超微弱发光图像的统计处理方法

应用超高灵敏度的光电成像系统，获得了活体昆明鼠的超微弱生物发光图像，并用概率统计理论研究了光子图像中的光子频数分布，得到了一种去除噪声的原则。文中首次提出了用Ｘ＾２准则拟合实际图像中的信号区和背景区分布，并根据得到的统计估计值对光子图像进行处理的方法，该法对实验获得的昆明鼠的超微弱生物发光有较好的处理效果，提高了图像的信噪比，得到了好的观察效果。     

Detection and analysis of radio pulses from extensive air showers

Radio pulses from extensive air showers (EAS) at 30, 44, and 60 MHz frequencies have been studied, using wide band broad-side arrays of half-wave dipole antenna systems. The experimental results support the theoretical prediction that the field strength of radio emission depends on the shower size. An asymmetry has been noticed in the pulse height distributions of radio pulses detected by North-South and East-West directed arrays. These observations are in agreement with the theory that the charge separation mechanism is predominant in generating radio pulses from EAS and radio emission is polarised in the East-West direction. Experimental data are compared with those of earlier workers.     

微型超高压宝石喷嘴内部的空化与磨损

宝石喷嘴是影响超高压水射流切割系统工作效率的重要部件,而宝石内部的空化直接影响射流的形成,也是宝石磨损的重要原因之一。对400 MPa压力范围内宝石孔内部的空化两相流进行了数值模拟,阐述了射流在宝石内的形成过程,分析了长径比、压力和入口形状对宝石内空化的影响,并在相应压力下对宝石喷嘴的磨损进行了实验研究。结果表明:宝石内部的空化发展程度随着长径比的增大而减弱;在一定的长径比范围内,空化可以发展到喷嘴出口,并最终使射流的初始直径小于喷嘴直径,且在此条件下当压力升高时,射流的初始直径增大;良好的入口形线可以降低空化的发展程度;宝石入口的磨损较出口更显著,空蚀和高压水的冲蚀造成了宝石孔边缘形状的破坏,这种破坏随着压力的升高而加剧,选择合适的长径比是减少冲蚀磨损的有效途径。     

超快中子探测器闪烁体性能计算

超快中子探测器是ICF聚变反应速率测量系统的核心部件。利用蒙特卡罗粒子输运工具包Geant4模拟了一种超快中子探测器——BC-422型闪烁探测器的中子探测过程,计算出了几种厚度的BC-422型闪烁体的探测效率、输出光信号强度和时间分辨力;对比了闪烁体的2种不同反射表面对输出光信号强度和时间分辨力的影响。计算的结果显示:设计适当的BC-422型闪烁探测器能够测量的最低中子产额在108量级,对DT中子的信号时间分辨力好于20 ps,对DD中子的信号时间分辨力达到30 ps,能够用于大型激光装置及其原型的聚变反应速率测量。     

Quasi in situ Ni K‐edge EXAFS investigation of the spent NiMo catalyst from ultra‐deep hydrodesulfurization of gas oil in a commercial plant

Ni species on the spent NiMo catalyst from ultra‐deep hydrodesulfurization of gas oil in a commercial plant were studied by Ni K‐edge EXAFS and TEM measurement without contact of the catalysts with air. The Ni–Mo coordination shell related to the Ni–Mo–S phase was observed in the spent catalyst by quasi in situ Ni K‐edge EXAFS measurement with a newly constructed high‐pressure chamber. The coordination number of this shell was almost identical to that obtained by in situ Ni K‐edge EXAFS measurement of the fresh catalyst sulfided at 1.1 MPa. On the other hand, large agglomerates of Ni₃S₂ were observed only in the spent catalyst by quasi in situ TEM/EDX measurement. MoS₂‐like slabs were sintered slightly on the spent catalyst, where they were destacked to form monolayer slabs. These results suggest that the Ni–Mo–S phase is preserved on the spent catalyst and Ni₃S₂ agglomerates are formed by sintering of Ni₃S₂ species originally present on the fresh catalyst.     

Growth,structural and optical properties of 12%‐deuterated KDP crystals

K(D_0.12H_0.88)₂PO₄ crystals were chosen to be used for quadratic nonlinear medium of wideband frequency doubling at 1 μm. A key limitation on this application is that little information can be found in the previous reports. In this work, growth as well as structural and optical properties of this crystal were investigated in detail. Experimental results in comparison with KDP indicate that lattice parameter along a‐axis changes much more than lattice parameter c and infra‐red absorption edge shift by 0.08 μm accompanied with increasing of transmittance in the whole region. With the introduction of deuterium atom, peak of ν₁(PO4) shifts to lower wave number and transverse stimulated Raman scattering was effectively suppressed. Extra‐ordinary and ordinary indices were also measured as function of wavelength. Good crystalline perfection and great performance of damage threshold also indicate that 12%‐DKDP is an appropriate choice in the application of wideband frequency doubling at 1 μm.     

