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991.
992.
Farid Farajollahi Othmar Marti Masoud Amirkhani 《Journal of Polymer Science.Polymer Physics》2015,53(10):709-718
The condensation of water vapor on a volatile polymeric solution leads to a porous surface after evaporation of both solvent and water. However, the stabilization of the water microdroplet is of great importance, which can be achieved using specific polymer or adding a third substance to the polymer solution. Short chain alcohols (methanol, ethanol, and n‐propanol) are utilized to fabricate a self‐assembled porous honeycomb film of linear, low molecular weight polystyrene using the breath figure technique. A combination of breath figure processing and the effect of alcohol on a water droplet can stabilize the pattern and make pores on the surface of the polymer film. The quality of the porous honeycomb film is strongly dependent on the type of alcohols and the concentration of polymer. In a specific range of polymer and alcohol concentration, pores cover all the surface of the polymer film. This method offers the possibility of producing a honeycomb structure with no trace of additive residual after the fabrication process and avoiding polymer modification. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 709–718 相似文献
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995.
Prof. Dr. Michael Stollenz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(17):4274-4298
The defined linear arrangement of metal atoms in discrete coordination complexes or polymers is still one of the most intriguing challenges in synthetic chemistry. These chain arrangements are of fundamental importance, because of their potential applications as molecular wires and single molecule magnets (SMM) in microelectronic devices on a molecular scale. Oligonuclear Group 11 metal complexes with suitable bridging ligands, specifically those that are based on copper as the first choice of a cheap precursor coinage metal, are of particular interest in this regard. This is due to the superior luminescence properties of these linear clusters that often show d10⋅⋅⋅d10 interactions in their molecular structures. The combination of CuI with heavier coinage metal ions results in tunable emissive arrays that are also stimuli-responsive. Thus, both linear multinuclear CuI and linear heteropolymetallic CuI/AgI as well as CuI/AuI clusters are excellent candidates for applications in molecular/organic light-emitting devices (OLEDs). Alternatively, paramagnetic multinuclear cupric arrays are prominent as potential molecular wires with enhanced magnetic properties through multiple coupled d9 centers. This Review covers the whole range of linear multinuclear assemblies of cuprous and cupric ions in complexes and coordination polymers, their syntheses, photophysical behavior, and magnetic properties. Moreover, recent advances in the rapidly progressing field of hetero-CuI/AgI and CuI/AuI molecular strings are also discussed. 相似文献
996.
Polytriacetylenes bearing directly attached functional groups with tunable physical and electronic properties
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We report the synthesis and characterization of a unique class of conjugated polymers, polytriacetyelenes (PTAs), from a set of trans‐enediyne (EDY) monomers bearing alkyl and aromatic substituents. Two different methods, i.e., Glaser‐Hay coupling and Pd‐catalyzed oxidative coupling, were employed depending on the nature of the side‐chains. Our methodology is highly versatile in that it allows direct attachment of aromatic substituents to the PTA main‐chains, allowing enhanced tunability in polymer electronic properties, which has not been achievable through previously reported methods. The newly synthesized PTAs displayed strong ability of quenching the fluorescence of poly(3‐hexylthiophene) (P3HT), a prototypical conjugated polymer in organic solar cells, indicating possible applications of these PTAs in optoelectronic devices. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1391‐1395 相似文献
997.
Dr. Wan-Shan Li Dr. Ren-Jie Yan Yi Yu Prof. Zhi Shi Dr. Attila Mándi Dr. Li Shen Prof. Tibor Kurtán Prof. Jun Wu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):13128-13136
Marine dinoflagellates produce remarkable organic molecules, particularly those with polyoxygenated long-carbon-chain backbones, namely super-carbon-chain compounds (SCCCs), characterized by the presence of numerous stereogenic carbon centers on acyclic polyol carbon chains. Even today, it is a challenge to determine the absolute configurations of these compounds. In this work, the planar structures and absolute configurations of two highly flexible SCCCs, featuring either a C69- or C71-linear carbon backbone, gibbosols A and B, respectively, each containing thirty-seven stereogenic carbon centers, were unambiguously established by a combined chemical, spectroscopic, and computational approach. The discovery of gibbosols A and B with two hydrophilic acyclic polyol chains represents an unprecedented class of SCCCs. A reasonable convergent strategy for the biosynthesis of these SCCCs was proposed. 相似文献
998.
A kinetic model which describes Ostwald's rule of stages, during the process of crystal growth from solution, is reported here. Reaction equations for stages are given where the stages convert from one to another. The final stage reacts to release a portion of solute back into solution, while the remainder converts to the final equilibrium form. Additionally, a remnant of the solute that was not consumed by any of the transitional stages, ultimately is converted into the final product. This particular model was motivated by a recent report for Boc-diphenylalanine self-assembly where the dissolved peptide was observed to go through two polymorphic stages before reaching the equilibrium supramolecular assembly [A. Levin et al., Nat. Commun. 5, 5219, (2014)]. Kinetic data for the concentration of solute present during the process are listed in the above-mentioned report. We show here how the model, for , describes the time-dependent behavior of the solute decay during the growth process. After comparing the model to the experimental data, we are able to report values for all of the rate constants and propose a rule whereby the relative magnitudes of these constants can be used to predict whether a supersaturated substance will noticeably pass through transitional stages or simply convert from solute to the equilibrium solid form. 相似文献
999.
Gibbs samplers derived under different parametrizations of the target density can have radically different rates of convergence. In this article, we specify conditions under which reparametrization leaves the convergence rate of a Gibbs chain unchanged. An example illustrates how these results can be exploited in convergence rate analyses. 相似文献
1000.
Poly(p‐benzamide) having isopropyl‐substituted chiral tri(ethylene glycol) side Chain: Synthesis and helical conformation
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Akihiro Yokoyama Suguru Nakano Tomoaki Saiki Tsutomu Yokozawa 《Journal of polymer science. Part A, Polymer chemistry》2015,53(13):1623-1628
Isopropyl‐substituted tri(ethylene glycol) is used as a chiral side chain of N‐substituted poly(p‐benzamide) in order to increase the difference of stability between the right‐ and left‐handed helical structures of the polymer. The target polymer is synthesized by the chain‐growth condensation polymerization of the corresponding monomer with an initiator using lithium 1,1,1,3,3,3‐hexamethyldisilazide as a base. A circular dichroism (CD) study of the polymer reveals that the CD signal is due to an excess of a thermodynamically controlled right‐handed helical structure of the polymer, and that the replacement of the methyl group with a bulkier isopropyl group at the side chain of poly(p‐benzamide) increases the abundance of right‐handed helical structure in chloroform. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1623–1628 相似文献