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91.
玻璃离子水门汀固化反应的红外光谱研究 总被引:4,自引:0,他引:4
用红外光谱研究了玻璃离子水门汀固化反应过程,结果显示,表征聚丙烯酸盐的峰强度(~1 413 cm-1)随时间延长而逐渐增加,而硅醇基团,即最强峰(~1 039 cm-1)上的肩峰(950 cm-1),在所观察的周期中仍然存在。因此,玻璃离子水门汀抗压强度随时间延长而增加的原因在于: ①Ca2+,Al3+与聚丙烯酸的固化化学反应在一个相当长的时间内仍在进行;②因玻璃结构分解形成的硅醇基团将长期存在,并在缩合形成硅凝胶的过程中,改变基体与填料间的界面结构和组成,因此对玻璃离子水门汀的长期力学性能也将产生一定的影响。 相似文献
92.
The purpose of this study was to evaluate the effect of monolithic zirconia thickness on degree of conversion (DC) of different resin cements. Five groups (1 mm, 1.5 mm, 2 mm monolithic zirconia, veneered zirconia substructure, and lithium disilicate) of disk-shaped ceramic specimens (14 mm in diameter) were prepared (n = 6). Three dental resin cements (Variolink II light-cured, Variolink II dual-cured and Zirconite dual-cured) were tested to evaluate their DC under each ceramic group. FTIR spectra were recorded using Attenuated Total Reflectance-Fourier Transform Infrared Spectrometer (ATR-FTIR). The DC% was calculated by ratio of infrared absorbance values of aliphatic and aromatic peaks for uncured and cured states. Data were statistically analyzed by Analysis of Variance (ANOVA) and post hoc Tukey tests (a = 0.05). DC of dental resin cement specimens under monolithic zirconia decreased with increasing thickness. For Variolink II light-cured cement, the highest DC found under lithium disilicate and the lowest DC observed under veneered zirconia specimens. Zirconite which is recommended for cementation of zirconia revealed the highest DC when polymerized under monolithic or veneered zirconia. Under lithium disilicate specimens, DC of Zirconite was similar with light-cured resin cement. 相似文献
93.
电感耦合等离子体原子发射光谱(ICP-AES)法与内标法的结合扩展了ICP-AES的分析范围。采用氢氧化钠熔融样品,ICP-AES-内标法测定各类水泥标准物质样品中SiO2、Al2O3、TFe2O3、MgO、TiO2等氧化物的含量。实验结果表明,标准物质测定值与标准值吻合,6次平行样品测定相对标准偏差小于1.4%。方法一次熔样,纵向测定主常量元素,操作简单,快速,准确,为水泥标准物质的研制提供了另一种定值方式。 相似文献
94.
Protein structure prediction and analysis are more significant for living organs to perfect asses the living organ functionalities. Several protein structure prediction methods use neural network (NN). However, the Hidden Markov model is more interpretable and effective for more biological data analysis compared to the NN. It employs statistical data analysis to enhance the prediction accuracy. The current work proposed a protein prediction approach from protein images based on Hidden Markov Model and Chapman Kolmogrov equation. Initially, a preprocessing stage was applied for protein images’ binarization using Otsu technique in order to convert the protein image into binary matrix. Subsequently, two counting algorithms, namely the Flood fill and Warshall are employed to classify the protein structures. Finally, Hidden Markov model and Chapman Kolmogrov equation are applied on the classified structures for predicting the protein structure. The execution time and algorithmic performances are measured to evaluate the primary, secondary and tertiary protein structure prediction. 相似文献
95.
To obtain accurate mechanical properties of an orthopedic Polymethylmethacrylate (PMMA-based) bone cement, nanomechanical testing was performed. Due to visoelastic characteristics of this polymer-like bone cement, the mechanical properties cannot be identified using conventional indentation methods. A well-known two-layer viscoplasticity model was selected and simulated in a finite element solver. A complete analogical study between the results of the finite element simulation and the experimental data was made to reach the best optimized parameters for the selected model. It is shown that the proposed model can be used to obtain the constitutive material relationship for polymeric materials. 相似文献
96.
A comprehensive experimental investigation of the effect of the Reynolds number on the degeneration law for turbulence generated by biplanar and wicker grids is carried out over a wide range of the grid geometry parameters and the flow velocity. It is established that an increase in the flow velocity leads to an increase in the turbulence intensity at a given distance from the biplanar grid and a decrease in the turbulence decay rate downstream of the grid. An empirical relation between the turbulence intensity behind the grid, on the one hand, and the relative distance x/M from the grid and the Reynolds number based on the grid rod diameter and the flow velocity at the grid mesh center, on the other hand, is proposed. For the same relative distance x/M from the grid the intensity of wicker-grid turbulence is higher than in the case of the flow past a biplanar grid. 相似文献
97.
前置液是影响固井质量的重要因素之一,对于海水钻井液体系,如何选用前置液是一个新的
课题. 提出了一种适宜于海水钻井液体系的新型前置液,对其在固井过程中的各种性能
进行了室内实验研究,结果表明:新型前置液与海水钻井液、固井水泥浆及盐水等环境流体
有良好的相容性,对井壁具有稳定作用,其中的固体颗粒及表面活性剂有利于冲刷海水钻井
液形成的泥饼. 在此基础上,将新型前置液应用于胜利油田的固井作业,进行现场试验,发
现:应用新型前置液后,环空水泥浆界面清晰,混浆段长度缩短,第2界面的胶结质量有明
显提高. 相似文献
98.
在古城区建筑地基上部,广泛赋存以炉灰渣为主要成分的杂填土,其厚度不一。随着城市化进程的迅猛发展,旧城改造对高层建筑地下空间的充分利用提出了更高要求,特别是在周围恶劣环境条件下开挖空间,从理论、实践上深入研究闹市区杂填土深基坑,采用何种经济技术合理的支护方案问题十分突出。但各种深基坑支护方法都有其局限性,岩土工程师在确定方案时必须充分考虑当地工程地质条件、建筑物基坑特点,选择组合支护技术方法,方可达到事半功倍之目的。通过成功支护某杂填土深基坑工程实例,详尽阐述了杂填土的工程特性、锚拉钢板桩挡墙、土钉挡墙的基本参数选取、设计计算,可为类似岩土工程条件下的基坑支护方案选型和设计提供借鉴及参考。 相似文献
99.
套管井中的声传播涉及到波在柱状多层介质中的传播问题。通过数值计算对比了宽带相控线阵声源在套管井外均匀地层中产生的纵横波声场的指向性。结果表明,在任意胶结状况下,均可实现向套管井外地层定向辐射纵横波的技术;与地层中纵波的传播特征不同的是在主瓣偏转角方向横波幅度随着偏转角的增大逐渐增加,且在主瓣辐射方向的横波幅度受套管井胶结状况的影响较纵波小;采用玻璃钢套管代替钢套管,会进一步减弱地层声场受胶结状况的影响,这有利于实现在套管井外地层较大范围内的精确定向辐射声波的技术。 相似文献
100.