全文获取类型
收费全文 | 2529篇 |
免费 | 78篇 |
国内免费 | 196篇 |
专业分类
化学 | 2155篇 |
晶体学 | 55篇 |
力学 | 8篇 |
综合类 | 8篇 |
数学 | 1篇 |
物理学 | 576篇 |
出版年
2024年 | 3篇 |
2023年 | 52篇 |
2022年 | 28篇 |
2021年 | 26篇 |
2020年 | 46篇 |
2019年 | 41篇 |
2018年 | 34篇 |
2017年 | 58篇 |
2016年 | 79篇 |
2015年 | 56篇 |
2014年 | 86篇 |
2013年 | 92篇 |
2012年 | 265篇 |
2011年 | 205篇 |
2010年 | 153篇 |
2009年 | 160篇 |
2008年 | 163篇 |
2007年 | 180篇 |
2006年 | 143篇 |
2005年 | 136篇 |
2004年 | 125篇 |
2003年 | 68篇 |
2002年 | 76篇 |
2001年 | 60篇 |
2000年 | 53篇 |
1999年 | 66篇 |
1998年 | 72篇 |
1997年 | 59篇 |
1996年 | 34篇 |
1995年 | 51篇 |
1994年 | 27篇 |
1993年 | 21篇 |
1992年 | 29篇 |
1991年 | 19篇 |
1990年 | 16篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有2803条查询结果,搜索用时 15 毫秒
81.
A spot test was implemented in a flow-injection system for the spectrophotometric determination of zinc in digests of plant materials. It is based on the influence of Zn2+ on the oxidation rate of 1-naphthylethylenediamine (NED) by hexacyanoferrate(III) under acidic conditions. In order to control the precipitate formation and to maintain the resulting suspension, a micellar medium was established by adding Triton X-100. The proposed system handles about 65 samples per hour, meaning 72 μg NED and 9.0 mg K3[Fe(CN)6] per determination. Baseline drift is usually <0.01 absorbance per hour and the analytical signals for 0.5-2.5 mg l−1 Zn range within ca. 0.07-0.45 absorbance. Linearity of the analytical curve is fair (r>0.999, n=6) and detection limit was estimated as 0.2 mg l−1 Zn. Results are precise (R.S.D.<1%, n=10) and in agreement with flame atomic absorption spectrometry and with certified values of standard reference materials. 相似文献
82.
气动雾化进样微波等离子体炬(MPT)原子荧光光谱法测定锌的研究 总被引:5,自引:0,他引:5
本文将水溶液雾化进样与微波等离子体炬原子荧光光谱法联用,建立了HCL-MPT-AFS测定Zn的新方法。讨论了实验条件的选择问题以及溶液中共存离子对测定Zn的影响,本文所推荐的方法具有较高的灵敏度和精密度,并将其用于实际样品分析。 相似文献
83.
A mild and highly efficient deoxygenation of variety of N-oxides using an inexpensive CuX, or a CuX-Zn or CuX-Al couple is described. 相似文献
84.
研究应用双波长K系数—标准加入吸光光度法同时测定锰和锌二组分混合物.试验确定了锰和锌测定中K_(Mn)与K_(Zn)的回归方程.对合成试样、人发试样测定,结果满意. 相似文献
85.
A simple and versatile protocol, based on use of solid phase extraction on strong ion exchangers and off-line detection by flame atomic absorption spectrometry, was devised to fractionate iron and zinc in common dietary food and beverages products, i.e., bee honeys, fruit juices and tea infusions. In the procedure proposed, cation exchanger Dowex 50Wx4 and anion exchanger Dowex 1x4 were used separately for distinguishing broadly meant the cationic metal fraction and the fraction of stable anionic metal complexes, respectively, after retention of metal species and their exhaustive elution by means of a 4.0 mol l−1 HCl solution. The third fraction, referred to the residual metal species, was retrieved by difference between total soluble metal contents and sum of metal quantities in separated cationic and anionic fractions. The fractionation pattern observed for both metals was described and discussed. 相似文献
86.
