溶剂对石墨烯量子点荧光性质的影响

采用柠檬酸热解法制备了石墨烯量子点(GQDs),研究了非极性溶剂戊烷,极性溶剂乙醇、丙酮、乙二醇对GQDs荧光性质的影响。透射电子显微镜(TEM)和原子力显微镜(AFM)图像表明,制备的GQDs尺寸分布在2~12 nm(平均尺寸为4.9 nm),分散均匀,高度分布在0.5~2 nm。吸收光谱表明,GQDs具有明显的紫外吸收特性,吸收峰位于259 nm和274 nm。光致发光谱表明,GQDs的发光具有明显的溶剂依赖性。GQDs在极性溶剂乙醇、丙酮、乙二醇中,发光峰的位置依赖于激发波长,发射波长在可见光区。而在非极性溶剂戊烷中,GQDs表现出对激发波长不依赖的荧光性能,且发射波长在近紫外。     

Continuous dependence results for inhomogeneous ill-posed problems in Banach space

We apply semigroup theory and other operator-theoretic methods to prove Hölder-continuous dependence on modeling for the inhomogeneous ill-posed Cauchy problem in Banach space. The inhomogeneous ill-posed Cauchy problem is given by , u(0)=χ, 0?t<T; where −A is the infinitesimal generator of a holomorphic semigroup on a Banach space X, χ∈X, and . For a suitable function f, the approximate problem is given by , v(0)=χ. Under certain stabilizing conditions, we prove that for a related norm, where and M are computable constants independent of β, 0<β<1, and ω(t) is a harmonic function. These results extend earlier work of Ames and Hughes on the homogeneous ill-posed problem.     

长程相依情形下部分线性回归模型的估计理论

讨论固定设计点部分线性模型Yn,j=xn,jβ g（tn,j） En,jj=1,2,…;n,其中（xn,j,tn,j）∈R×[0,1]是非随机的固定设计点,β是待估计的本知参数,g（.）是定义在[0,1]则上的未知的光滑函数,{En,j}是长程相依的随机误差．本文在一定的正则性条件下得到了部分线性模型中参数β和函数g(.)的估计的弱相合性、均方相合性和收敛速度,同时得到了这些估计的渐近表示和渐近分布．本文所得到的结果与独立和弱相依情形下的结果有很大的差别．     

考虑路径相关性的非比例循环塑性本构模型

根据非比例加载下金属材料响应的延迟特性及加载路径相关性,选取沿应力迹法向的塑性应变的累积量作为非比例加载影响的度量,相应给出反映非比例附加强化的变量,并假设其模量和强化率与加载路径的几何参数相关．为反映由于非比例加载而引起的材料强化的异向效应,在Valanis的塑性内时响应方程中引入与加载路径几何性质有关的应力项,构成非比例循环塑性本构关系．对316和304不锈钢材料在一些典型非比例循环加载路径下的应力响应进行了理论预测,与Benallal等及McDowell的实验结果取得了良好的一致．     

Conductivity of Phosphoric Acid, Sodium, Potassium, and Ammonium Phosphates in Dilute Aqueous Solutions from 278.15 K to 308.15 K

Precise conductivity measurements on aqueous solutions of phosphoric acid, sodium dihydrogen phosphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, diammonium hydrogen phosphate, sodium phosphate, and potassium phosphate were performed from 5 to 35°C. Data analysis was executed by the use of the Quint–Viallard equation for unsymmetrical electrolytes. Equations are given for the concentration dependence of electrolyte and single-ion conductivities at all temperatures.     

TIME-REVERSAL SYMMETRY AND TIME-DEPENDENT PHYSICS

In this letter I study the concept of time-reversal invariance in both classical and quantum physics in the absence of time-translation invariance (explicit time dependence/external time-dependent fields). Accordingly I generalize the concept of time-reversed process when the time-origin of the process has physical significance. The cases of classical physics, standard quantum mechanics and time-neutral quantum mechanics with and without explicit time dependence are discussed.     

Relativistic effects and the halogen dependencies in the 13C chemical shifts of CH4−nIn,CH4−nBrn,CCl4−nIn,and CBr4−nIn (n=0–4)

Linear and nonlinear halogen dependencies of the ¹³C magnetic shielding constants of CH_4−nI_n, CH_4−nBr_n, CCl_4−nI_n, and CBr_4−nI_n were fairly reproduced by the ab initio generalized unrestricted Hartree–Fock (GUHF)/finite perturbation (FP) method including spin‐orbit (SO) interaction and spin‐free relativistic (SFR) terms. As seen from the experimental trends, the calculated ¹³C chemical shifts in CCl_4−nI_n and CBr_4−nI_n depend linearly on n=0–4, while those in CH_4−nI_n and CH_4−nBr_n depend nonlinearly. We found that both the linear and nonlinear dependencies are due to the relativistic effects, and especially due to the Fermi–Contact (FC) term originating from the SO interaction. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 528–536, 2001     

Über röntgenographische Einkristalluntersuchungen an Na2FeAlF7, Na2MIIGaF7 (MII = Ni,Zn) und Na2ZnFeF7 und die Strukturchemie der Weberite

On X-Ray Single Crystal Studies of Na₂FeAlF₇, Na₂M^IIGaF₇ (M^II = Ni, Zn), and Na₂ZnFeF₇ and the Structural Chemistry of Weberites At single crystals of the orthorhombic weberite Na₂NiGaF₇ (a = 716.1, b = 1021.6, c = 740.9 pm; Imma, Z = 4) and of the monoclinic variants (C2/c, Z = 16) Na₂FeAlF₇ (a = 1242.6, b = 727.8, c = 2420.6 pm, β = 99.99°), Na₂ZnGaF₇ (a = 1251.9, b = 730.3, c = 2435.3 pm, β = 99.74°) and Na₂ZnFeF₇ (a = 1261.0, b = 7.359, c = 2453.8 pm, β = 99.70°) complete X-ray structure determinations were performed. The results and the influence of radii on the bridge angles M^II–F–M^II and M^II–F–M^III are discussed in connection with general features within the structural chemistry of 28 weberites.     

Guided transmission of oxygen ions through Al2O3 nanocapillaries

The transmissions of oxygen ions through Al2O3 nanocapillaries each 50 nm in diameter and 10 μm in length at a series of different tilt angles are measured,where the ions with energies ranging from 10 to 60 keV and charge states from 1 up to 6 are involved.The angular distribution and the transmission yields of transported ions are investigated.Our results indicate both the existence of a guiding effect when ions pass through the capillary and a significant dependence of the ion transmission on the energy and the charge state of the ions.The guiding effects are observed to be enhanced at lower projectile energies and higher charge states.Meanwhile,the results also exhibit that the transmission yields increase as the tilt angle decreases at a given energy and charge state.