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101.
Martin G Banwell Alison J Edwards Gwion J Harfoot Katrina A Jolliffe 《Tetrahedron》2004,60(3):535-547
An enantiomerically pure cis-1,2-dihydrocatechol, which is readily obtained via a toluene dioxygenase-mediated dihydroxylation of toluene in a whole-cell biotransformation process, has been converted over 17 steps into the linear triquinane (−)-hirsutene. Since the enantiomer of the starting material is also available this work constitutes a formal total synthesis of the naturally occurring (+)-form of hirsutene. Furthermore, minor modifications of the route used here offer the possibility of accessing (+)-hirsutene from the original starting material. 相似文献
102.
Zh. D. Chaplanova Yu. K. Mikhailovskii V. E. Agabekov V. K. Ol’khovik N. A. Galinovskii E. A. Gracheva 《Journal of Applied Spectroscopy》2007,74(3):333-337
We have studied the spectral properties and morphology of thin films (TVD films) formed by thermal vacuum deposition of 4,4′-bis[(E)-1-(1,3-benzoxazol-2-yl)-2-ethenyl]-1,1′-biphenyl
and its substituted derivatives. We have shown that introducing bulky 2,2′-oxyhexyl substituents into the biphenyl units leads
to a shift of the fluorescence maximum for the TVD films toward shorter wavelengths, a decrease in their photostability, and
aggregation of the films during storage.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 3, pp. 300–303, May–June, 2007. 相似文献
103.
我们对多电子束契伦柯夫自由电子激光进行了首次实验研究。280A,500kV的电子束被引入一多介质矩形谐振腔,在频率为33.4GHz处产生了1.7MW的契伦柯夫相干受激辐射。互作用效率为1.2%。 相似文献
104.
The line search method incorporating the Wolfe conditions is modified to ensure that a descent algorithm terminates in a finite number of steps at an approximate stationary point where the second-order conditions of optimality are satisfied. A simple procedure based on conjugate directions is proposed to determine directions of negative curvature. 相似文献
105.
对用Talbot效应及云纹干涉法测试镜面反射体曲率和斜率的灵敏度进行了分析,同时给出了由于光栅稀密对测试的影响和相应的解释。这对从事这项工作或工程上利用此技术测试物体曲率和斜率提供了一个可行的方案。 相似文献
106.
用共沉淀法制备了Mg2 + 掺杂的In2 O3 纳米粉 ,研究了镁掺杂对In2 O3 电导和气敏性能的影响 .结果表明 :MgO和In2 O3 间可形成有限固溶体In2 -xMgxO3 (0≤x≤ 0 .40 ) ;MgIn× 电离的空穴对材料导带电子的湮灭 ,使掺镁纳米粉的电导变得很小 ;n(Mg2 + )∶n(In3 + ) =1∶2共沉淀物于 90 0℃下热处理 4h ,用所得的纳米粉制作的传感器在 32 0~ 370℃下 ,对 45 μmol/LC2 H5OH的灵敏度达 10 2 .5 ,为相同浓度干扰气体Petrol的 12倍多 . 相似文献
107.
牛顿环实验中的误差分析 总被引:2,自引:0,他引:2
本文对牛顿环测透镜曲率半径实验中引起误差的各种原因进行分析讨论,指出了误差的主要来源及比较完善可行的处理方法。 相似文献
108.
A. Hansen M.H. Jensen K. Sneppen G. Zocchi 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(1):157-161
We present a statistical mechanics treatment of the stability of globular proteins which takes explicitly into account the
coupling between the protein and water degrees of freedom. This allows us to describe both the cold and the warm unfolding,
thus qualitatively reproducing the known thermodynamics of proteins.
Received: 19 March 1998 / Revised and Accepted: 25 May 1998 相似文献
109.
M. Stenger S. Baumhoff J.-Y. Prieur J. Joffrin J.-P. Contour 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):177-182
We present measurements of the attenuation and phase velocity of surface acoustic waves in thin YBa2Cu3O films as a function of temperature, in magnetic fields up to 3.6 T applied parallel to the c-axis of the films. We have observed anomalies in both, the attenuation and the phase velocity in the vicinity of the superconducting
critical temperature which do not depend on the magnetic field. Possible origins of these anomalies, observed, to our knowledge,
for the first time in YBa2Cu3O thin films, are discussed and compared to bulk acoustic wave experiments. We present a kind of feedback technique for surface
acoustic waves which improves the sensitivity of this type of measurement. The actual sensitivity limits are mentioned.
Received: 7 August 1997 / Revised: 7 November 1997 / Accepted: 17 November 1997 相似文献
110.
C. Ruyer-Quil P. Manneville 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(2):277-292
A new model of film flow down an inclined plane is derived by a method combining results of the classical long wavelength
expansion to a weighted-residuals technique. It can be expressed as a set of three coupled evolution equations for three slowly
varying fields, the thickness h, the flow-rate q, and a new variable that measures the departure of the wall shear from the shear predicted by a parabolic velocity profile. Results of a preliminary
study are in good agreement with theoretical asymptotic properties close to the instability threshold, laboratory experiments
beyond threshold and numerical simulations of the full Navier-Stokes equations.
Received: 16 April 1998 / Revised: 29 June 1998 / Accepted: 2 July 1998 相似文献