Fe/SnO2非晶多层膜的磁特性

研究了高频溅射制备的Fe/SnO₂非晶多层膜的磁特性.当SnO₂层厚度d_s固定为5nm时，样品的饱和磁化强度M_s随Fe层厚度d_m的减小而降低，这主要受样品的死层效应和维度效应的影响.另外，在d_m很小时，样品呈现准二维磁性.样品居里温度T_C随d_m的减小单调下降.样品矫顽力H_c随d_m的变化呈现 关键词：     

Fabrication and Characterization of Mn0.5Zn0.5Fe2O4 Magnetic Nanofibers

Mn0.5Zn0.5Fe2O4 Magnetic nanofibers were fabricated by calcining electrospun polymer/inorganic composite nanofibers and characterized by thermogravimetric and differential thermal analysis, x-ray diffraction, field emission scanning electron microscopy, high resolution transmission electron microscopy and a vibrating sample magnetometer. The experimental results show that the pure spinel structure is basically formed when the composite nanofibers are calcined at 450°C for 2h. With the increasing calcination temperature, both the saturation magnetization and coercivity of nanofiber samples increase initially along with the growth of Mn0.5Zn0.5Fe2O4 nanocrystals contained in the nanofibers. However, when the calcination temperature reaches 550°C, the saturation magnetization of nanofibers starts to dramatically decrease owing to the formation of the α-Fe2O3 phase at this temperature. The prepared Mn0.5Zn0.5Fe2O4 nanofibers calcined at 500°C for 2h have diameters ranging from 100 to 200nm. Their saturation magnetization and coercivity are 12.37emu/g and 4.81kA/m at room temperature, respectively.     

Magnetic Properties of Ni-Zn Ferrite Prepared with the Layered Precursor Method

We prepare NiZnFe2O4 soft magnetic ferrites with different molar ratios with the layered precursor method and investigate their magnetic properties. In the layered precursor, metal ions are scattered on the layer plate in a certain way on account of the effect of lowest lattice energy and lattice orientation. After high temperature calcinations, spinel ferrites with uniform structural component and single magnetic domain can be obtained, and the magnetic property is improved greatly. NiZnFe2O4 ferrites prepared have the best specific saturation magnetization of 79.15 emu·g^-1, higher than that of 68 emu·g^-1 prepared by the chemical co-precipitation method and that of 59 emu·g^-1prepared by the emulsion-gel method. Meanwhile the coercivity of NiZnFe2O4 ferrites prepared by layered precursor method is 14 kA·m^-1, lower than that of 50 emu·g^-1 prepared by the co-precipitation method and that of 59 emu·g^-1 prepared by the emulsion-gel method.     

氧化-共沉淀法制备Mn-Zn铁氧体的机理及影响因素

以FeSO4.7H2O、MnSO4.H2O、ZnSO4.7H2O、HCl为原料,NaOH溶液为沉淀剂、H2O2为氧化剂,采用氧化-共沉淀法在液相中制备Mn-Zn铁氧体,通过傅里叶变换红外光谱仪(IR),X射线衍射仪(XRD)和振动样品磁强计(VSM)对样品进行表征,讨论了Mn-Zn铁氧体在液相中的形成机理和氧化共沉淀法制备Mn-Zn铁氧体的影响因素。结果表明:采用氧化-共沉淀法能在液相中直接制备出Mn-Zn铁氧体,溶液的浓度和pH值是形成单相Mn-Zn铁氧体的两个关键因素;溶液的浓度和pH值低时,制备出的样品中含有非晶相FeOOH且饱和磁化强度低。     

甚高频用超低饱和磁化强度In∶BiCaVIG晶体生长及磁特性研究

利用加速坩埚转动技术制备了超低饱和磁化强度(M_s)石榴石型In∶BiCaVIG单晶铁氧体材料,系统研究了单晶样品的晶体结构、微观形貌及磁学性能。结果表明:In∶BiCaVIG单晶样品结晶良好,具有体心立方结构;样品的居里温度为104 ℃,饱和磁化强度为60 G,饱和磁化强度偏差达到±20 G, 略优于美国Microphere公司同类型材料产品。经过抛光处理后的球形样品线宽明显减小,最小线宽为5.8 Oe,这是因为化学抛光处理可以均匀腐蚀加工应力层,导致线宽减小。另外,与未掺杂BiCaVIG单晶相比,超低饱和磁化强度样品的线宽明显要大,这主要跟样品的饱和磁化强度大小有关。     

非线性铁氧体传输线的脉冲陡化作用

阐述了非线性铁氧体传输线的工作机理,并给出了等阻抗的设计方法。针对已有重复频率脉冲功率源输出脉冲特点,设计了工作重复频率可达10 kHz的铁氧体传输线,并可实现将前沿ns级的高压脉冲陡化至几百ps。采用多种NiZn铁氧体磁芯开展陡化实验,研究了磁芯参数、铁氧体传输线长度及外加励磁场等因素对陡化效果的影响,得出采用高饱和磁化强度的磁芯可以获得更快的脉冲前沿;采用小磁芯可以加快输出脉冲前沿,但需要的铁氧体长度更长;外加轴向励磁对陡化前沿也具有促进作用,但励磁场并非越大越好,而是存在一个最佳范围。目前,根据实验结果优化后,经铁氧体传输线可将脉冲前沿从4 ns陡化至450 ps,且输出脉冲电压峰值39 kV,基本实现了高重复频率、高功率及快脉冲输出。     

Monte Carlo study of nanowire magnetic properties

In this work, we use Monte Carlo simulations to study the magnetic properties of a nanowire system based on a honeycomb lattice, in the absence as well as in the presence of both an external magnetic field and crystal field. The system is formed with NL layers having spins that can take the values σ = ±1/2 and S = ±1, 0. The blocking temperature is deduced, for each spin configuration, depending on the crystal field Δ. The effect of the exchange interaction coupling Jp between the spin configurations σ and S is studied for different values of temperature at fixed crystal field. The established ground-state phase diagram, in the plane (Jp ,Δ), shows that the only stable configurations are: (1/2, 0), (1/2, +1), and (1/2,-1). The thermal magnetization and susceptibility are investigated for the two spin configurations, in the absence as well as in the presence of a crystal field. Finally, we establish the hysteresis cycle for different temperature values, showing that there is almost no remaining magnetization in the absence of the external magnetic field, and that the studied system exhibits a super-paramagnetic behavior.     

相分离Nd0.5Ca0.5MnO3体系的再入型自旋玻璃行为和电荷有序

K左右出现典型再入型自旋玻璃行为,同时观察到了负的磁化率异常. 结果表明,Nd0.5Ca0.5MnO3体系在低温下存在着典型的相分离和多种复杂的磁相互作用竞争机制,这为强关联锰氧化物体系物理机制的理解提供了重要的实验资料.     

ZnxFe3-xO4复合磁性流体的磁特性

制备了配以不同表面活性剂和基液的几种接Zn的Fe3O4复合磁性液体．通过对其中磁性微粒颗粒度、分布均匀性的分析和复合磁性液体比饱和磁化强度、矫顽力等磁特性的测试,阐述了掺Zn量及表面活性剂等因素对世性液体磁特性的影响,并对其磁性机理进行了探讨．