Application of 1H NMR in the flow surveillance of oil wells

Test‐separator units, as traditional methods of well surveillance, mainly suffer from their inherent constraints including the expensive instrumental, mechanical, electrical, piping and safety devices along with technical and protective inspections, repair and operation services, facilities and infrastructures. Other problems are time and cost consuming, uncertainty of well isolation in test separator and need to close the co‐line wells, which are diminished using multivariate thermal well testing. A novel approach was proposed and tested to classify the oil samples taken from individual wells by source and type. The novelties of this work were the use of the applied aspects of ¹H NMR spectroscopy in petroleum upstream engineering, the replacement of traditional test methods, the improvement of the confidence of tests and the recognition of multisource streams. The weighed sum method was used to correlate the spectra information, taken from the samples of Iranian offshore oil wells. The experimental results and the field data revealed that the present approach was appropriate for precocious, quick and reliable surveillance of individual oil wells located in an oil field. The model was supported by field experiments and has predicted the accurate productivity of oil wells with respect to the current expensive techniques since 2010. Copyright © 2012 John Wiley & Sons, Ltd.     

Mechanism of interaction of pressure waves at a discrete partial blockage

This paper analyses the mechanism of interaction between an incident pressure wave and blockages of different geometrical characteristics (i.e., a butterfly and a ball valves, two short stretches of pipe with a reduced diameter, and a device simulating a longitudinal body blockage) by means of laboratory and numerical tests. Experiments have shown that the mechanism of interaction with pressure waves is influenced by their path through the device: sinuous because of the device body for partially closed in-line valves (type I mechanism), and straight for the small bore pipe devices (type II mechanism). Type I mechanism is characterized by a rise followed by an almost constant value whereas in type II one a drop occurs after the rise. To complete the investigation the effect of the pre-transient condition is discussed.     

Advanced high-performance liquid chromatography method for highly polar nitroaromatic compounds in ground water samples from ammunition waste sites

An advanced HPLC-photodiode array detection method for the determination of 12 selected highly polar nitroaromatic compounds in ground water samples of ammunition waste sites has been developed and validated. After solid-phase extraction the limits of detection were in the range 0.1–0.5 μg/l. To prove the applicability of the method to other polar nitroaromatic compounds the retention time of another 32 polar compounds under the specified chromatographic conditions were determined and their UV spectra recorded. To review the method, interlaboratory comparisons were performed with a spiked and a real ground water sample.     

Boundary layers for parabolic perturbations of quasi‐linear hyperbolic problems

In this paper, we study the asymptotic relation between the solutions to the one‐dimensional viscous conservation laws with the Dirichlet boundary condition and the associated inviscid solution. We assume that the viscosity matrix is positive definite, then we prove the existence and the stability of the weak boundary layers by discussing nonlinear well‐posedness of the inviscid flow with certain boundary conditions. Copyright © 2009 John Wiley & Sons, Ltd.     

Risk perceptions and rationality in measures of risk

Individuals may have biased perceptions of health and safety risks. We conjecture perceptions of mortality risk from various risk measures using parametric and non-parametric methods. We investigate how risk perceptions are measured and what rational explanations can be found for these measures with implication for risk and solvency.     

Application to other fields of techniques used for gravity wave detection

Summary The experimental techniques developed to build a sensitive gravitational wave antenna can find application in many different fields of research. In the present paper we discuss briefly two experiments that we are developing in the Istituto Fisica Spazio Interplanetario of C.N.R. More precisely, a noncryogenic gravity gradiometer to be flown on the subsatellite of the TSS and a cryogenic force sensor which will be used to verify some recent results on the interaction of neutrino with matter are described. To speed up publication the proofs were not sent to the authors and were superivised by the Scientific Committee.     

Innovative stabilization/solidification processes of fly ash from an incinerator plant of urban solid waste

Fly ash samples from an incineration plant of urban solid waste (USW) were submitted to a stabilization/solidification process based on encapsulation with a polyester resin. With this process, a very limited increase of about 25% in weight and a compressive strength as high as 1200 kg/cm² can be obtained. The efficiency of the process to stabilize/solidify the residues and to reduce the pollutant release was evaluated by performing both mechanical and leaching tests following the IRSA–CNR standard method. The leaching test was based on treating the sample with an acetic acid solution adjusted to pH 5.2 for 24 h under magnetic stirring. Toxic metals (Pb, Cd, and Cu) and organic pollutants (PAHs, PCBs, and OCPs) were determined in raw fly ash samples and in the leaching solutions of treated samples. Raw residues showed higher concentrations of trace metals than the regulatory limits, whereas the stabilized/solidified residues showed a concentration of all the pollutants lower than the regulatory limits and a compressive strength much higher than the suggested minimum value. Finally, a critical comparison with conventional stabilization/solidification processes based on the use of Portland cement highlighted that the polyester resin-based process performed much better in terms of the release of both organic and inorganic pollutants, thus substantially lowering the environmental impact of these residues.     

The analytical solution and the complete electronic structure of quantum well

With a detailed analysis of the Bloch wave properties of one-dimensional infinite crystal, we find the exact analytical solution of the quantum confinement states in quantum well with infinite barrier. Based on the analytical solution, we calculate the complete electronic structure of quantum well with arbitrary geometries. The calculation results demonstrate that the transitions only occur between specific pairs of sub-bands. It also shows that the band edge state plays an insignificant role in the optical properties, although it is the most distinguishing feature of the quantum well.     

二维井眼轨道设计模型及应用

讨论了一般二维井眼轨道设计问题.建立了二维轨道设计一般数学模型,根据轨道设计约束方程,可任意选择两个设计参数作为未知数进行求解,得到了全部解析计算公式.这种方法设计计算简单、精确、快速、灵活,具有普遍适用性.可广泛用于二维定向井、水平井和多目标井的设计,为井眼轨道设计提供了理论依据.     

Electronic speckle pattern interferometry analysis of tensile tests of semihard copper sheets

Uniaxial tension tests of semihard copper sheets were studied by means of electronic spekle pattern interferometry (ESPI). The setup allowed the authors to analyze in detail the transitions from elastic to plastic behavior and from homogeneous to inhomogeneous plastic deformation. In agreement with the conventional definition of the yield point for copper fully plastic behavior starded at permanent strains close to 0.005. The strain-hardening coefficient was very low at the early stage of plastic flow (“easy glide”), increasing progressively until values on the order of 0.13 to 0.14 were reached at maximum load. A this point, the appearance of unequally spaced fringes signaled the beginning of inhomogeneous deformation. With ESPI, this occurrence may thus serve as a criterion to establish the forming limit of the material.