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981.
982.
Nikolaos Athanasios Malamataris 《国际流体数值方法杂志》2012,70(1):71-95
The influence of aspect ratio in three‐dimensional, numerical experiments of separated flows is studied in the case of the backward‐facing step at Reynolds numbers 600, 800, and 950. The computational domain is designed as an actual laboratory experiment. The governing equations are the steady state, isothermal, and incompressible Navier–Stokes equations. The expansion ratio of the computational domain is 1:2. The aspect ratio varies from 1:10 to 1:40. The results of the computations focus on the spanwise variations of the length and the strength of the two eddies along the lower and upper wall. It is concluded that both numerical and laboratory experiments should be designed with an aspect ratio of at least 1:20, if only the accuracy of the position of the detachment and the re‐attachment points matters. If the accuracy of the shear‐stress distributions is also taken into account, then an aspect ratio of at least 1:30 should be chosen. Finally, if the magnitudes of the vortex centers are also considered, then only the aspect ratio of 1:40 qualifies for a realization of two‐dimensional flow conditions in the plane of symmetry. This is contrary to the common practice in the field, at least from the side of laboratory experiments, where an aspect ratio of 1:10 is still considered adequate for this purpose. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
983.
《Biomedical chromatography : BMC》2018,32(8)
In the present study, a new extraction method based on a three–phase system, liquid–liquid–liquid extraction, followed by dispersive liquid–liquid microextraction has been developed and validated for the extraction and preconcentration of three commonly prescribed tricyclic antidepressant drugs – amitriptyline, imipramine, and clomipramine – in human plasma prior to their analysis by gas chromatography–flame ionization detection. The three phases were an aqueous phase (plasma), acetonitrile and n–hexane. The extraction mechanism was based on the different affinities of components of the biological sample (lipids, fatty acids, pharmaceuticals, inorganic ions, etc.) toward each of the phases. This provided high selectivity toward the analytes since most interferences were transferred into n–hexane. In this procedure, a homogeneous solution of the aqueous phase (plasma) and acetonitrile (water–soluble extraction solvent) was broken by adding sodium sulfate (as a phase separating agent) and the analytes were extracted into the fine droplets of the formed acetonitrile. Next, acetonitrile phase was mixed with 1,2–dibromoethane (as a preconcentration solvent at microliter level) and then the microextraction procedure mentioned above was performed for further enrichment of the analytes. Under the optimum extraction conditions, limits of detection and lower limits of quantification for the analytes were obtained in the ranges of 0.001–0.003 and 0.003–0.010 μg mL−1, respectively. The obtained extraction recoveries were in the range of 79–98%. Intra– and inter–day precisions were < 7.5%. The validated method was successfully applied for determination of the selected drugs in human plasma samples obtained from the patients who received them. 相似文献
984.
985.
We have successfully extended our implicit hybrid finite element/volume (FE/FV) solver to flows involving two immiscible fluids. The solver is based on the segregated pressure correction or projection method on staggered unstructured hybrid meshes. An intermediate velocity field is first obtained by solving the momentum equations with the matrix‐free implicit cell‐centered FV method. The pressure Poisson equation is solved by the node‐based Galerkin FE method for an auxiliary variable. The auxiliary variable is used to update the velocity field and the pressure field. The pressure field is carefully updated by taking into account the velocity divergence field. This updating strategy can be rigorously proven to be able to eliminate the unphysical pressure boundary layer and is crucial for the correct temporal convergence rate. Our current staggered‐mesh scheme is distinct from other conventional ones in that we store the velocity components at cell centers and the auxiliary variable at vertices. The fluid interface is captured by solving an advection equation for the volume fraction of one of the fluids. The same matrix‐free FV method, as the one used for momentum equations, is used to solve the advection equation. We will focus on the interface sharpening strategy to minimize the smearing of the interface over time. We have developed and implemented a global mass conservation algorithm that enforces the conservation of the mass for each fluid. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
986.
987.
