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971.
972.
Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (CT = 10, 25, or 40%) and with SSS mole fractions covering a broad range (fSSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed CT. The dependence of swelling on μ shows both polyelectrolyte (fSSS beyond the minimum) and antipolyelectrolyte behaviors (in the low fSSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with fSSS for any CT. Moreover, in the low fSSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007 相似文献
973.
974.
975.
J. Feuer 《Journal of Mathematical Analysis and Applications》2007,332(1):564-569
In this paper, we will study two classes of difference equations which are piecewise-linear and of similar forms. We will show that all nontrivial solutions of one equation are eventually periodic with prime period three. We will show this result for one case of the second equation. 相似文献
976.
曾韧英 《应用数学与计算数学学报》1997,11(1):27-32
本文讨论定义在Banach空间上的,既具有等式约束又具有不等式约束的,非光滑(F,P)不变凸多目标规划的Wolfe对偶性,Mond-Weir型对偶性可类似讨论之。 相似文献
977.
Weimin Xue 《中国科学A辑(英文版)》1997,40(7):673-679
A ringR is left co-semihereditary (strongly left co-semihereditary) if every finitely cogenerated factor of a finitely cogenerated
(arbitrary) injective leftR-module is injective. A left co-semihereditary ring, which is not strongly left co-semihereditary, is given to answer a question
of Miller and Tumidge in the negative. If
R
U
S
defines a Morita duality,R is proved to be left co-semihereditary (left semihereditmy) if and only ifS is right semihereditary (right co-semihereditary). Assuming thatS⩾R is an almost excellent extension,S is shown to be (strongly) right co-semihereditary if and only ifR is (strongly) right co-semihereditary.
Project supported by the National Natural Science Foundation of China. 相似文献
978.
Tokuzo Shiga 《Probability Theory and Related Fields》1997,108(3):417-439
Summary. We study the exponential decay rate of the survival probability up to time t>0 of a random walker moving in Zopf;
d
in a temporally and spatially fluctuating random environment. When the random walker has a speed parameter κ>0, we investigate
the influence of κ on the exponential decay rate λ(d,κ). In particular we prove that for any fixed d≥1, λ(d,κ) behaves like as logκ as κ↘0.
Received: 21 May 1996 / In revised form: 2 February 1997 相似文献
979.
Ansgar Jüngel 《Mathematische Nachrichten》1997,185(1):85-110
A multi-dimensional transient drift-diffusion model for (at most) three charged particles, consisting of the continuity equations for the concentrations of the species and the Poisson equation for the electric potential, is considered. The diffusion terms depend on the concentrations. Such a system arises in electrophoretic modeling of three species (neutrally, positively and negatively charged) and in semiconductor theory for two species (positively charged holes and negatively charged electrons). Diffusion terms of degenerate type are also possible in semiconductor modeling. For the initial boundary value problem with mixed Dirichlet - Neumann boundary conditions and general reaction rates, a global existence result is proved. Uniqueness of solutions follows in the Dirichlet boundary case if the diffusion terms are uniformly parabolic or if the initial and boundary densities are strictly positive. Finally, we prove that solutions exist which are positive uniformly in time and globally bounded if the reaction rates satisfy appropriate growth conditions. 相似文献
980.