四氢β—咔啉类化合物的~(13)C NMR研究

测定了四对新合成的四氢β-咔啉化合物的~13C NMR谱,通过APT,HETCOR和HETCOLOC谱指认了所有碳的归属.所确定的化学位移规律可以用来确定它们的构型.     

Differential Proteomic Analysis of Neonatal Cardiomyocytes in Response to β-Adrenergic Receptor Stimulation

Introduction Adrenoceptors(ARs),membersofthesuperfami lyofG proteincoupledreceptors,arethemostimpor tantreceptorsinvolvedincardiacregulation[1].ARsin cardiacmuscleincludebothαARsandβARssub types,whileinmostmammalianheart,βARsarethe predominantsubtypes.…     

RO-heparin Inhibits L-Selectin-mediated Neutrophils Adhesion to Vascular Endothelium Under Flow Conditions

Introduction Migrationandrecruitmentofleukocytesfromblood toinflammatorylesionsitesaresequentiallyregulated byadhesionmoleculesandtheirreceptors[1].These lectinfamilyplaysamajorroleininitiatingattachement ofneutrophilstotheactivatedendothelium.P selectin,…     

New Levels in ^118Pd Observed in the β Decay of Very Neutron-Rich ^118Rh Isotope

We investigate the β decay of very neutron-rich ^118Rh isotope using on-line mass-separated sources which are produced by applying 25 MeV proton induced symmetric fission of natural uranium at the IGISOL facility. The β-γ and γ-γ coincidence spectroscopy is employed to establish the level scheme of daughter nucleus ^118Pd. Five low-lying new levels are identified for the first time with tentative spin and parity assignments based on the even-mass Pd systematics.     

Synthesis of a Novel Aromatic Diamino-bridged Bis（β-cyclodextrin） and its Inclusion Complexation with Dyes Molecules

Bridged bis(β-cyclodextrin)s (CDs), as a very important family of CD derivatives, have been known that they can significantly alter the molecular binding ability and selectivity toward a variety of guests in comparison with parent cyclodextrin. Their two…     

Effect of Nonradiative Recombination on Carrier Dynamics in GaInNAs/GaAs Quantum Wells

The nonradiative recombination effect on carrier dynamics in GalnNAs/GaAs quantum wells is studied by timeresolved photoluminescence （TRPL） and polarization-dependent TRPL at various excitation intensities. It is found that both recombination dynamics and spin relaxation dynamics strongly depend on the excitation intensity. Under moderate excitation intensities the PL decay curves exhibit unusual non-exponential behaviour. This result is well simulated by a rate equation involving both the radiative and non-radiative recombinations via the introduction of a new parameter of the effective concentration of nonradiative recombination centres in the rate equation. In the spin dynamics study, the spin relaxation also shows strong excitation power dependence. Under the high excitation power an increase of spin polarization degree with time is observed. This new finding provides a useful hint that the spin process can be controlled by excitation power in GaInNAs systems.     

无介质微波作用下酮与稳定叶立德的反应

酮与稳定膦叶立德在家用微波炉中加热，在无任何溶剂或固体介质条件下，4．5min之内完成反应，得到了良好产率的Wittig反应产物，较之液相苯中回流反应的传统方法，此法具有时间短、操作步骤简单、无毒害等优点，同时使一些在传统方法中与稳定叶立德不反应或难反应的酮得以进行并有较好收率。此外，在得到α，β-不饱和酯的同时，还发现了少量重排产物β，γ-不饱和酯，并对其机理进行了推测与证明。     

LOCAL SPECTRA OF UNILATERAL OPERATOR WEIGHTED SHIFTS

In this note, the local spectral properties of unilateral operator weighted shifts arestudied.     

离子注入合成β-FeSi2薄膜的显微结构

采用MEVVA源(Metal Vapor Vacuum Arc Ion Source)离子注入合成β-FeSi2薄膜,用常规透射电镜和高分辨电镜研究了不同制备参数下β-FeSi2薄膜的显微结构变化. 研究结果表明:调整注入能量和剂量,可以得到厚度不同的β-FeSi2表面层和埋入层. 制备过程中生成的α,β,γ和CsCl型FeSi2相的相变顺序为γ-FeSi2→β-FeSi2→α-FeSi2,CsCl-FeSi2→β-FeSi2→α-FeSi2或β-FeSi2→α-FeSi2. 当注入参数增加到60kV,4×1017ions/cm2,就会导致非晶的形成,非晶在退火后会晶化为β-FeSi2相,相变顺序就变为非晶→β-FeSi2→α-FeSi2. 随退火温度逐渐升高硅化物颗粒逐渐长大,并向基体内部生长,在一定的退火温度下硅化物层会收缩断裂为一个个小岛状,使得硅化物/硅界面平整度下降. 另外,对于β-FeSi2/Si界面取向关系的研究表明,在Si基体上难以形成高质量β-FeSi2薄膜的原因在于多种非共格取向关系的并存、孪晶的形成以及由此导致的界面缺陷的形成.     

首次测定短寿命缺中子同位素153Er和157Yb的EC/β+衰变纲图

利用¹⁶O重离子束轰击¹⁴²Nd和¹⁴⁷Sm同位素靶分别生成¹⁵³Er和¹⁵⁷Yb.借助氦喷嘴带传输系统和X-γ、γ-γ符合测量方法分离鉴别核素并测量其衰变性质.首次建立了¹⁵³Er和¹⁵⁷Yb的EC/β⁺衰变纲图.从中指认出¹⁵³Ho的一个新三(准)粒子态和两个新单粒子态,指认出¹⁵⁷Tm的一个新的同质异能态和一条新转动带.低位能级系统分析表明:在Ho和Tm这两条奇A核的同位素链中基态形状的转变区都在中子数86和88之间.