Ozlem Yazici M. Reyhan Moroglu Husnu Cankurtaran Ozlem Cankurtaran Ferdane Karaman 《Mikrochimica acta》2008,160(4):441-445
The composites of graphite with Ardel?D-100 which is a trademark of a polyester of bisphenol-A with terephthalic and isophthalic acid were used as a sensing material
in a conductometric vapor sensor. The magnitudes of responses are increased in the order of benzene, isobutyl acetate, isoamyl
acetate, ethyl benzene and chloro benzene. This suggests that Ardel?D-100 can be used as a sensing material for chlorobenzene, ethyl benzene and isoamyl acetate. On the other hand, specific
retention volumes of the sensed vapors on Ardel?D-100 coated on graphite were determined by inverse gas chromatography at temperatures between 200 and 260 °C. The distribution
coefficient, K
s of the vapors between stationary and mobile phases in the column was obtained. It was revealed for the first time that the
logarithm of K
s of the solvents varies almost linearly with their responses based on conductometric resistance of the sensing polymer composite.
Subsequently, the study suggests that gas chromatographic retention data can be used in prediction of the conductometric responses
of a polymeric sensor to vapors.
Correspondence: Ferdane Karaman, Department of Chemistry, Yildiz Technical University, 34220 Istanbul-Esenler, Turkey 相似文献
988.
The present paper investigates the multigrid (MG) acceleration of compressible Reynolds‐averaged Navier–Stokes computations using Reynolds‐stress model 7‐equation turbulence closures, as well as lower‐level 2‐equation models. The basic single‐grid SG algorithm combines upwind‐biased discretization with a subiterative local‐dual‐time‐stepping time‐integration procedure. MG acceleration, using characteristic MG restriction and prolongation operators, is applied on meanflow variables only (MF–MG), turbulence variables being simply injected onto coarser grids. A previously developed non‐time‐consistent (for steady flows) full‐approximation‐multigrid (s–MG) is assessed for 3‐D anisotropy‐driven and/or separated flows, which are dominated by the convergence of turbulence variables. Even for these difficult test cases CPU‐speed‐ups rCPUSUP∈[3, 5] are obtained. Alternative, potentially time‐consistent approaches (unsteady u–MG), where MG acceleration is applied at each subiteration, are also examined, using different subiterative strategies, MG cycles, and turbulence models. For 2‐D shock wave/turbulent boundary layer interaction, the fastest s–MG approach, with a V(2, 0) sawtooth cycle, systematically yields CPU‐speed‐ups of 5±½, quasi‐independent of the particular turbulence closure used. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
989.
Summary. We derive a set of asymptotically exact coupled amplitude-streaming flow ({CASF}) equations governing the evolution of weakly nonlinear nearly inviscid multimode Faraday waves and the associated
streaming flow in finite geometries. The streaming flow is found to play a particularly important role near mode interactions.
Such interactions come about either through a suitable choice of parameters or through breaking of degeneracy among modes
related by symmetry. An example of the first case is provided by the interaction of two nonaxisymmetric modes in a circular
container with different azimuthal wavenumbers. The second case arises when the shape of the container is changed from square
to slightly rectangular, or from circular to slightly noncircular but with a plane of symmetry. The generation of streaming
flow in each of these cases is discussed in detail and the properties of the resulting CASF equations are described. A preliminary
analysis suggests that these equations can resolve discrepancies between existing theory and experimental results in the first
two of the above cases. 相似文献
990.
This paper uses the element‐free Galerkin (EFG) method to simulate 2D, viscous, incompressible flows. The control equations are discretized with the standard Galerkin method in space and a fractional step finite element scheme in time. Regular background cells are used for the quadrature. Several classical fluid mechanics problems were analyzed including flow in a pipe, flow past a step and flow in a driven cavity. The flow field computed with the EFG method compared well with those calculated using the finite element method (FEM) and finite difference method. The simulations show that although EFG is more expensive computationally than FEM, it is capable of dealing with cases where the nodes are poorly distributed or even overlap with each other; hence, it may be used to resolve remeshing problems in direct numerical simulations. Flows around a cylinder for different Reynolds numbers are also simulated to study the flow patterns for various conditions and the drag and lift forces exerted by the fluid on the cylinder. These forces are calculated by integrating the pressure and shear forces over the cylinder surface. The results show how the drag and lift forces oscillate for high Reynolds numbers. The calculated Strouhal number agrees well with previous results. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献