全文获取类型
收费全文 | 19726篇 |
免费 | 2063篇 |
国内免费 | 1868篇 |
专业分类
化学 | 11903篇 |
晶体学 | 243篇 |
力学 | 307篇 |
综合类 | 183篇 |
数学 | 8607篇 |
物理学 | 2414篇 |
出版年
2024年 | 40篇 |
2023年 | 344篇 |
2022年 | 355篇 |
2021年 | 380篇 |
2020年 | 637篇 |
2019年 | 653篇 |
2018年 | 642篇 |
2017年 | 501篇 |
2016年 | 755篇 |
2015年 | 790篇 |
2014年 | 1106篇 |
2013年 | 1678篇 |
2012年 | 1102篇 |
2011年 | 1257篇 |
2010年 | 1104篇 |
2009年 | 1288篇 |
2008年 | 1342篇 |
2007年 | 1244篇 |
2006年 | 1091篇 |
2005年 | 808篇 |
2004年 | 777篇 |
2003年 | 767篇 |
2002年 | 700篇 |
2001年 | 483篇 |
2000年 | 486篇 |
1999年 | 440篇 |
1998年 | 375篇 |
1997年 | 312篇 |
1996年 | 282篇 |
1995年 | 308篇 |
1994年 | 250篇 |
1993年 | 184篇 |
1992年 | 189篇 |
1991年 | 108篇 |
1990年 | 95篇 |
1989年 | 75篇 |
1988年 | 81篇 |
1987年 | 42篇 |
1986年 | 41篇 |
1985年 | 68篇 |
1984年 | 64篇 |
1983年 | 23篇 |
1982年 | 63篇 |
1981年 | 55篇 |
1980年 | 43篇 |
1979年 | 40篇 |
1978年 | 44篇 |
1977年 | 32篇 |
1976年 | 37篇 |
1973年 | 25篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
R. Souzy B. Ameduri B. Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5077-5097
The radical co‐ and terpolymerization of 4‐[(α,β,β‐trifluorovinyl)oxy]bromo benzene (TFVOBB) with 1,1‐difluoroethylene (or vinylidene fluoride, VDF, or VF2), hexafluoropropene (HFP), perfluoromethyl vinyl ether (PMVE), and chlorotrifluroroethylene (CTFE) is presented. Although TFVOBB could be thermocyclodimerized, it could not homopolymerize under radical initiation. TFVOBB could be copolymerized in solution under a radical initiator with VDF or CTFE comonomers, while its copolymerization with HFP or PMVE were unsuccessful. The terpolymerization of TFVOBB with VDF and HFP, or VDF and PMVE, or VDF and CTFE also led to original fluorinated terpolymers bearing bromoaromatic side‐groups. The conditions of co‐ and terpolymerization were optimized in terms of the nature of the radical initiators, and of the nature of solvents (fluorinated or nonhalogenated). Various monomer concentrations in the co‐ and terpolymers were assessed by 19F and 1H‐NMR spectroscopy. The thermal and physico chemical properties were also studied. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5077–5097, 2004 相似文献
102.
本文考虑损失函数的估计问题,分别对于球对称分布和均匀分布情形给出了其参数的J-S型估计量的损失之估计,它们满足[1]中提出的条件(Ⅰ)和(Ⅱ). 相似文献
103.
Any system that approximates an infinite lattice by a family of finite clusters (with periodic boundary conditions) passes through an intermediate region with enlarged (hidden) symmetry as the system size is increased. The hidden symmetry allows for extra degeneracies and level crossings and has application to exact-diagonalization studies, Monte Carlo simulations, lattice gauge theories, and renormalization group calculations. 相似文献
104.
The general centered form for multi-variate polynomials is investigated and a computing procedure is proposed that results in a certain superset. Based on this procedure the optimal centered forms for monomials and for some special cases of polynomials are investigated. 相似文献
105.
Xuefeng Yue Xinliang Lu Yongyuan Song Zongshu Shao Daliang Sun Quanzhong Jiang Huanchu Chen 《Applied physics. B, Lasers and optics》1991,53(5-6):319-322
The use of Cu-doped (K0.5Na0.5)0.2(Sr0.61Ba0.39)0.9Nb2O6 as self-pumped phase conjugators using internal reflection is reported. Reflectivities as high as 63% at 5145.5 nm and 60% at 632.8 nm were realized. It was found that the photorefractive response changes significantly at different doping concentration. The responses of the crystals to the laser wavelength, incident angle and dopant concentration are studied. 相似文献
106.
本文用ab initio计算方法,采用STO-3G基组,对二硝基卤代甲烷CH_2(NO_2)_3(1),CF_2(NO_2)_2(2);CCl_2(NO_2)_2(3)等分子作了单点计算,研究其旋转势能.全构型优化研究了五个具有对称性构型的结构和稳定性,并作了理论分析和探讨. 相似文献
107.
X. Y. Yang H. C. Gao X. L. Tan H. Z. Yuan G. Z. Cheng S. Z. Mao S. Zhao L. Zhang J. Y. An J. Y. Yu Y. R. Du 《Colloid and polymer science》2004,282(3):280-286
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate. 相似文献
108.
M. C. Jones 《Annals of the Institute of Statistical Mathematics》2004,56(4):733-742
A simple new family of distributions is proposed which has support the unit disc in two dimensions. The density functions
of the family are unimodal, monotonic or uniantimodal. The bivariate symmetric beta distributions, which include the uniform
distribution, are special cases, but many members of the family are skew. The distributions have three parameters, one controlling
orientation, one controlling degree of concentration and the third controlling skewness, or more precisely off-centredness.
Importantly, these parameters are globally orthogonal. An illustrative example of fitting the model to data is given. Conditional
and marginal distributions are considered. The new distributions are compared favourably with an earlier suggestion of the
same author. 相似文献
109.
The pentafluorobenzenethiyl radical is an efficient hydrogen abstractor from an activated methylene or methine group and bis(pentafluorophenyl) disulfide is an efficient electron acceptor from the resulting radical intermediate. Thus benzyl-OTBS ether was easily converted into the corresponding pinacol, and 2-phenyl-1,3-dioxanes are converted into the monobenzoates of diols. 相似文献
110.
Janusz Mierczyński Wenxian Shen Xiao-Qiang Zhao 《Journal of Differential Equations》2004,204(2):471-510
The purpose of this paper is to investigate uniform persistence for nonautonomous and random parabolic Kolmogorov systems via the skew-product semiflows approach. It is first shown that the uniform persistence of the skew-product semiflow associated with a nonautonomous (random) parabolic Kolmogorov system implies that of the system. Various sufficient conditions in terms of the so-called unsaturatedness and/or Lyapunov exponents for uniform persistence of the skew-product semiflows are then provided. Among others, it is shown that if the associated skew-product semiflow has a global attractor and its restriction to the boundary of the state space has a Morse decomposition which is unsaturated or whose external Lyapunov exponents are positive, then it is uniformly persistent. More specific conditions are discussed for uniform persistence in n-species, particularly 3-species, random competitive systems. 相似文献