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41.
金属的冲击温度及熔化温度测量对构建其完全状态方程具有重要意义。简要综述了用于金属冲击温度及熔化温度辐射法测量的一维热传导理想界面模型和非理想界面模型,并着重对模型中明示或隐含的关键假定的合理性、影响金属冲击温度与熔化温度结果的主要因素进行了分析、讨论,以期对实验数据有一个合理的评估。还讨论了求解理想和非理想界面模型一维热传导方程界面温度时所隐含的冲击压缩下热导率不随温度而变、冲击压缩下金属样品/窗口界面辐射的灰体假定,以及窗口材料的透明性、非理想界面模型中表观界面温度的修正、动载条件下金属高压熔化温度的测量、界面的非Flourier热传导等问题。分析结果表明,目前采用辐射法测量大致可以得到冲击温度,在发生熔化的情况下可获得熔化温度,但离精密测量的要求还有较大差距。 相似文献
42.
使用Galerkin方法,结合Sobolev空间理论和不等式技巧,给出了广义神经传播方程解的存在唯一性定理,然后利用吸引子存在性定理,采用半群方法证明了方程整体吸引子的存在性. 相似文献
43.
通过第一原理电子结构计算来研究有序多孔纳米网的电导特性变化的能带机理.能带结构分析结果表明:石墨烯纳米网超晶格(3m,3n)(m和n为整数)的电子本征态在布里渊区中心点发生四重简并;碳空位孔洞规则排列形成的石墨烯纳米网具有由简并态分裂形成的宽度可调带隙,无论石墨烯的两个子晶格是否对等.在具有磁性网孔阵列的石墨烯纳米网中,反铁磁耦合使对称子晶格的反演对称性增加了一项量子限制条件,导致能带结构在K点的二重简并态分裂成带隙.通过控制网孔密度能够有效调节石墨烯纳米网的带隙宽度,为实现新一代石墨烯纳米电子器件提供了理论依据. 相似文献
44.
A. D. Kirillov N. P. Kakurkin V. V. Shcherbakov 《Russian Journal of Electrochemistry》2007,43(1):114-117
The electroconductivity of calcium oxide-ethylene glycol (EG) and calcium oxide-EG-water systems is measured in wide ranges of temperatures and compositions. With increasing temperature, the conductivity of the former system passes through a maximum, which shifts to lower temperatures with increasing electrolyte concentration. Thermodynamic characteristics of the calcium hydroxy glycolate association in EG are estimated using the Lee-Wheaton equation. The conductivity of the latter system decreases with increasing EG content. Its dependence on the limiting high-frequency conductivity of the mixed solvent is analyzed. The activation energy for conduction in both systems decreases with increasing temperature and electrolyte concentration. 相似文献
45.
W. Russ Algar 《Analytica chimica acta》2010,673(1):1-25
A comprehensive review of the development of assays, bioprobes, and biosensors using quantum dots (QDs) as integrated components is presented. In contrast to a QD that is selectively introduced as a label, an integrated QD is one that is present in a system throughout a bioanalysis, and simultaneously has a role in transduction and as a scaffold for biorecognition. Through a diverse array of coatings and bioconjugation strategies, it is possible to use QDs as a scaffold for biorecognition events. The modulation of QD luminescence provides the opportunity for the transduction of these events via fluorescence resonance energy transfer (FRET), bioluminescence resonance energy transfer (BRET), charge transfer quenching, and electrochemiluminescence (ECL). An overview of the basic concepts and principles underlying the use of QDs with each of these transduction methods is provided, along with many examples of their application in biological sensing. The latter include: the detection of small molecules using enzyme-linked methods, or using aptamers as affinity probes; the detection of proteins via immunoassays or aptamers; nucleic acid hybridization assays; and assays for protease or nuclease activity. Strategies for multiplexed detection are highlighted among these examples. Although the majority of developments to date have been in vitro, QD-based methods for ex vivo biological sensing are emerging. Some special attention is given to the development of solid-phase assays, which offer certain advantages over their solution-phase counterparts. 相似文献
46.
47.
48.
采用分子动力学方法模拟了固态氩的纳米变截面结构的导热性质,研究发现纳米变截面材料的热阻和热流的大小与方向都相关:当纳米结构沿热流的方向为渐缩时,纳米结构的热阻随热流的增加而增大,而当纳米结构沿热流的方向为渐扩时,纳米结构的热阻随热流的增加呈减小的趋势;当热流较大时,热流沿渐缩方向时的热阻明显大于热流沿渐扩方向时的热阻,但当热流较小时纳米变截面结构的热阻和热流方向的关系不大.最后依据热质的运动和传递理论的动能效应对该现象进行了分析解释. 相似文献
49.
L. Raymond J.-M. Laugier S. Schäfer G. Albinet 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,31(3):355-364
Binary disordered systems are usually obtained by mixing two ingredients in variable proportions: conductor and insulator,
or conductor and super-conductor. They present very specific properties, in particular the second-order percolation phase
transition, with its fractal geometry and the multi-fractal properties of the current moments. These systems are naturally
modeled by regular bi-dimensional or tri-dimensional lattices, on which sites or bonds are chosen randomly with given probabilities.
The two significant parameters are the ratio h = σ
1/σ of the complex conductances, σ and σ
1, of the two components, and their relative abundances p (or, respectively, 1 - p). In this article, we calculate the impedance of the composite by two independent methods: the so-called spectral method,
which diagonalises Kirchhoff's Laws via a Green function formalism, and the Exact Numerical Renormalization method (ENR). These methods are applied to mixtures of
resistors and capacitors (R-C systems), simulating e.g. ionic conductor-insulator systems, and to composites constituted of resistive inductances and capacitors (LR-C systems),
representing metal inclusions in a dielectric bulk. The frequency dependent impedances of the latter composites present very
intricate structures in the vicinity of the percolation threshold. In this paper, we analyse the LR-C behavior of compounds
formed by the inclusion of small conducting clusters (“n-legged animals”) in a dielectric medium. We investigate in particular their absorption spectra who present a pattern of sharp
lines at very specific frequencies of the incident electromagnetic field, the goal being to identify the signature of each
animal. This enables us to make suggestions of how to build compounds with specific absorption or transmission properties
in a given frequency domain.
Received 16 August 2002 Published online 14 February 2003
RID="a"
ID="a"e-mail: laurent.raymond@l2mp.fr
RID="b"
ID="b"e-mail: steffen.schaefer@l2mp.fr
RID="c"
ID="c"UMR CNRS 6137 相似文献
50.
The ionic conduction properties of undoped and doped Tl4HgI6 were investigated using electrical conductivity, dielectrics, differential scanning calorimetry, and X-ray diffraction techniques.
The heavy Tl+-ions diffusion was activated at high temperature, whereas low conductivity at the lower temperature suggested electronic
contribution in undoped Tl4HgI6. The partial replacement of heavy Tl+ ion by suitable cations (Ag+ and Cu+) enhanced the conductivity by several orders of magnitude, whereas diminution in conductivity results with increasing dopants’
concentration in Tl4HgI6. These results can be interpreted in terms of a lattice contraction and vacancy–vacancy interaction (leading to the cluster
formation), respectively. The dielectric values of undoped Tl4HgI6 system gradually increasing with temperature, followed by a sharp change, were observed around 385 K and can be explained
on the basis of increasing number of space charge polarization and ions jump orientation effects. The activation energy of
undoped and doped Tl4HgI6 systems were calculated, and it was found that ionic conductivity activation energy for 5 mol% of cation dopants is much
lower than that of undoped one, and also 10 mol% doped Tl4HgI6 systems. 相似文献