全文获取类型
收费全文 | 18997篇 |
免费 | 2718篇 |
国内免费 | 1937篇 |
专业分类
化学 | 12701篇 |
晶体学 | 256篇 |
力学 | 761篇 |
综合类 | 185篇 |
数学 | 807篇 |
物理学 | 8942篇 |
出版年
2024年 | 57篇 |
2023年 | 219篇 |
2022年 | 621篇 |
2021年 | 642篇 |
2020年 | 661篇 |
2019年 | 624篇 |
2018年 | 548篇 |
2017年 | 721篇 |
2016年 | 857篇 |
2015年 | 822篇 |
2014年 | 1014篇 |
2013年 | 1816篇 |
2012年 | 1198篇 |
2011年 | 1173篇 |
2010年 | 981篇 |
2009年 | 1195篇 |
2008年 | 1116篇 |
2007年 | 1081篇 |
2006年 | 1040篇 |
2005年 | 996篇 |
2004年 | 883篇 |
2003年 | 724篇 |
2002年 | 593篇 |
2001年 | 423篇 |
2000年 | 491篇 |
1999年 | 412篇 |
1998年 | 316篇 |
1997年 | 299篇 |
1996年 | 293篇 |
1995年 | 238篇 |
1994年 | 221篇 |
1993年 | 195篇 |
1992年 | 174篇 |
1991年 | 135篇 |
1990年 | 127篇 |
1989年 | 112篇 |
1988年 | 104篇 |
1987年 | 76篇 |
1986年 | 76篇 |
1985年 | 71篇 |
1984年 | 65篇 |
1983年 | 26篇 |
1982年 | 54篇 |
1981年 | 36篇 |
1980年 | 19篇 |
1979年 | 25篇 |
1978年 | 12篇 |
1977年 | 9篇 |
1976年 | 7篇 |
1973年 | 25篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
C. Vaca‐Garcia G. Gozzelino W. G. Glasser M. E. Borredon 《Journal of Polymer Science.Polymer Physics》2003,41(3):281-288
The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003 相似文献
62.
Electron paramagnetic resonance (EPR) investigations has been carried out on the new family of molybdenum doped vanadium sesquioxides (V1−xMox)2−δO3. The oxidation effects were monitored from the rate of paramagnetic V4+ created when the sample is exposed to the air. The effects of the oxidation time, sample temperature, and annealing at 1000 °C under a diluted hydrogen atmosphere on the EPR signal features are analyzed. The V4+ concentration in the oxidized samples is determined and the relaxation effects driven by the conduction electrons are pointed out from the thermal behaviour of the EPR line features. EPR spectra of all the oxidized samples also reveal a small ferromagnetic contribution strongly correlated with the V4+ content. 相似文献
63.
U. Turgut 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,86(4):353-359
The Coster-Kronig transition, f23, was determined using differential fluorescence cross sections of Ll X-ray for Th and U. The targets were irradiated an Am-241 radioisotope at the different incident angle. The Ll X-rays were counted with a Si (Li) detector at the different scattering angle varying from 60° to 90° at 10° intervals. For each angle, the Coster-Kronig transition probability, f23, was found. An obtained Coster-Kronig transition probability value was fitted versus emission angle. According to present results we can say that the Coster-Kronig transition probability, f23, shows isotropic distribution. 相似文献
64.
It is suggested that the question of existence of a jamming phase transition in a broad class of single-lane cellular-automaton traffic models may be studied using a correspondence to the asymmetric chipping model. In models where such correspondence is applicable, jamming phase transition does not take place. Rather, the system exhibits a smooth crossover between free-flow and jammed states, as the car density is increased. 相似文献
65.
We study the elastic responses of double-(ds) and single-stranded (ss) DNA at external force fields. A double-strand-polymer
elastic model is constructed and solved by path integral methods and Monte Carlo simulations to understand the entropic elasticity,
cooperative extensibility, and supercoiling property of dsDNA. The good agreement with experiments indicates that short-ranged
base-pair stacking interaction is crucial for the stability and the high deformability of dsDNA. Hairpin-coil transition in
ssDNA is studied with generating function method. A threshold force is needed to pull the ssDNA hairpin patterns, stabilized
by base pairing and base-pair stacking, into random coils. This phase transition is predicted to be of first order for stacking
potential higher than some critical level, in accordance with experimental observations. 相似文献
66.
The crystal structure of [N(CH3)4]3[As2Cl9] is determined at 293 K. It crystallizes in trigonal space group P31c: a = 9.2199(8), c = 21.065(3)Å, Z = 2, R1 = 0.0505, wR2 = 0.1283. The crystal is built of the discrete bioctahedral [As2Cl9]3— anions and the deformed tetramethylammonium cations. A structural phase transition in [N(CH3)4]3[As2Cl9] is detected by the DSC and dilatometric techniques at 146/151 K (on cooling/heating). Dielectric relaxation studies in the frequency range 75 kHz — 5 MHz indicate reorientations of the tetramethylammonium cations within the high temperature phase. Optical observations show the existence of the ferroelastic domain structure below 146 K. The possible mechanism of phase transition is discussed on the basis of the presented results. 相似文献
67.
I. Iovel L. Golomba J. Popelis S. Grinberga E. Lukevics 《Chemistry of Heterocyclic Compounds》2003,39(1):49-55
The addition of hydrosilanes (HSiEt3, HSiMe2Ph, H2SiPh2) to the CH=N bond of heterocyclic azomethines has been studied in the presence of monovalent complexes of rhodium and palladium. The effect on the reaction of the CF3 group of the aldimines, which were obtained from O-, S-, and N-heteroaromatic aldehydes and 2-trifluoromethylaniline, has been clarified, as were other regularities of the processes being studied. A series of corresponding furans, thiophenes, and pyridine amines has been synthesized. 相似文献
68.
5‐Methylene‐2‐oxazolidinone (1) and 5‐methylene‐1,3‐thiazolidine‐2‐thione (4) react with various isocyanates to give the corresponding urethanes 3 and 5 in high yields in the presence of palladium(0) or palladium(II) catalyst under mild reaction conditions. A mechanism is proposed. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
69.
利用相干渡越辐射(CTR)测量短和超短电子束团长度是国际上束测领域新发展的频域测量技术.文中理论分析和数值计算了北京自由电子激光装置的皮秒级的射频电子束团序列产生的CTR,当辐射波长在长于束长(4ps)时,渡越辐射发生相干增强效应;与非相干渡越辐射相比,当λ≥2πσz时,增强的倍数约等于束团中粒子的数目(108);CTR从亚毫米波到毫米波段呈宽带连续谱特性;渡越辐射能量主要集中在轴线附近,宏脉冲辐射能量高达几毫焦.设计采用偏振型束团长度测量系统,利用CTR自相关技术,实验测量该束团序列的纵向长度,并藉助傅里叶变换光谱法,推求束团电子分布. 相似文献
70.