用 PCA 及 PLS 分步处理分光光度数据,有效降低了计算的维数。以该法对不同酸度体系的5-Br-PADAP-钴、镍、铜、锌分光光度数据进行了处理,定量分析结果良好。 相似文献
87.
John Fielden Patrick T. Gunning De-Liang Long Margaret Nutley Arkady Ellern Paul Kgerler Leroy Cronin 《Polyhedron》2006,25(18):3474-3480
The coordination chemistry of the tetradentate pyridyl N-donor ligand cis-3,5-bis-[2-pyridinyleneamin]-trans-hydroxycyclohexane (DDOP) has been investigated with zinc(II) nitrate and triflate. The resulting complexes, [Zn(DDOP)(H2O)(NO3)](NO3) (1), and [Zn(DDOP)(H2O)(OTf)](OTf) (2) differ not only in their counterions, but also the arrangement of the axial ligands and their solid state hydrogen bonded networks. Isothermal titration calorimetry was used to assess the difference in binding properties exhibited by the two zinc complexes at physiological pH in an aqueous environment. A series of coordinating amino acids were found to preferentially bind to the mononuclear zinc triflate (1) complex over the corresponding nitrate (2) assembly, with histidine exhibiting a two centre binding mode. 相似文献
88.
Complex [Zn2(bimb)2(mal)2(H2O)2]·4H2O (1) (mal=−OCOCH2COO−) was obtained by reaction of bidentate ligand 4,4′-bis(imidazole-1-ylmethyl)biphenyl (bimb) with zinc(II) salt of malonate, while the reaction of the same metal salt with 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene (titmb) gives another novel complex [Zn2(titmb)2(mal)][mal]·12H2O (2). The structures of these complexes were determined by X-ray crystallography. The results revealed that 1 is a cyclic dinuclear complex in which the malonate groups act as terminators and prevent further aggregation, while 2 is a 2D honeycomb network in which each independent 2D sheet contains two sub-layers bridged by the malonate groups and complex 2 also contains free malonate as a counteranion connected to the 2D layer by C-H?O hydrogen bonds. The entirely different structure and topology of complexes 1 and 2, on the one hand, indicates that the nature of organic ligands affected the structures of assemblies greatly, and on the other, reveals the versatility of the malonate which can act as a bridging and/or blocking ligand. 相似文献
89.
综述了锌在小儿神经系统疾病和内分泌代谢性疾病中的作用及临床意义,尤其是对癫痫的发病起重要作用,大量资料证明高锌与癫痫发作有关,其血锌值明显高于健康儿童,因此在治疗中不要轻易补锌。还综述了锌与智能发育障碍、生长发育障碍、多动症、胎儿畸形、遗传性感音神经性聋等疾病的关系及在治疗糖尿病、肝豆状核变性等内分泌和代谢性疾病时要注意维持锌的正常动态平衡。 相似文献
90.
M.?H.?Pournaghi-AzarEmail author H.?Nahalparvari 《Journal of Solid State Electrochemistry》2004,8(8):550-557
The use of a zinc substrate as an electrode and the modification of its surface by means of a thin film of platinum-doped nickel hexacyanoferrate (Pt-NiHCF) were developed. The modification conditions of the zinc surface including the electroless deposition of metallic nickel on the electrode surface from NiCl2 solution, chemical derivatization of the deposited nickel to the NiHCF film in 0.5 M K3[Fe(CN)6] solution, and electrochemical penetration of metallic platinum into the modified film are described. The modified zinc electrodes prepared under optimum conditions show a well-defined redox couple due to the [NiIIFeIII/II(CN)6]1–/2–
system. The effects of pH, the alkali metal cation, and the anion of the supporting electrolyte on the electrochemical characteristics of the modified electrode were studied in detail. The diffusion coefficients of hydrated alkali metal cations in the film (D), the transfer coefficient (), and the transfer rate constant for the electron (ks) were calculated in the presence of some alkali metal cations. The electrocatalytic activity of the modified electrode for methanol oxidation was demonstrated. The stability of the modified electrode under various experimental conditions was investigated. 相似文献