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61.
Merlet D Béguin L Courtieu J Giraud N 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,209(2):315-322
The application of the G-SERFph pulse sequence is presented on enantiomeric mixtures dissolved in a chiral liquid crystal. It aims at editing, within one single 2D spectrum, every proton coupling which is experienced by a given proton site in the molecule, and leads to real phased T-edited spectroscopy (T=J+2D). This NMR experiment is based on the combination of homonuclear semi-selective refocusing techniques with a spatial frequency encoding of the sample. This approach, which consists in handling selectively each coupling in separate cross sections of the sample, is applied to the visualization of enantiomers dissolved in a chiral liquid crystalline phase. Advantages and limits of this methodology are widely discussed. 相似文献
62.
63.
Branko Drlja?aSvetislav Savovi? Alexandar Djordjevich 《Optics and Lasers in Engineering》2011,49(5):618-622
The time-dependent power flow equation, which is reduced to its time-independent counterpart is employed to calculate frequency response and bandwidth in addition to mode coupling and mode-dependent attenuation in a step-index plastic optical fiber. The frequency response is specified as a function of distance from the input fiber end. This is compared to reported measurements. Mode-dependent attenuation and mode dispersion and coupling are known to be strong in plastic optical fibers, leading to major implications for their frequency response in data transmission systems. 相似文献
64.
We present an approach based on Gronwall’s inequalities for the asymptotic complete phase-frequency synchronization of Kuramoto oscillators with finite inertia. For given finite inertia and coupling strength, we present admissible classes of initial configurations and natural frequency distributions, which lead to the complete phase-frequency synchronization asymptotically. For this, we explicitly identify invariant regions for the Kuramoto flow, and derive second-order Gronwall’s inequalities for the evolution of phase and frequency diameters. Our detailed time-decay estimates for phase and frequency diameters are independent of the number of oscillators. We also compare our analytical results with numerical simulations. 相似文献
65.
Visarath In Patrick LonghiniAndy Kho Norman LiuSuketu Naik Antonio PalaciosJoseph D. Neff 《Physica D: Nonlinear Phenomena》2011,240(8):701-708
A novel coupling scheme using M≥2 arrays of coupled nonlinear elements arranged in a specific configuration can produce multifrequency patterns or a frequency down-converting effect on an external (input) signal. In such a configuration, each array contains N≥3 nonlinear elements with similar dynamics and each element is coupled unidirectionally within the array. The subsequent arrays in the cascade are coupled in a similar fashion except that the coupling direction is arranged in the opposite direction with respect to that of the preceding array. Previous theoretical work and numerical results have already been reported in [P. Longhini, A. Palacios, V. In, J. Neff, A. Kho, A. Bulsara, Exploiting dynamical symmetry in coupled nonlinear elements for efficient frequency down-conversion, Phys. Rev. E 76 (2007) 026201]. This paper is focused on results of experiments implemented on two distinct systems: the first system is fabricated using discrete component circuits to approximate an overdamped bistable Duffing oscillator described by a quartic potential system, and the second system is built in a microcircuit, where the nonlinearity is described by a hyperbolic tangent function, with the option of applying an external signal to investigate resonant effects. In particular, the circuit implementations for each case use M=2 arrays, but their voltage oscillations already demonstrate that the frequency relations between each of the successive arrays decrease by a rational factor, conforming to earlier theoretical and numerical results for the general case containing M arrays. This behavior is important for efficient frequency down-converting applications which are essential in many communication systems where heterodyning is typically used and it involves multi-step processes with complicated circuitry. 相似文献
66.
Ping Chen Min LiuLing Wang Yin PooRui-xin Wu 《Journal of magnetism and magnetic materials》2011,323(23):3081-3086
We experimentally studied the frequency dependent complex permittivity ε and permeability μ of composite composed of carbonyl iron powder (CIP) and epoxy resin in the frequency range 1-18 GHz. We found that the intrinsic ε and μ of CIP extracted from the measured ε and μ of composites follow the classical Maxwell equations and the Landau-Lifshitz-Gilbert (LLG) equation, respectively. The dependences of ε and μ of composites on the volume fraction of CIP (vfCIP) were investigated using the two-exponent phenomenological percolation equation (TEPPE). We found that the TEPPE can fit the experimental results very well. Comparing the results of percolation parameters derived by experimental data at different frequencies, we show that the TEPPE is frequency independent for the composites at microwave frequencies. The results also show that the ε and μ spectrums of composites with definite vfCIP can be correctly calculated by combining the TEPPE with the theoretical models of intrinsic ε and μ. 相似文献
67.
We study the cross-correlations of buy and sell volumes on the Korean stock market in high frequency. We observe that the pulling effects of volumes are as small as that of returns. The properties of the correlations of buy and sell volumes differ. They are explained by the degree of synchronization of stock volumes. Further, the pulling effects on the minimal spanning tree are studied. In minimal spanning trees with directed links, the large pulling effects are clustered at the center, not uniformly distributed. The Epps effect of buy and sell volumes are observed. The reversal of the cross-correlations of buy and sell volumes is also detected. 相似文献
68.
Er3+掺杂ZBLAN非晶的激发态频率上转换 总被引:3,自引:1,他引:2
非晶ZBLAN光纤玻璃中掺杂稀土离子Er3+的上转换发光的研究表明,在室温、大功率半导体激光器的激发下,Er3+的荧光主要是通过单离子步进双光子过程发生的,而其多光子过程虽然非常微弱,但在强的半导体激光的照射下也可产生.通过对这两种不同过程的实验测量,可以为进一步深入地研究上转换机制提供新的依据. 相似文献
69.
K. L. Vodopyanov 《Optics Communications》1998,150(1-6):210-212
Infrared pulses, continuously tunable in the 8–13 μm range, and with up to 1 MW peak power, have been achieved using single-stage frequency conversion in a CdSe travelling-wave optical parametric generator, pumped by 100 ps pulses from an actively mode-locked, Q-switched and cavity dumped 2.8 μm Cr,Er:YSGG laser. The external quantum conversion efficiency reached 10%. 相似文献
70.
In this paper, we report 30 THz measurements of ammonia in its excited, ν2 = 1, inversion state. These measurements include transition frequencies and pressure shifts (where significant enough to be observed). Included in the data are two forbidden and three ro-inversion transitions, as well as 18 transitions never directly measured before. The measurements were made with an all-solid-state, diode-laser, difference-frequency spectrometer. Using an innovative laser-frequency locking scheme, this spectrometer provided accurately determined and continuously tuned THz-frequencies without requiring accurate knowledge of the absolute laser frequencies. The details of the spectrometer’s frequency calibration is discussed. A global analysis of NH3 based on the available ground state, ν2 = 1 state, and ν2-band transitions was carried out, and the resulting set of recommended molecular effective-Hamiltonian parameters for ammonia is presented. In addition, calculated center frequencies and intensities for all possible transitions up to J = 20 between rotation, inversion, and vibration levels in the ground and ν2 = 1 states are included as supplementary material. 相似文献