SCDA for 3D lattice gases with repulsive interaction

The selfconsistent diagram approximation (SCDA) is generalized for three-dimensional lattice gases with nearest neighbor repulsive interactions. The free energy is represented in a closed form through elementary functions. Thermodynamical (phase diagrams, chemical potential and mean square fluctuations), structural (order parameter, distribution functions) as well as diffusional characteristics are investigated. The calculation results are compared with the Monte Carlo simulation data to demonstrate high precision of the SCDA in reproducing the equilibrium lattice gas characteristics. It is shown that similarly to two-dimensional systems the specific statistical memory effects strongly influence the lattice gas diffusion in the ordered states. Received 7 August 2002 / Received in final form 22 January 2003 Published online 24 April 2003     

The electrostatics of Einstein’s unified field theory

When sources are added at their right-hand sides, and g_(ik) is a priori assumed to be the metric, the equations of Einstein’s Hermitian theory of relativity were shown to allow for an exact solution that describes the general electrostatic field of n point charges. Moreover, the injunction of spherical symmetry of g_(ik) in the infinitesimal neighbourhood of each of the charges was proved to yield the equilibrium conditions of the n charges in keeping with ordinary electrostatics. The tensor g_(ik), however, cannot be the metric of the theory, since it enters neither the eikonal equation nor the equation of motion of uncharged test particles. A physically correct metric that rules both the behaviour of wave fronts and of uncharged matter is the one indicated by Hély.In the present paper it is shown how the electrostatic solution predicts the structure of the n charged particles and their mutual positions of electrostatic equilibrium when Hély’s physically correct metric is adopted.     

Unitarily Inequivalent Representations in Algebraic Quantum Theory

It has been maintained that the physical content of a model of a system is completely contained in the C∗-algebra of quasi-local observables that is associated with the system. The reason given for this is that the unitarily inequivalent representations of are physically equivalent. But, this view is dubious for at least two reasons. First, it is not clear why the physical content does not extend to the elements of the von Neumann algebras that are generated by representations of . It is shown here that although the unitarily inequivalent representations of are physically equivalent, the extended representations are not. Second, this view detracts from special global features of physical systems such as temperature and chemical potential by effectively relegating them to the status of fixed parameters. It is desirable to characterize such observables theoretically as elements of the algebra that is associated with a system rather than as parameters, and thereby give a uniform treatment to all observables. This can be accomplished by going to larger algebras. One such algebra is the universal enveloping von Neumann algebra, which is generated by the universal representation of ; another is the direct integral of factor representations that are associated with the set of values of the global features. Placing interpretive significance on the von Neumann algebras mentioned earlier sheds light on the significance of unitarily inequivalent representations of , and it serves to show the limitations of the notion of physical equivalence.     

Improved Ligand-Field Theory with Effect of Electron-Phonon Interaction

Traditional ligand-field theory has to be improved by taking into account both “pure electronic” contribution and electron-phonon interaction one (including lattice-vibrational relaxation energy). By means of improved ligand-field theory, R₁, R₂, R₃', R₂', and R₁' lines, U band, ground-state zero-field-splitting (GSZFS), and ground-state g factors of ruby and/or GSGG:Cr³⁺ as well as thermal shifts of GSZFS, R₁ line and R₂ line of ruby have been calculated. The results are in very good agreement with the experimental data. Moreover, it is found that the value of cubic-field parameter given by traditional ligand-field theory is inappropriately large. For thermal shifts of GSZFS, R₁ line and R₂ line of ruby, several conclusions have also been obtained.     

Multi-types of Skyrmions in SU(N) Quantum Hall System

The skyrmions in SU(N) quantum Hall (QH) system are discussed. By analyzing the gauge field structure and the topological properties of this QH system it is pointed out that in the SU( N) QH system there can exist ( N - 1)types of skyrmion structures, instead of only one type of skyrmions. In this paper, by means of the Abelian projections according to the (N - 1) Cartan subalgebra local bases, we obtain the (N - 1) U(1) electromagnetic field tensors in the SU(N) gauge field of the QH system, and then derive (N - 1) types of skyrmion structures from these U(1) sub-field tensors. Furthermore, in light of the φ-mapping topological current method, the topological charges and the motion of these skyrmions are also discussed.     

Two-Flux Colliding Plane Waves in String Theory

We construct the two-flux colliding plane wave solutions in higher-dimensional gravity theory with dilaton,and two complementary fluxes. Two kinds of solutions have been obtained: Bell-Szekeres (BS) type and homogeneous type. After imposing the junction condition, we find that only the BS type solution is physically well-defined. Furthermore, we show that the future curvature singularity is always developed for our solutions.     

N2-broadening coefficients in the ν2 and ν4 bands of PH3

N₂-broadening coefficients are measured for 61 transitions of PH₃ in the ^QR branch of the ν₂ band and the ^PP, ^RP, ^SP, and ^PQ branches of the ν₄ band, using a tunable diode-laser spectrometer. The recorded lines with J values ranging from 1 to 16 and K from 0 to 11 are located between 1008 and 1106 cm⁻¹. The collisional widths are determined by fitting each spectral line with a Voigt profile, a Rautian profile, and a speed-dependent Rautian profile. The latter models provide larger broadening coefficients than the Voigt model. These coefficients have also been calculated on the basis of a semiclassical model of interacting linear molecules by considering an atom-atom Lennard-Jones potential in addition to the electrostatic contributions. The theoretical results are in good agreement with the experimental data and reproduce the J dependence of the broadenings, but their decrease at high J values is overestimated for the ^QR (J, K) transitions.     

Adsorption of argon and nitrogen in cylindrical pores of MCM-41 materials: application of density functional theory

Adsorption of argon and nitrogen at their respective boiling points in cylindrical pores of MCM-41 type silica-like adsorbents is studied by means of a non-local density functional theory (NLDFT), which is modified to deal with amorphous solids. By matching the theoretical results of the pore filling pressure versus pore diameter against the experimental data, we arrive at a conclusion that the adsorption branch (rather than desorption) corresponds to the true thermodynamic equilibrium. If this is accepted, we derive the optimal values for the solid-fluid molecular parameters for the system amorphous silica-Ar and amorphous silica-N₂, and at the same time we could derive reliably the specific surface area of non-porous and mesoporous silica-like adsorbents, without a recourse to the BET method. This method is then logically extended to describe the local adsorption isotherms of argon and nitrogen in silica-like pores, which are then used as the bases (kernel) to determine the pore size distribution. We test this with a number of adsorption isotherms on the MCM-41 samples, and the results are quite realistic and in excellent agreement with the XRD results, justifying the approach adopted in this paper.     

The limitimg behaviour of the well width of a quantum two-dimensional metal–insulator transition

Metal–Insulator transition using an exact two-dimensional (2D) dielectric function is investigated for a shallow donor in an isolated well of a GaAs/Ga_1−xAl_sAs superlattice system within the effective mass approximation. Vanishing of the donor ionization energy as a function of well width and the donor concentration suggests that a phase transition is not possible even below a well width of 10 Å, supporting the scaling theory of localization. The effects of Anderson localization, exchange and correlation in the Hubbard model are included in a simple way. The relationship between the present model and the Mott criterion in terms of Hubbard model is also brought out. The critical concentration appears to be enhanced when a random distribution of impurities is considered. The limiting behaviour of the well width for a quantum 2D well is brought out. A simple expression is derived for a Mott constant in 2D, a*N_c^1/2 exp (9.86 exp (−L/a*))=0.123, where N_c is the critical concentration per area. Results are compared with the existing data available and discussed in the light of existing literature.