Ca+-Pyridine络合物的光解反应

使用反射式飞行时间质谱仪,得到 Ca~ -pyridine 络合物在412～ 690nm 的光解谱.从谱图可见,反应有两个通道,一个是 Ca~ 与 pyridine 分子解离开的非反应淬灭过程,这个通道在所有波段都有,且占优势；生成产物 Ca~ NH_2的通道不仅所占比例小,且在530～590nm 波段关闭. 作为激光波长函数的 Action spectrum 显示出明显的峰,对应于络合物的跃迁.反应的分支比也支持了光解谱图的结论.     

高灵敏度区域中子监测仪探测效率曲线模拟

中子监测仪对不同能量中子的探测效率是其重要的性能指标,直接影响其测量值的可信度与使用效果。针对中国科学院高能物理研究所生产的高灵敏度区域中子监测仪（HANM型）,利用蒙特卡罗软件模拟其探测效率曲线,模拟结果表明该仪器探测效率随能量增加,先上升后下降,其探测效率最高值在1 MeV附近。通过改变模拟条件中的射线入射方向,对比探测效率曲线趋势变化,验证该型仪器的探测效率曲线趋势的可靠性。在此基础上,分别利用D-D,D-T加速器产生2.5 MeV和14 MeV单能中子,对探测效率曲线进行校准与验证,最终获得此型仪器的探测效率曲线。     

三核铁甲酸簇合物[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O在乙炔、水汽体系中的反应行为

本文研究了[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O(简称)在乙炔、水汽体系中的反应行为。发现当温度高于220℃,脱落部分配体的具有活化乙炔进行加成反应的性能。采用原位红外光谱法和气相色谱法对此反应过程进行了跟踪探索,报道了产物的定性及半定量结果。     

Nonlinear optical behaviors in a silver nanoparticle array at different wavelengths

The optical nonlinearities of an Ag nanoparticle array are investigated by performing Z-scan measurements at the selected wavelengths (400, 600, 650, and 800 nm). The nonlinear refraction index in the resonant region (around 400 nm) exhibits a significant enhancement by two orders compared with that in the off-resonant region (around 800 nm)), and exhibits an sign alternation of the resonant nonlinear absorption, which results in a negligible nonlinear absorption at a certain excitation intensity. Moreover, a low degree of nonlinear absorption was measured at the edges of the resonant region (600 and 650 nm), which is attributed to the competition of the saturated absorption and the two-photon absorption processes.     

含垫层的预紧接触式结构非线性动态特性研究

预紧接触式结构是指结构中存在预紧构件，预紧构件与其他构件之间是相互接触的。在工程中经常遇到预紧接触式结构，如产品在包装时采用的泡沫垫层、武器设计中使用的垫层等，这些结构的共同点是在正常工作环境中垫层总处于受压状态，即垫层结构在有效的工作环境中沿厚度方向是不能承受拉力的。预紧接触式系统中，在预紧力一定的条件下，结构的动力学特性会随激励力幅值大小以及频率的变化而变化。在小幅值振动的条件下，可以认为系统是线性的，在幅值较大时，结构会表现出明显的非线陛特征。当激励满足一定条件时，系统会产生滑移、接触分离，而这往往是工程实际中所不允许的。分析此类问题需要了解结构的动态特性，而滑移、接触分离将导致系统的强非线性，就不能采用拟线性的方法来处理这类问题。     

基于反应论模型的指数型环境因子点估计

已知指数型产品在环境S下的定数截尾数据(Ti,ri)，i=1，…，k(其中Ti为环境Si下的累积试验时间，ri为环境Si下的关联故障总数)，考虑产品在环境S2下相对于环境S1，的环境因子点估计问题。     

《应用声学》征稿简则

《应用声学》是声学领域的学术刊物,中国自然科学核心期刊,中国科学引文数据库、中国科技论文统计用刊.国内外公开发行.办刊的宗旨是繁荣应用声学事业,促进新成果的开发与推广,促进科研、工程技术人员与生产实践者之间的相互了解和合作.读者对象是从事声学方面科研、教学、医疗、产品与设备开发、科技管理、企业管理的工作者,以及大专院校学生.     

Optical bistability induced by quantum coherence in a negative index atomic medium

Bistability behaviors in an optical ring cavity filled with a dense V-type four-level atomic medium are theoretically investigated. It is found that the optical bistability can appear in the negative refraction frequency band, while both the bistability and multi-stability can occur in the positive refraction frequency bands. Therefore, optical bistability can be realized from conventional material to negative index material due to quantum coherence in our scheme.     

Thermodynamic properties of 3C-SiC

In the present paper, we report on the results of various thermodynamic properties of 3C-SiC at high pressure and temperature using first principles calculations. We use the plane-wave pseudopotential density functional theory as im- plemented in Quantum ESPRESSO code for calculating various cohesive properties in ambient condition. Further, ionic motion at a finite temperature is taken into account using the quasiharmonic Debye model. The calculated thermody- namic properties, phonon dispersion curves, and phonon densities of states at different temperatures and structural phase transitions at high pressures are found to be in good agreement with experimental and other theoretical results.     

Molecular dynamics study of thermal stress and heat propagation in tungsten under thermal shock

Using molecular dynamics （MD） simulation, we study the thermal shock behavior of tungsten （W）, which has been used for the plasma facing material （PFM） of tokamaks. The thermo-elastic stress wave, corresponding to the collective displacement of atoms, is analyzed with the Lagrangian atomic stress method, of which the reliability is also analyzed. The stress wave velocity corresponds to the speed of sound in the material, which is not dependent on the thermal shock energy. The peak pressure of a normal stress wave increases with the increase of thermal shock energy. We analyze the temperature evolution of the thermal shock region according to the Fourier transformation. It can be seen that the “obvious” velocity of heat propagation is less than the velocity of the stress wave; further, that the thermo-elastic stress wave may contribute little to the transport of kinetic energy. The heat propagation can be described properly by the heat conduction equation. These results may be useful for understanding the process of the thermal shock of tungsten.