三维非结构粘性网格生成方法

描述了一套适合粘性流动计算的三维非结构网格自动生成方法.在物面附近的粘性作用区域,采用推进层方法生成各向异性的"扁平"四面体网格,并通过一定的网格伸长控制参数,实现整个流场区域网格高度的平滑过渡.当粘性网格的推进高度达到预定要求时,推进层方法自动停止,转而采用阵面推进方法生成常规意义的尽量接近正四面体的各向同性网格.同时给出了利用该方法生成的M6机翼非结构粘性网格来求解机翼粘性绕流的简单算例.     

A Complex Mode Method for Wind-Induced Responses of 6-Parameter Practical Viscoelastic Damping Energy Dissipation Structures Based on the Davenport Wind Speed Spectrum北大核心CSCD

针对六参数实用黏弹性阻尼耗能结构,基于Davenport风速谱系列响应问题进行了系统的研究.首先,利用六参数黏弹性阻尼器的微分型本构关系,建立了耗能结构基于Davenport风速谱激励下的运动方程;然后,运用复模态法将耗能结构的运动方程由二阶微分方程转化为一阶方程,获得了耗能结构系统对风振激励响应的频域解和功率谱密度函数表达式;最后,利用数学恒等式,基于随机振动理论获得了耗能结构系统在Davenport风速谱激励下的响应和阻尼器受力的解析解.该文方法不仅考虑了结构系统在风振激励作用下全振型展开的结果,表达式较现有结果更为简便,效率及精度更高,且适用于非经典阻尼结构.     

Global classical solutions to the compressible micropolar viscous fluids with large oscillations and vacuum

In this paper, we consider the three dimensional Cauchy problem of the compressible micropolar viscous flows. We prove the existence of unique global classical solution for smooth initial data with small initial energy but possibly large oscillations and the initial density may allowed to contain the interior and far field vacuum states. Furthermore, the large time behavior of the solution is obtained as well.     

固壁近旁Stokes流中粘性液滴的运动和变形

发展了一种模拟固壁近旁轴对称Stokes流中粘性液滴的运动和变形及直接计算固壁上应力的边界积分方法．用此方法对不同的液滴-固壁初始相对间距、粘度比、表面张力和浮力联合参数以及环境流动参数情况进行了数值实验．数值结果显示,由于环境流动和浮力的作用,随着时间的推进,液滴在轴向压缩,在径向拉伸．当环境流动的作用弱于浮力作用时,随着时间的推移,液滴上升并向上弯,固壁上由液滴运动所引起的应力不断减小．当环境流动的作用强于浮力作用时,随着时间的推移,液滴变得越来越扁．在这种情形,当大初始间距时,壁面上的应力随液滴的演变而增大;当小初始间距时,由环境流动、浮力及壁面对流动的较强作用的联合影响,此应力随液滴的演变而减小．由于液滴运动所引起的壁面应力的有效作用仅限于对称轴附近的一个小范围内,且此范围随液滴与固壁的初始间距增大而增大．应力的大小随初始间距增大而大为减小．表面张力对液滴变形有阻止作用．液滴粘性会减小液滴的变形和位置迁移．     

弱粘性流体中垂直激励表面波的阻尼效应

在竖直振动的圆柱形容器中,将Navier-Stokes方程线性化,利用两时间尺度奇异摄动展开法研究了弱粘性流体的单一自由面驻波运动．整个流场被分为外部势流区和内部边界层区两部分,对两部分区域分别求解,得到包含阻尼项和外驱动影响的线性振幅方程．利用稳定性分析,得到形成稳定表面波的条件,给出了临界曲线．此外,还获得了阻尼系数的解析表达式．最后,将线性阻尼加到理想流体条件下所得到的色散关系中对其进行修正,理论结果证明修正后的驱动频率更加接近实验的结果．通过计算发现,当驱动的频率较低时,流体的粘性对表面波模式选择有重要影响,而表面张力的影响不明显;但当驱动频率较高时,流体的表面张力起主要作用,而流体的粘性影响甚小．     

Viscosity and Thermodynamics of Viscous Flow of 1-propanol with Aniline,N-methylaniline and N,N-dimethylaniline

Abstract

Viscosities of the systems, 1-propanol + aniline, 1-propanol+N-methylaniline and 1-propanol+N,N-dimethylaniline have been measured in the temperature range 294.15 to 323.15K for the whole range of composition. The viscosities have been plotted against mole fraction of anilines. The viscosity-composition curves show minima, though not well-defined, in highly rich, moderately rich and moderately poor regions of 1-propanol respectively for 1-propanol + aniline, 1-propanol + N-methylaniline and 1-propanol +N,N-dimethylaniline systems. The excess viscosities have been found to be negative for all the systems throughout the whole composition and plotted against mole fraction of anilines. The thermodynamic activation parameters, such as, enthalpies, entropies and free energies and their excess values have been evaluated. The excess free energies have been found to be negative for all the systems and over the whole range of composition. The excess free energies have been plotted against the mole fraction of anilines. The viscosities, excess viscosities and excess free energies have been explained by assuming that the associated compounds, aniline, N-methylaniline and 1-propanol, are dissociated into smaller units in the solution systems by the rupture of H-bonds.     

Enzyme immobilization strategies for the design of robust and efficient biocatalysts

Different strategies for the preparation of efficient and robust immobilized biocatalysts are here reviewed. Different physico-chemical approaches are discussed.i.- The stabilization of enzyme by any kind of immobilization on pre-existing porous supports.ii.- The stabilization of enzymes by multipoint covalent attachment on support surfaces.iii.- Additional stabilization of immobilized-stabilized enzyme by physical or chemical modification with polymers.These three strategies can be easily developed when enzymes are immobilized in pre-existing porous supports. In addition to that, these immobilized-stabilized derivatives are optimal to develop enzyme reaction engineering and reactor engineering. Stabilizations ranging between 1000 and 100,000 folds regarding diluted soluble enzymes are here reported.     

Oxidation of Benzoins to Benzils with Chromium Trioxide Under Viscous Conditions

Reaction of chiral allylic cyclic carbonates with Grignards reagent in the presence of NiCl₂(dppe) as a catalyst afforded the alkylated (E)-allylic alcohols with high regio- and diastereoselectivity.