Quasi-static deformation and final fracture behaviour of aluminium alloy 5083: influence of cryomilling

The commercial aluminium alloy 5083 was processed via cryomilling to produce nanocrystalline (NC) powders with an average grain size of ～25–50?nm. The powders were subsequently degassed at 723 K (450°C), pre-heated and immediately quasi-isostatic (QI)-forged to produce a thermally stable bulk ultrafine grain (UFG) material having average grain size values ranging from 190 to 350?nm, depending on the processing conditions used. In this paper, the tensile properties and fracture behaviour of the bulk UFG material are presented and compared with the tensile properties of its conventionally processed counterpart. The specific influence of preheat temperature on strength and ductility of the alloy is briefly discussed. Three different pre-heat temperatures of 523, 623 and 723?K (250, 350 and 450°C) were chosen and used with the primary objective of controlling grain growth during forging. The influence of preheat temperature on tensile deformation and final fracture behaviour is highlighted. The macroscopic fracture modes of the bulk nanostructured material (BNM) prepared following three pre-heat temperatures are investigated. The microscopic mechanisms controlling tensile deformation and final fracture behaviour are discussed with regards to the intrinsic microstructural effects in the UFG alloy, nature of loading, and the kinetics and mechanisms of deformation.     

Rapid synthesis and characterization of ultra‐thin shell Au@SiO2 nanorods with tunable SPR for shell‐isolated nanoparticle‐enhanced Raman spectroscopy (SHINERS)

The recently reported shell‐isolated nanoparticle‐enhanced Raman spectroscopy (SHINERS) is considered as the next generation of advanced spectroscopy for its surface and molecular generality. With the aim to utilize the virtues of shell‐isolated strategy and advance the SHINERS technique, we introduce a silane‐based rapid synthesis method of silica‐coating Au nanorods (Au@SiO₂ NRs) with manoeuvrable ultra‐thin shell and tunable SPR. The results demonstrate that the SPR of Au NRs could be optimized to obtain large Raman enhancement using either 633 nm or 785 nm laser. Differing from previously reported Au@SiO₂ NRs synthesis method, we can tune the silica shell thickness within several nanometers to maximize the Raman signal while effectively eliminating the exterior interference. And this advanced synthesis method has also significantly reduced the silica‐coating time from one day to ca. 1 h. This method as a new development of SHINERS technique has successfully got enhanced signal in solution Raman tests of malachite green, giving a great potential to be extended to in‐situ measurement for daily life detection. Copyright © 2013 John Wiley & Sons, Ltd.     

QuEChERS/超高效液相色谱-串联质谱法快速测定土壤中19种氟喹诺酮类抗生素残留

建立了一种基于QuEChERS前处理技术,结合超高效液相色谱-串联质谱(UPLC-MS/MS)和内标法,快速测定土壤中19种氟喹诺酮类抗生素(FQs)残留的分析方法。5. 0 g土壤样品添加200μg/kg基质匹配同位素内标后,经20 m L 0. 1 mol/L EDTA-McIlvaine缓冲液和乙腈混合溶剂(体积比1∶1)提取,基质分散固相萃取(150 mg无水MgSO4、15 mg PSA、15 mg C18)净化后,采用UPLC-MS/MS进行测定。质谱分析采用电喷雾电离,正离子扫描,多反应监测模式。在优化条件下,19种抗生素的相关系数(r~2)为0. 992～0. 998,检出限为0. 2～1. 0μg/kg,定量下限为1. 0～5. 0μg/kg;在10、50、200μg/kg加标水平下的回收率为65. 2%～104%,相对标准偏差(n=5)不大于14%。该方法操作简单快速、准确度高,适用于土壤中氟喹诺酮类抗生素残留的检测。     

Guidelines for tuning the macropore structure of monolithic columns for high‐performance liquid chromatography

The ability to control the external porosity and to tune the dimensions of the macropore size on multiple length scales provides the possibility of tailoring the monolithic support structure towards separation performance. This paper discusses the properties of conventional polymer–monolithic stationary phases and its limitations regarding the effects of morphology on kinetic performance. Furthermore, guidelines to improve the macropore structure are discussed. The optimal monolithic macropore structure is characterized by high external porosity (while maintaining ultra‐high‐pressure stability), high structure homogeneity, polymer globule clusters in the submicron range, and macropores with a diameter tuned toward speed (small diameter in the 100–500 nm range using short beds) or efficiency (larger macropores in the range of 500 nm–1 μm allowing the use of longer column formats). Finally, promising approaches to control the morphology are discussed.