Research progress in degradation mechanism of silicon anode materials for lithium-ion batteries

硅负极材料由于具有非常高的理论比容量,使之成为锂离子电池极具前景的负极替代材料,然而,硅负极材料在充放电过程中会发生非常大的体积变形,这会引起活性材料的破坏失效,严重影响其电化学循环性能,成为制约其在锂离子电池领域广泛应用的最大瓶颈,本文介绍了硅负极材料的不同结构形态及其在充放电过程中电化学性能的退化机理,并综述了充放电过程中的力学性能演化、相关理论分析、数值模拟计算等方面的最新国际研究进展,展望了硅负极材料力学失效方面的研究重点,     

Comparison between computational fluid dynamics,fluid–structure interaction and computational structural dynamics predictions of flow-induced wall mechanics in an anatomically realistic cerebral aneurysm model

Haemodynamically induced stress plays an important role in the progression and rupture of cerebral aneurysms. The current work describes computational fluid dynamics (CFD), fluid–structure interaction (FSI) and computational structural dynamics (CSD) simulations in an anatomically realistic model of a carotid artery with two saccular cerebral aneurysms in the ophthalmic region. The model was obtained from three-dimensional (3D) rotational angiographic imaging data. CFD and FSI were studied under a physiologically representative waveform of inflow. The arterial wall was assumed elastic or hyperelastic, as a 3D solid or as a shell depending on the type of modelling used. The flow was assumed to be laminar, non-Newtonian and incompressible. The CFD, FSI and CSD models were solved with the finite elements package ADINA. Predictions of velocity field and wall shear stress (WSS) on the aneurysms made using CFD and FSI were compared. The CSD model of the aneurysms using complete geometry was compared with isolated aneurysm models. Additionally, the effects of hypertensive pressure on CSD aneurysm models are also reported. The vortex structure, WSS, effective stress, strain and displacement of the aneurysm walls showed differences, depending on the type of modelling used.     

Numerical analysis of turbulent flow in a rotating U-bend with roughened walls

A numerical analysis has been performed for a developing turbulent flow in a rotating U-bend of strong curvature with rib-roughened walls using an anisotropic turbulent model. In this calculation, an algebraic Reynolds stress model is used to precisely predict Reynolds stresses, and a boundary-fitted coordinate system is introduced as a method of coordinate transformation to set the exact boundary conditions along the complicated shape of U-bend with rib-roughened walls. Calculated results for mean velocity and Reynolds stresses are compared to the experimental data in order to validate the proposed numerical method and the algebraic Reynolds stress model. Although agreement is certainly not perfect in all details, the present method can predict characteristic velocity profiles and reproduce the separated flow generated near the outer wall, which is located just downstream of the curved duct. The Reynolds stresses predicted by the proposed turbulent model agree well with the experimental data, except in regions of flow separation.     

各向同性钢材的断裂模型和屈服模型

基于钢材断裂前必先屈服的基本事实, 以钢材断裂面为屈服面后继扩大直至材料完整性(连续性）发生破坏为假设, 以已有的屈服模型的共同特征为切入点, 建议了各向同性钢材在主应力空间的二次函数型断裂模型和屈服模型. 根据不同钢材的特征应力值, 量化了各向同性钢材的二次函数型断裂模型和屈服模型. 依据不同钢材的特征应力值的相互关系, 建议的各向同性钢材的二次函数型断裂模型和屈服模型相应地描述为主应力空间的圆柱面、椭球面、抛物面和双曲面. 建议的各向同性钢材的二次函数型断裂模型和屈服模型较已有的强度模型更具一般性.     

基于应变计观测数据的混凝土温度应力解析

混凝土温度应力测定一直是人们致力解决的科学难题.本文根据振弦式混凝土应变计的工作原理,提出了基于混凝土应变计观测数据的温度应力计算公式,并采用电热带给试件直接施加温度作用的方法,模拟弹性约束条件进行了温度应力试验测定,确定了计算公式中温度应力修正系数与温度变化的关系.研究结果表明,振弦式混凝土应变计可以用来测定均匀温度作用产生的温度应力,根据本文提出的计算公式得到的温度应力计算值与实测值吻合良好.     

