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41.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(11):1301-1315
Three hyperbranched multi-methacrylates (H20-MMA, H30-MMA and H40-MMA) have been synthesized by reacting Boltorn dendritic polyols with methacrylic anhydride and methacryloyl chloride. Their structures were characterized by FT-IR and NMR (1H and 13C) and molecular weights were measured by GPC. These multi-methacrylates (H-MMAs) mixed well with a variety of monomers such as acrylic acid (AA), methacrylic acid (MA), methyl methacrylate (MMA), 2-hydroxy-ethyl methacrylate (HEMA), tri(ethylene glycol) dimethdimethacrylate (TEGDMA), and bisphenol A glycidyl dimethacrylate (BisGMA). The initial studies on thermal polymerization activities of 10% of H-MMAs with AA, MA, and MMA showed that they gave higher polymerization enthalpy than the corresponding homopolymerization. The resulting materials showed one glass transition temperature, indicating a typical single-phase resin. The H-MMAs can effectively copolymerize with AA, MA, and MMA, with essentially no homopolymers produced, as indicated by acetone extraction studies. This indicated that the hyperbranched multi-methacrylates have the potential to be used as crosslinking agents or modifiers with a number of monomers to produce new thermosets. 相似文献
42.
B. Sen B. Das P. Chatterjee 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,49(2):211-216
Nonlinear dust acoustic solitary waves in a dusty plasma are studied for nonzero kinematic viscosity. Sagdeev’s potential
can be obtain upto any order in ϕ. The existence of soliton solution is determined by pseudopotential approach. It is seen
that the electron inertia has a significant effect on the existence of solitary waves in presence of kinematic viscosity. 相似文献
43.
L.P. Kaptari B. Kämpfer S.S. Semikh S.M. Dorkin 《The European Physical Journal A - Hadrons and Nuclei》2003,17(1):119-132
The exclusive charge exchange reaction pD↦n(pp) at intermediate and high energies is studied within the Bethe-Salpeter formalism. The final-state interaction in the detected
pp pair at nearly zero excitation energy is described by the 1
S
0 component of the Bethe-Salpeter amplitude. Results of numerical calculations of polarization observables and differential
cross-section persuade that, as in the non-relativistic case, this reaction i) can be utilized as a “relativistic deuteron
polarimeter” and ii) delivers further information about the elementary nucleon-nucleon charge exchange amplitude.
Received: 26 November 2002 / Accepted: 30 January 2003 / Published online: 29 April 2003 相似文献
44.
分析了壁面具有不同渗透的涨缩管道内微极性流体的流动.对于壁面的胀缩,考虑常系数和时间函数的膨胀率两种情况.对于第1种情况,应用同伦分析方法得到该问题的速度和微旋转角度的表达式.并且画图分析了各个不同参数,特别是膨胀系数和不同的渗透率对流体的动力特征的影响.可以得到第1个重要的结论:壁面的膨胀率和不同的渗透对流体的动力特征有重要的影响.根据Xu的模型,考虑了第2种也是更具有一般性的情况,假设壁面的膨胀率随时间的变化而变化.在这样的假设下,控制方程被转化成非线性偏微分方程,并且同样也可以应用HAM方法进行求解.应用代数和指数的模型来描述膨胀率从初始状态到最终状态的演变过程.然而,结果表明包含有时间的解很快地趋向于稳态的解.这样可以得到第2个重要的结论,时间在壁面的膨胀收缩中扮演着次要的角色,可以忽略不计. 相似文献
45.
Xiao-Chuan Cai William D. Gropp David E. Keyes 《Numerical Linear Algebra with Applications》1994,1(5):477-504
In recent years, competitive domain-decomposed preconditioned iterative techniques of Krylov-Schwarz type have been developed for nonsymmetric linear elliptic systems. Such systems arise when convection-diffusion-reaction problems from computational fluid dynamics or heat and mass transfer are linearized for iterative solution. Through domain decomposition, a large problem is divided into many smaller problems whose requirements for coordination can be controlled to allow effective solution on parallel machines. A central question is how to choose these small problems and how to arrange the order of their solution. Different specifications of decomposition and solution order lead to a plethora of algorithms possessing complementary advantages and disadvantages. In this report we compare several methods, including the additive Schwarz algorithm, the classical multiplicative Schwarz algorithm, an accelerated multiplicative Schwarz algorithm, the tile algorithm, the CGK algorithm, the CSPD algorithm, and also the popular global ILU-family of preconditioners, on some nonsymmetric or indefinite elliptic model problems discretized by finite difference methods. The preconditioned problems are solved by the unrestarted GMRES method. A version of the accelerated multiplicative Schwarz method is a consistently good performer. 相似文献
46.
