全文获取类型
收费全文 | 2155篇 |
免费 | 447篇 |
国内免费 | 507篇 |
专业分类
化学 | 1753篇 |
晶体学 | 21篇 |
力学 | 91篇 |
综合类 | 26篇 |
数学 | 131篇 |
物理学 | 1087篇 |
出版年
2024年 | 12篇 |
2023年 | 33篇 |
2022年 | 117篇 |
2021年 | 140篇 |
2020年 | 177篇 |
2019年 | 117篇 |
2018年 | 110篇 |
2017年 | 93篇 |
2016年 | 145篇 |
2015年 | 116篇 |
2014年 | 140篇 |
2013年 | 161篇 |
2012年 | 156篇 |
2011年 | 150篇 |
2010年 | 112篇 |
2009年 | 166篇 |
2008年 | 128篇 |
2007年 | 130篇 |
2006年 | 150篇 |
2005年 | 112篇 |
2004年 | 108篇 |
2003年 | 76篇 |
2002年 | 77篇 |
2001年 | 66篇 |
2000年 | 51篇 |
1999年 | 38篇 |
1998年 | 40篇 |
1997年 | 34篇 |
1996年 | 25篇 |
1995年 | 28篇 |
1994年 | 14篇 |
1993年 | 14篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1982年 | 6篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1971年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有3109条查询结果,搜索用时 15 毫秒
31.
贮氢合金材料电化学与表面性能的研究进展①杨勇李骏林祖赓(厦门大学化学系,固体表面物理化学国家重点实验室,厦门361005)八十年代后期以来,人们对地球的环境保护提出了更高的要求,而便携式电器(如移动电话,摄像机与笔记本电脑等)对电池的需求也大量增加... 相似文献
32.
The diffraction peak broadening induced by hydrogen absorption-desorption cycling has been analyzed in four different Laves phase compounds with the C14 and C15 structures. The broadening is due to strain most probably originating from dislocations generated at the interface between the α and β hydride phases in connection with the cell volume difference between the two phases. It has been shown that it is strongly compound dependent. In the case of the C14 structure, the broadening is large and isotropic, and the latter can be related to the isotropy of the elastic constants of the metallic phase. The broadening is less for the compounds with the C15 structure, which can be related to a possibly softer lattice. Better ageing properties after long-term cycling are predicted for this crystal structure. 相似文献
33.
A wide variety of liquid streams are generated as
part of the process research and development effort. Frequently these streams
are drummed off, either as intermediates that must be held for processing
or as wastes that must be sent off-site for disposal. Because of the long
times and low concentrations often involved, current thermoanalytical techniques
were inadequate to detect the potential of streams to generate gas. A custom-made
apparatus, the gas evolution test cell (GETC), was developed in the Merck
Research Laboratories to measure the gas generation potential of various streams
under precisely defined conditions, is the key innovation for the development
of a quantitative gas-generation test method. 相似文献
34.
L.L. Carvalho 《European Polymer Journal》2006,42(10):2589-2595
Samples of a methacrylic side-chain azopolymer were synthesized by a radical copolymerization of methyl-methacrylate with the methacrylic derivative of the commercial dye Disperse Red-13 (DR13). Copolymers with different molecular weight were obtained by varying the reaction time and the concentration of initiator. Samples with molecular weight averages (Mw) from 3 to 8 × 104 g/mol and 1.4-1.7 polydispersity were obtained. The glass transition temperature of the samples increased linearly from the lower to the highest molecular weight. Optical quality cast films were prepared for all samples and photoinduced birefringence was successfully carried out in all samples as well as surface relief gratings could be inscribed in the cast films. 相似文献
35.
富镧和富铈混合稀土贮氢电极的性能 总被引:1,自引:0,他引:1
富镧和富铈混合稀土贮氢电极的性能*赵东江马松艳(黑龙江省绥化师专化学系绥化市152061)关键词混合稀土贮氢电极性能中图分类号O646.54混合稀土贮氢合金具有良好的电化学特性和较低的价格,成为贮氢电极研究的主要对象,已经开发出许多实用的电极材料[1... 相似文献
36.
37.
报道了一种单颗粒微电极制备新方法, 并研究了LaNi4.7Al0.3球形单颗粒微电极的电化学行为. 相似文献
38.
M. J. Whitcombe A. Gilbert G. R. Mitchell 《Journal of polymer science. Part A, Polymer chemistry》1992,30(8):1681-1691
The syntheses of three methacrylate monomers with cinnamate ester side-chains and of a further monomer with a corresponding cinnamide side-chain are described. Two of the monomers, with isomeric structures, were thermotropic liquid crystals. Although the clearing points were very similar the crystal melting points differed by 8°C. One compound also exhibited a monotropic smectic phase, behavior not shown by its isomer. The other two monomers were not liquid crystalline. The monomers were polymerized by free radical polymerization, both as homopolymers and as copolymers with methyl methacrylate. In the case of one of the mesogenic ester monomers, copolymers with a cyanophenyl benzoate monomer were also prepared. Three of the four monomers formed thermotropic liquid crystalline homopolymers and the copolymers with the benzoate monomer were also liquid crystalline. The monomers were considered as photoactive components of polymeric liquid crystals. As a preliminary investigation of their photochemistry, copolymers with methyl methacrylate were prepared and irradiated in solution with a broad-band source. Under these conditions two of the materials show a facile photo-Fries rearrangement of the aryl cinnamate ester group. © 1992 John Wiley & Sons, Inc. 相似文献
39.
The boxes contained kiwifruits were irradiated with cobalt-60 γ-rays at different dosages (0.6 , 1.8 and 3.6 KGy) and stored in a room ventilated at night, the natural ambient air being used as cool source.The results showed that the treatment which fruits irradiated with 0.6 KGy was the best after 85 days. It gave the normal-fruit rate of 95.10%, fruit flesh hardness of 4.10 Kg · cm-2, fresh and plump fruits, good quality and less Vc loss. 相似文献
40.