant concentration on pipe walls following radial jet injection: a computational fluid dynamics approach

A computational fluid dynamics technique has been used to predict the likely concentration levels along a pipe wall of chemicals injected radially from a nozzle. No published empirical data appear to be available, despite the importance of this subject in protecting pipe walls in the vicinity of the dosing point if the chemicals and pipe materials are incompatible. Validation of predictions is by comparison with experimental data for other parameters related to the flow. Where possible, results have been analyzed and presented in dimensionless form so that the article can act as a more generally useful design guide.     

基于数字微镜阵列光调制的激光防护系统

提出一种基于数字微镜阵列(DMD)的激光防护系统设计方案, 利用DMD的光调制作用减少强激光对光电成像设备的损坏.详细介绍了系统的工作原理、DMD及CCD的选型、投影光路和光学转换系统的设计, 运用相移莫尔法进行了图像像素的调校.模拟实验结果显示, 该系统可在不同光斑半径和光强的条件下成功识别激光光斑中心点的像素坐标和半径, 实现对光斑对应区域的微反射镜控制, 激光光强可衰减70%以上.     

Liquid extraction surface analysis in-line coupled with capillary electrophoresis for direct analysis of a solid surface sample

A surface-sampling technique of liquid extraction surface analysis (LESA) was in-line coupled with capillary electrophoresis (CE) to expand the specimen types for CE to solid surfaces. The new direct surface analysis method of LESA–CE was applied to the determination of organophosphorus pesticides, including glufosinate-ammonium, aminomethylphosphonic acid, and glyphosate on the external surface of a fruit such as apple. Without any sample pretreatment, the analytes sprayed on the surface of a half apple were directly extracted into a liquid microjunction formed by dispensing the extractant from the inlet tip of a separation capillary. After extraction, the analytes were derivatized in-capillary with a fluorophore 4-fluoro-7-nitro-2,1,3-benzoxadiazole and analyzed with CE-laser induced fluorescence (LIF). The limits of detection for glufosinate-ammonium, aminomethylphosphonic acid, and glyphosate were 2.5, 1, and 10 ppb, respectively, which are at least 20 times lower than the tolerance limits established by the U.S. Environmental Protection Agency. Thus, we demonstrated that LESA–CE is a quite sensitive and convenient method to determine analytes on a solid surface avoiding the dilution from sample pretreatment procedures including homogenization of a bulk sample.     

Simple and Efficient Method for the Protection of Hydroxyl Groups as 4-Methoxybenzyl Ethers

PMB ethers of alcohols are obtained in good yields and under mild conditions using the 4-methoxybenzyl N-allyl thiocarbamate and N-bromosuccinimide (NBS)/TfOH as the catalyst. The present method is very fast, simple, and efficient.     

Microwave-assisted synthesis of 1,3-benzodioxole derivatives from catechol and ketones or aldehydes

An efficient synthetic procedure for the preparation of a diverse library of 1,3-benzodioxoles was developed by applying controlled microwave heating in comparison with currently available conventional heating. Reactions were completed in less than 3 h. The isolation of product is simple, the isolated yields are good to excellent, and this method is applicable to large scale production.     

溶胶-凝胶-水热晶化法制备锐钛矿TiO2纳米膜的耐蚀性能

以钛酸正丁酯为前驱体, 采用溶胶-凝胶-水热晶化法在不锈钢(SS)表面制备TiO₂纳米膜. 利用X射线衍射(XRD)、Raman光谱、场发射扫描电子显微镜(SEM)、原子力显微镜(AFM)和俄歇电子能谱(AES)表征了TiO₂纳米膜的晶型、表面形貌和表面化学组成. 通过极化曲线和电化学阻抗谱(EIS)研究了TiO₂纳米膜的耐蚀性能. 170 °C下水热晶化制备的锐钛矿TiO₂与450 °C焙烧制备的锐钛矿TiO₂的结晶度类似, 但两种TiO₂薄膜的表面结构存在明显差异, 水热晶化法制备的TiO₂纳米膜在3.5% (w) NaCl溶液中的耐蚀性能优于焙烧法制备的.