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31.
32.
在风速为6~30m/s的范围内,许多研究表明可近似认为热线探针的偏角因子K1和倾角因子K2不随风速变化,倾角θ对K1及偏角ψ对K2也近似认为没有影响,一般采用k1≈0.2,K2≈1.02.然而在极低风速下,特别是1 m/s以下,由于热线的传热机理发生变化,所以K1和K2也出现了显著的变化.本文对单丝探针和双丝探针方向特性进行了探讨性的研究,实验表明,风速小于3m/s时,K1和K2随速度发生变化,且θ对K1以及ψ对K2都有影响.当取ψ和θ为90°时,K1和K2在整个角度范围内计算速度的误差较小. 相似文献
33.
等离子喷涂层接触疲劳失效模式及失效机理的研究 总被引:5,自引:1,他引:5
研究了等离子喷涂层在不同应力水平下的接触疲劳失效模式与声发射幅值的对应关系,并分析了涂层的接触疲劳失效机理.结果表明:声发射幅值与接触应力的大小无明显的关系,根据疲劳失效时的声发射幅值可以判断涂层接触疲劳失效模式,幅值为87~93 dB时易发生剥落或分层失效,幅值为78~83 dB易发生点蚀失效.涂层表面微凸体与轴承球滚压接触产生黏着磨损以及涂层、磨粒、轴承球三者形成的三体磨料磨损是点蚀失效产生的主要原因.剥落失效主要与涂层表面微观缺陷处裂纹的萌生、扩展以及表面磨损行为有关.层内分层失效是由涂层内部最大剪切应力控制的,而界面分层失效主要是由涂层与基体的低结合强度、热失配以及界面剪切应力造成的. 相似文献
34.
35.
为制备适用于干压成型的氧化铝造粒粉,研究了PEG聚合度对氧化铝造粒粉微观形貌、流动性和松装密度的影响.结果表明PEG的聚合度对氧化铝浆料粘度影响显著,PEG2000-6000是较为理想的粘结剂选择,造粒粉的流动性与环境温度及湿度相关.采用正交实验设计,以造粒粉的流动性和松装密度为评价指标,对PEG聚合度、粘结剂添加量和固含量进行了优选,其影响顺序为PEG聚合度>固含量>粘结剂添加量.以优选参数PEG6000、添加量为4wt;、固含量为80wt;,制备了性能优良的氧化铝喷雾造粒粉. 相似文献
36.
The present modeling of a free-burning argon arc accounts for copper vapor contamination from the anode. Simulations are made for an atmospheric arc that has a length of 10 mm and an electric current of 200 amps. Predicted results for two different anode evaporation rates are compared to those from a pure argon arc with no copper vapor contamination. Copper vapor concentration, temperature, electric potential, and current density profiles are presented. Included in this analysis are radiation losses from both the argon and copper by using recently calculated net emission coefficients. It was found that evaporation of copper from the anode results in a cooling of the arc in a region close to the anode, but has an insignificant influence on the arc close to the cathode. Due to the arc flow characteristics most of the copper vapor tends to be confined to the anode region. 相似文献
37.
To understand the effect of Au and thiol atoms in octane molecule, a structural and charge density analysis has been carried out by high level ab initio quantum chemical calculations using MP2 and B3PW91 methods with the basis sets 6-311G(d,p) and LANL2DZ. The optimized geometries, specifically, the geometry obtained from both levels reveal the effect of S- and Au-atoms in octane molecule. An introduction of sulfur atom in octane molecule lengthen its backbone C–C bond distances, and further adding of Au-atom at the terminals of octane dithiolate stabilizes these distances. The bond densities of the C–C bonds of octane are 1.6 eÅ−3, these values are decreased significantly and the charges are largely depleted, when thiol and Au-atoms added in the octane molecule. The presence of negative Laplacian 2ρ(r) at bond critical points of C–C and C–H bonds, indicate, the charges are concentrated in these bonds, confirm that these bonds exhibit an open shell type interaction. The moderate values of density and the negative Laplacian of S–C bonds confirm the covalent character. The positive 2ρ(r) value of Au–S bonds, characterize, the bonding interaction is a closed shell interaction. The combined observed low value of electron density and the positive Laplacian of Au–S bond comprises, the gold and S interaction is not a covalent interaction, but it is a very weak coordination bond interaction. The small positive value of total energy density in Au–S bond indicates, the charges in these bonds are highly depleted and this is further confirmed by the Laplacian of bond characterization. 相似文献
38.
Determination of the arc-root position in a DC plasma torch 总被引:4,自引:0,他引:4
Seungho Paik P. C. Huang J. Heberleinand E. Pfender 《Plasma Chemistry and Plasma Processing》1993,13(3):379-397
The behavior of an arc operated in the nontransferred mode with a conical-shaped cathode and a nozzle-shaped anode is studied by applying general tyro-dimensional conservation equations and auxiliary relations for the simulation of arc channel flows. The position of the arc-root attachment at the anode surface is determined by using Steenbeck's minimum principle, which postulates a minimum arc voltage for a given current and certain given boundary conditions. The overall effects of the anode-arc root on the plasma flow are, studied by comparing the results with those of the transferred mode of operation. Specific arc-channel diameters are chosen in the simulation in order to verify flit, numerical model through comparisons with experimental results. The results show that Steenbeck's minimum principle is useful for determining the position of the arc-root attachment at the anode surface. Application of this method for control of the arc-anode attachment may be valuable in the design and operation of plasma spray torches to avoid jet instabilities. 相似文献
39.
V. P. Bubnov I. S. Krainskii E. E. Laukhina E. B. Yagubskii 《Russian Chemical Bulletin》1994,43(5):746-750
The effect of the parameters of the electric arc (helium pressure, current and voltage, clearance between electrodes) and of the peculiarities of the setup design (arrangement of electrodes, distance between the arc and the cooling surface, temperature of the soot condensation surface) on the yield of fullerenes has been studied. Conditions for producing soot with a C60 and C70 content up to 43% (toluene extract) have been found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 805–809, May, 1994.The authors are grateful to N. G. Spitsyna and A. V. Dubovitskii for the determination of the content of C60 and C70 fullerenes in the extract.The work was financially supported by the Russian Foundation for Basic Research (Project 93-03-18705). 相似文献
40.
The coloration of glass via melting techniques presents some unique problems with respect to the reproducibility, toxicology and economics of certain colors, especially if the market demands are highly variable. This is also the case for consumer products such as crystal glass and tableware. Traditionally, the decoration of crystal glasses is performed by laborious manual techniques, which are costly and do not meet modern market requirements. Alternatively, spraying of colored lacquers is a highly flexible and valuable tool for the development of new products. Sol-gel type hybrid coatings provide several advantages compared to conventional organic systems like high abrasion resistance, almost perfect adhesion, refractive index matching and sufficient stability in dishwashing procedures. The solubility of organic dyes in the hybrid matrix is sufficient for intense colors even at rather low layer thicknesses, which on the other hand convey the high brilliance of the base material. The development of transparent, translucent and opaque hybrid coatings for crystal glass has been completed in the last few years and the production of partially coated articles has started recently. The synthesis and properties of the coating material are reviewed and the industrial process and first market results are also outlined. 相似文献