We show that there do not exist computable functions f 1(e, i), f 2(e, i), g 1(e, i), g 2(e, i) such that for all e, i ∈ ω, (1) $ {\left( {W_{{f_{1} {\left( {e,i} \right)}}} - W_{{f_{2} {\left( {e,i} \right)}}} } \right)} \leqslant _{{\rm T}} {\left( {W_{e} - W_{i} } \right)}; $ (2) $ {\left( {W_{{g_{1} {\left( {e,i} \right)}}} - W_{{g_{2} {\left( {e,i} \right)}}} } \right)} \leqslant _{{\rm T}} {\left( {W_{e} - W_{i} } \right)}; $ (3) $ {\left( {W_{e} - W_{i} } \right)} \not\leqslant _{{\rm T}} {\left( {W_{{f_{1} {\left( {e,i} \right)}}} - W_{{f_{2} {\left( {e,i} \right)}}} } \right)} \oplus {\left( {W_{{g_{1} {\left( {e,i} \right)}}} - W_{{g_{2} {\left( {e,i} \right)}}} } \right)}; $ (4) $ {\left( {W_{e} - W_{i} } \right)} \not\leqslant _{{\rm T}} {\left( {W_{{f_{1} {\left( {e,i} \right)}}} - W_{{f_{2} {\left( {e,i} \right)}}} } \right)}{\text{unless}}{\left( {W_{e} - W_{i} } \right)} \leqslant _{{\rm T}} {\emptyset};{\text{and}} $ (5) $ {\left( {W_{e} - W_{i} } \right)} \leqslant _{{\rm T}} {\left( {W_{{g_{1} {\left( {e,i} \right)}}} - W_{{g_{2} {\left( {e,i} \right)}}} } \right)}{\text{unless}}{\left( {W_{e} - W_{i} } \right)} \leqslant _{{\rm T}} {\emptyset}. $ It follows that the splitting theorems of Sacks and Cooper cannot be combined uniformly. 相似文献
47.
《Mathematische Nachrichten》2018,291(2-3):492-517
We study the existence of nonnegative and nonzero solutions for the following class of quasilinear Schrödinger equations: where V and Q are potentials that can be singular at the origin, unbounded or vanishing at infinity. In order to prove our existence result we used minimax techniques in a suitable weighted Orlicz space together with regularity arguments and we need to obtain a symmetric criticality type result. 相似文献
48.
Based on the analysis of molecular gas dynamics, the drag and moment acting on an ellipsoid particle of revolutionX
2/a
2+Y
2/a
2+Z
2/c
2=1, as an example of nonspherical particles, are studied under the condition of free-molecular plasma flow with thin plasma
sheaths. A nonzero moment which causes nonspherical particle self-oscillation and self-rotation around its own axis in the
plasma flow—similar to the pitching moment in aerodynamics—is discovered for the first time. When the ratio of axis lengthc/a is unity, the moment is zero and the drag formula are reduced to the well-known results of spherical particles. The effects
of the particle-plasma relative velocity, the plasma temperature, and the particle materials on the drag and moment are also
investigated. 相似文献
49.
The action of lithium butyl acetylenide in THF causes 4,4-diethyl-1,2-dithiolane to undergo ring-opening to form 2,2-diethyl-4-thia-5-decyne-1-thiol,
which cyclizes to give 2-butyl-6,6-diethyl-5,6-dihydro-1,4-dithiepin by either a homolytic or a nucleophilic mechanism.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 204–206, January, 1997. 相似文献
50.
Sophie Ketter Aathira Gopinath Olga Rogozhnikova Dmitrii Trukhin Dr. Victor M. Tormyshev Prof. Dr. Elena G. Bagryanskaya Dr. Benesh Joseph 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(7):2299-2304
In situ investigation of membrane proteins is a challenging task. Previously we demonstrated that nitroxide labels combined with pulsed ESR spectroscopy is a promising tool for this purpose. However, the nitroxide labels suffer from poor stability, high background labeling, and low sensitivity. Here we show that Finland (FTAM) and OX063 based labels enable labeling of the cobalamin transporter BtuB and BamA, the central component of the β-barrel assembly machinery (BAM) complex, in E coli. Compared to the methanethiosulfonate spin label (MTSL), trityl labels eliminated the background signals and enabled specific in situ labeling of the proteins with high efficiency. The OX063 labels show a long phase memory time (TM) of ≈5 μs. All the trityls enabled distance measurements between BtuB and an orthogonally labeled substrate with high selectivity and sensitivity down to a few μm concentration. Our data corroborate the BtuB and BamA conformations in the cellular environment of E. coli. 相似文献