持荷混凝土构件耐久性试验加载装置应用技术

针对混凝土构件耐久性试验环境的腐蚀性和多变性、试验设备容量的限制、混凝土的徐变及加载杆件的松弛等影响,对持荷试件加载装置进行了设计与研究。通过自平衡加载装置对紧固件施加扭矩来控制持荷试件的应力水平,并实时监测不同材质及环境下的扭矩系数、混凝土徐变和紧固件的应力松弛,以此获得扭矩的衰减规律,为试件应力补偿提供理论依据。采用两套加载装置对8根(套)试件进行了测试,试验结果表明,自平衡加载装置适用性强、加载及其补偿简便且能够满足试验要求,持荷试件应力损失在六周后趋于稳定。该装置及其应用技术可用于荷载与环境共同作用下混凝土构件的耐久性试验。     

轻质泡沫混凝土的劈裂破坏力学行为分析

利用平台巴西圆盘加载方式和钢质压条加载方式,对两种厚度为25mm和50mm、不同密度的轻质泡沫混凝土(400～1000kg/m3)进行巴西圆盘劈裂试验,研究密度和厚度对泡沫混凝土裂纹宽度、劈裂强度、断裂韧度、断裂能的影响规律。结果表明,在橡胶垫平台巴西圆盘和钢质压条加载方式下,其劈裂断裂特征大致分为四个阶段:线性弹性段、非线性弹性段、起裂阶段、失稳阶段。同样加载率下最大裂纹宽度随着泡沫混凝土密度增加逐渐减小,劈裂拉伸强度、断裂韧度、断裂能呈幂函数形式增加。借鉴Reinhardt非线性软化曲线,对不同密度泡沫混凝土的应力软化关系进行曲线拟合,建立基于拉伸强度、断裂韧度等控制参数的应力-裂纹宽度关系三段式模型。基于试验结果,对理想多孔材料细观力学预测模型进行修正,获得泡沫混凝土孔隙率与拉伸强度的半经验公式。     

预制裂缝宽度对HCFBD试件确定岩石断裂韧度的影响

为了考察人工预制裂缝宽度对确定岩石断裂韧度的影响,采用大理岩制作了含有不同预制裂缝宽度的中心圆孔裂缝平台巴西圆盘试件(hole-cracked flattened Brazilian disc, HCFBD),在RMT150B试验机上进行试验,对不同预制裂缝宽度圆盘的应力强度因子进行有限元计算,并对测试方法进行了研究。结果表明,采用将预制裂缝宽度视作零宽度裂缝方法确定的断裂韧度值偏低,给出了一种采用最小载荷和最大无量纲应力强度因子确定岩石断裂韧度的新方法,该方法能够消除预制裂缝宽度对圆盘试件测定岩石断裂韧度的影响。     

两种湍流模型时域颤振计算方法研究

采用时域计算分析方法进行了机翼跨音速颤振特性研究。在结构运动网格的基础上,采用格点格式有限体积方法进行空间离散和双时间全隐式方法进行时间推进求解雷诺平均N-S方程。针对流动粘性分别应用了SST湍流模型和SSG雷诺应力模型,通过对跨音速标模算例AGARD445.6机翼的计算结果与实验值的对比分析,其中应用SST湍流模型得到的颤振速度与实验值最为接近,特别是在跨音速段平均相对误差在3%以内;并且计算结果整体上反映了跨音速颤振"凹坑"物理特性,验证了方法的有效性。     

复合材料切口应力奇性指数计算

提出一种计算广义平面应交状态下复合材料切口应力奇性指数的新方法.在切口尖端的位移幂级数渐近展开式被引入正交各向异性材料的物理方程后,将用位移表示的应力分量代入切口端部柱状邻域的线弹性理论控制方程,切口应力奇性指数的计算被转化为常微分方程组特征值的求解.采用插值矩阵法求解该常微分方程组,可一次性地获取切口尖端多阶应力奇性指数.本法适合平面和反平面应力场耦合或解耦的情形,并可退化计算裂纹或各向同性材料切口的应力奇性指数.算例表明,所提方法对分析复合材料切口应力奇性指数是一种准确有效的手段.